Transition metal ditellurides(TMTDs)have versatile physical properties,including non-trivial topology,Weyl semimetal states and unique spin texture.Controlled growth of high-quality and large-scale monolayer TMTDs wit...Transition metal ditellurides(TMTDs)have versatile physical properties,including non-trivial topology,Weyl semimetal states and unique spin texture.Controlled growth of high-quality and large-scale monolayer TMTDs with preferred crystal phases is crucial for their applications.Here,we demonstrate the epitaxial growth of 1T'-MoTe_(2) on Au(111)and graphitized silicon carbide(Gr/SiC)by molecular beam epitaxy(MBE).We investigate the morphology of the grown1T'-MoTe_(2) at the atomic level by scanning tunnelling microscopy(STM)and reveal the corresponding microscopic growth mechanism.It is found that the unique ordered Te structures preferentially deposited on Au(111)regulate the growth of monolayer single crystal 1T'-MoTe_(2),while the Mo clusters were preferentially deposited on the Gr/SiC substrate,which impedes the ordered growth of monolayer MoTe_(2).We confirm that the size of single crystal 1T'-MoTe_(2) grown on Au(111)is nearly two orders of magnitude larger than that on Gr/SiC.By scanning tunnelling spectroscopy(STS),we observe that the STS spectrum of the monolayer 1T'-MoTe_(2) nano-island at the edge is different from that at the interior,which exhibits enhanced conductivity.展开更多
通过一步溶剂热法,在泡沫镍衬底(NF)上成功地制备了一种多功能电极材料,即含锆掺杂的镍硫化物(命名为Zr-Ni_(0.96)S/NF).通过调节锆源加入量,以优化样品微观结构和催化活性,结果表明:在锆源加入量为1 mmol时,得到的Zr-Ni_(0.96)S/NF纳...通过一步溶剂热法,在泡沫镍衬底(NF)上成功地制备了一种多功能电极材料,即含锆掺杂的镍硫化物(命名为Zr-Ni_(0.96)S/NF).通过调节锆源加入量,以优化样品微观结构和催化活性,结果表明:在锆源加入量为1 mmol时,得到的Zr-Ni_(0.96)S/NF纳米材料展现出均匀的纳米颗粒涂层结构.在1 M KOH溶液中,该材料表现出优异的HER(hydrogen evolution reaction)活性,在10 mA cm^(-2)电流密度下,其析氢过电位仅为95 mV,并且具有超过30小时的良好循环稳定性.当使用Zr-Ni_(0.96)S/NF同时作为阴极和阳极进行全解水时,它能够在1.98 V电压下产生200 mA cm^(-2)的电流密度,并具有15小时以上的循环稳定性,优于当前大多数非贵金属的电催化剂.展开更多
Purpose： The aims of this study were to assess differences of limb symmetry index （LSI） in strength- and coordination-related tasks between high-level, competitive, noninjured ski racers of different age-related pe...Purpose： The aims of this study were to assess differences of limb symmetry index （LSI） in strength- and coordination-related tasks between high-level, competitive, noninjured ski racers of different age-related performance levels and to prospectively assess limb differences as a possible risk factor for traumatic and overuse injury in youth ski racers. Methods： The study （Study 1） included 285 high-level competitive ski racers （125 females, 160 males） of 3 age-related performance levels and based on the school system： 95 youth （10-14 years, secondary modem school）, 107 adolescent （15-19 years, grammar school）, and 83 elite athletes （20-34 years）. To investigate the second aim （Study 2）, 67 of the 95 youth athletes were included and any traumatic or overuse injuries were prospectively recorded over 2 seasons. All athletes performed 4 unilateral tests （strength related： one-leg counter movement jump （OL-CMJ） and one-leg isometric/isokinetic press strength test （OL-ILS）; coordination related： one-leg stability test （OL-ST） and one-leg speedy jump test （OL-SJ））. The LSI was calculated by dividing the dominant leg by the nondominant leg and multiplying by 100. Kruskal-Wallis H tests and binary logistic regression analyses were conducted. Results： There were significant differences between the LSI of the 3 age-related performance-level groups only in the strength-related tests： the OL-CMJ （X^2（2, 285） = 9.09; p = 0.01） and the OL-ILS （X^2（2,285） = 14.79; p 〈 0.01）. The LSI for OL-ILS was found to be a significant risk factor for traumatic injury in youth ski racers （Wald = 7.08; p 〈 0.01）. No significant risk factors were found for overuse injuries. Conclusion： Younger athletes display slightly greater LSI values only in the strength-related tests. The cut-off value of limb differences of 〈 10% for return to sport decisions seems to be appropriate for elite athletes, but for youth and adolescent athletes it has to be critically discussed. It seems to be necessary to define thresholds based on specific performance tasks （strength vs. coordination related） rather than on generalizations, and age-related performance levels must be considered. Limb differences in unilateral leg extension strength represent a significant injury risk factor in youth ski racers.2018 Published by Elsevier B.V. on behalf of Shanghai University of Sport. This is an open access article under the CC BY-NC-ND license. （http：//creativecommons.org/licenses/by-nc-nd/4.0/）.展开更多
We give an existence result of the obstacle parabolic equations3b（x,u） div（a（x,t,u, Vu））＋div（（x,t,u））=f in QT, 3twhere b（x,u） is bounded function ot u, the term atva,x,r,u, v u）） is a Letay type operat...We give an existence result of the obstacle parabolic equations3b（x,u） div（a（x,t,u, Vu））＋div（（x,t,u））=f in QT, 3twhere b（x,u） is bounded function ot u, the term atva,x,r,u, v u）） is a Letay type operator and the function is a nonlinear lower order and satisfy only the growth condition. The second term belongs to L1 （QT）. The proof of an existence solution is based on the penalization methods.展开更多
基金Project supported by the National Key R&D Program of China (Grant No.2022YFA1204302)the National Natural Science Foundation of China (Grant Nos.52022029,52221001,92263107,U23A20570,62090035,U19A2090,and 12174098)+1 种基金the Hunan Provincial Natural Science Foundation of China (Grant Nos.2022JJ30142 and 2019XK2001)in part supported by the State Key Laboratory of Powder Metallurgy,Central South University。
文摘Transition metal ditellurides(TMTDs)have versatile physical properties,including non-trivial topology,Weyl semimetal states and unique spin texture.Controlled growth of high-quality and large-scale monolayer TMTDs with preferred crystal phases is crucial for their applications.Here,we demonstrate the epitaxial growth of 1T'-MoTe_(2) on Au(111)and graphitized silicon carbide(Gr/SiC)by molecular beam epitaxy(MBE).We investigate the morphology of the grown1T'-MoTe_(2) at the atomic level by scanning tunnelling microscopy(STM)and reveal the corresponding microscopic growth mechanism.It is found that the unique ordered Te structures preferentially deposited on Au(111)regulate the growth of monolayer single crystal 1T'-MoTe_(2),while the Mo clusters were preferentially deposited on the Gr/SiC substrate,which impedes the ordered growth of monolayer MoTe_(2).We confirm that the size of single crystal 1T'-MoTe_(2) grown on Au(111)is nearly two orders of magnitude larger than that on Gr/SiC.By scanning tunnelling spectroscopy(STS),we observe that the STS spectrum of the monolayer 1T'-MoTe_(2) nano-island at the edge is different from that at the interior,which exhibits enhanced conductivity.
文摘通过一步溶剂热法,在泡沫镍衬底(NF)上成功地制备了一种多功能电极材料,即含锆掺杂的镍硫化物(命名为Zr-Ni_(0.96)S/NF).通过调节锆源加入量,以优化样品微观结构和催化活性,结果表明:在锆源加入量为1 mmol时,得到的Zr-Ni_(0.96)S/NF纳米材料展现出均匀的纳米颗粒涂层结构.在1 M KOH溶液中,该材料表现出优异的HER(hydrogen evolution reaction)活性,在10 mA cm^(-2)电流密度下,其析氢过电位仅为95 mV,并且具有超过30小时的良好循环稳定性.当使用Zr-Ni_(0.96)S/NF同时作为阴极和阳极进行全解水时,它能够在1.98 V电压下产生200 mA cm^(-2)的电流密度,并具有15小时以上的循环稳定性,优于当前大多数非贵金属的电催化剂.
文摘Purpose： The aims of this study were to assess differences of limb symmetry index （LSI） in strength- and coordination-related tasks between high-level, competitive, noninjured ski racers of different age-related performance levels and to prospectively assess limb differences as a possible risk factor for traumatic and overuse injury in youth ski racers. Methods： The study （Study 1） included 285 high-level competitive ski racers （125 females, 160 males） of 3 age-related performance levels and based on the school system： 95 youth （10-14 years, secondary modem school）, 107 adolescent （15-19 years, grammar school）, and 83 elite athletes （20-34 years）. To investigate the second aim （Study 2）, 67 of the 95 youth athletes were included and any traumatic or overuse injuries were prospectively recorded over 2 seasons. All athletes performed 4 unilateral tests （strength related： one-leg counter movement jump （OL-CMJ） and one-leg isometric/isokinetic press strength test （OL-ILS）; coordination related： one-leg stability test （OL-ST） and one-leg speedy jump test （OL-SJ））. The LSI was calculated by dividing the dominant leg by the nondominant leg and multiplying by 100. Kruskal-Wallis H tests and binary logistic regression analyses were conducted. Results： There were significant differences between the LSI of the 3 age-related performance-level groups only in the strength-related tests： the OL-CMJ （X^2（2, 285） = 9.09; p = 0.01） and the OL-ILS （X^2（2,285） = 14.79; p 〈 0.01）. The LSI for OL-ILS was found to be a significant risk factor for traumatic injury in youth ski racers （Wald = 7.08; p 〈 0.01）. No significant risk factors were found for overuse injuries. Conclusion： Younger athletes display slightly greater LSI values only in the strength-related tests. The cut-off value of limb differences of 〈 10% for return to sport decisions seems to be appropriate for elite athletes, but for youth and adolescent athletes it has to be critically discussed. It seems to be necessary to define thresholds based on specific performance tasks （strength vs. coordination related） rather than on generalizations, and age-related performance levels must be considered. Limb differences in unilateral leg extension strength represent a significant injury risk factor in youth ski racers.2018 Published by Elsevier B.V. on behalf of Shanghai University of Sport. This is an open access article under the CC BY-NC-ND license. （http：//creativecommons.org/licenses/by-nc-nd/4.0/）.
文摘We give an existence result of the obstacle parabolic equations3b（x,u） div（a（x,t,u, Vu））＋div（（x,t,u））=f in QT, 3twhere b（x,u） is bounded function ot u, the term atva,x,r,u, v u）） is a Letay type operator and the function is a nonlinear lower order and satisfy only the growth condition. The second term belongs to L1 （QT）. The proof of an existence solution is based on the penalization methods.
