Magma Mixing Genesis of the Mafic Enclaves and Related Granitoids in the Kan Granite-Gneiss Complex of Central Côte d’Ivoire: Evidence from Geology, Petrology and Geochemistry

The mafic enclaves from Paleoproterozoic domain are considered to be the results of large-scale crust-mantle interaction and magma mixing. In this paper, petrography, mineralogy and geochemistry were jointly used to determine the origin of the mafic enclaves and their relationship with the host granitoids of the Kan granite-gneiss complex. This study also provides new information on crust-mantle interactions. The mafic enclaves of the Kan vary in shape and size and have intermediate chemical compositions. The diagrams used show a number of similarities in the major elements (and often in the trace elements) between the mafic enclaves and the host granitoids. Geochemical show that the Kan rock are metaluminous, enriched in silica, medium to high-K calc-alkaline I-type granite. The similarities reflect a mixing of basic and acid magma. Mafic enclaves have a typical magmatic structure, which is characterized by magma mixing. The genesis of these rocks is associated with the context of subduction. They result from the mixing of a mafic magma originating from the mantle and linked to subduction, and a granitic magma (type I granite) that arises from the partial melting of the crust.

Seasonal and Spatial Variations in Water Physicochemical Quality of Coastal Potou Lagoon (Côte d’Ivoire, Western Africa)

The study investigates the seasonal and spatial variations in water quality parameters at four different locations along Potou lagoon for seventeen consecutive months. In order to explore spatial variation among different stations and seasonal changes, no parametric test of ANOVA was used to compare the mean values of the tested parameters for all the different sampling sites and seasons. Seasonal observations on water quality parameters and chlorophyll-a in Potou coastal lagoon revealed that the coastal water was significantly influenced by freshwater during the long and short rainy seasons. The seasonal significant variation (p a increased during the long dry season, whereas, the concentration of nutrients (nitrite, nitrate, ammonium and soluble reactive phosphorus) increased in the rainy periods. Contrary to the seasonal variation, a spatial homogeneity (horizontal) was registered for all variables, a condition related to the low human occupation in the lagoon watershed. Comparing this study with others conducted in Potou lagoon in 2008, no critical differences that evidence alteration in the water quality were found.

Evaluation of the Compaction of a No-Till Vertisol Field Using Methods of Cone Index and Pedotransfer Function in Semi-arid Context of Morocco

This study evaluated compaction level of a 15-year old no-till vertisol field crop(40.91%clay,44.16%loam and 14.93%sand)having organic matter contents of 2.23%and 2.91%in 0-10 cm and 10-20 cm profiles,respectively.The bulk density ranged from 1.30 g/cm^3 to 1.80 g/cm^3 in the field boundaries,and from 1.01 g/cm^3 to 1.40 g/cm^3 in its center.The field showed a gradient of limestone from 3%to 13%.Measurements were done to evaluate soil strength(cone index)and soil plasticity(Atterberg limits).The soil strength showed different levels of compaction from 4.5 MPa to 16 MPa to distinct five spatial clusters in the field.The soil compactness was related to limestone gradient according the correlation found between the soil strength and limestone levels.The soil plasticity test showed occurrence of plastic limits when the moisture content decreased from 26%to 15%within 5 d interval.The Atterberg limits showed the importance of respecting intervention delays to avoid soil compaction due to its plasticity.A pedotransfer function was developed using soil parameters of texture,organic matter,bulk density,cohesion,internal friction angle and moisture content to compute its precompression stress.Results showed importance of compaction in the field extremities due to importance of machines/tools traffic without avoiding cropping interventions during soil plasticity state.The soil strength(as measured value)was correlated to precompression stress(as estimated values)to show the importance of using pedotransfer function as significant method to evaluate indirectly compactness or susceptibility to compaction of the studied vertisol.

Qualitative Assessment and Typology of the Water Resource Used for the Production of Drinking Water in Duékoué, Western Côte d’Ivoire

The objective of this study was to evaluate the typology of water through physicochemical and bacteriological characterization with the aim of highlighting its vulnerability as a drinking water resource. The methodology adopted was to evaluate the level of pollution by monitoring the spatiotemporal variation of the water pollution indicator levels of Lake Dohou. The sampling frequency is monthly for one year, from November 2017 to October 2018, in order to obtain a fairly representative image of water quality and its seasonal evolution in eight (8) well-defined stations. The parameters were determined using the standard methods defined by the French Association for Standardization (AFNOR). This study shows that the waters are acidic, with an average pH of 5.81 and a low electrical conductivity of between 42.67 ± 4.30 and 59.62 ± 21.84 μS.cm-1. At all stations, seasonal mean water transparencies are low (<1 m). It is also noted that 99.7% of the water samples collected had total nitrogen (TN) levels above the limit of 4 mg.L-1. All of the lake’s waters have non-compliant BOD5 (2.L-1) for raw water intended for the production of drinking water. Sites D6 and D7 have COD/BOD5 ratio greater than 3, which indicates the presence of non-biodegradable organic matter in these areas. Total coliforms, Escherichia coli and Enterococci were present in 100% (28/28) water samples at concentrations ranging from 2300 to 173,000 CFU/100 mL, from 100 to 1650 CFU/100 mL and from 20 to 1140 CFU 1/100 mL respectively. For Salmonella pathogens, they were detected in 50% of the dry season samples and in 100% of the rainy season samples. This almost permanent presence of this pathogenic germ denotes a poor quality of water with reference to this parameter. The presence of total coliform and other microbial contaminants suggests that supplied water is highly contaminated with pathogens and great reservoirs for them. Principal component analysis (PCA) of the physicochemical data set allowed defining three different classes of water on the Dohou Lake. Outside the upstream zone (D6 and D8), water could continue to be used for the production of drinking water.

Assessment of the Quality of Sediments and Agricultural Soils: Case of the Ity-Floleu Area in the Prefecture of Zouan-Hounien, Western Côte d’Ivoire

The objective of this study is to assess the level of metal contamination of sediments and agricultural soils in the Ity-Floleu zone. The concentrations of trace elements (Fe, Mn, As, Cd, Cr, Cu, Hg, Ni, Pb and Zn) were measured in different seasons over two successive years. The sediment pollution index made it possible to note that the sediments and agricultural soils of the various stations studied are highly polluted in all seasons. The calculation of the geoaccumulation index indicates that surface water sediments most often experience extreme or moderate pollution in As, Cd, Cu, Hg and Zn in the dry or rainy season except in Pb in some cases. We observed that the sediments of the Cavally river present a serious pollution due to extreme anthropic activities carried out along the river. Over the entire region, the results of the potential ecological risk index (RI) indicate that all the sediments and agricultural soils analysed present a moderate ecological risk in terms of Pb and Zn in certain cases and an ecological risk is observed low bound to other metals in all seasons. This metallic pollution generated by human activities in this region can have consequences for the environment and biodiversity.

Mapping and Characterization of Agricultural Systems from Time Series of Normalized Difference Vegetation Index (NDVI) in the Northeast Area of Tadla, Morocco

Introduction: Agriculture is the focus of sustainable development and food security in Morocco, contributing 14% to the national economy and its socio-economic impact depends on agro-climatic conditions and the availability of water resources. The objective of this work is to demonstrate that agriculture in Morocco, and especially in the Tadla region, is distributed according to the availability of underground water. Method: This work was carried out in the transition zone between the phosphate plateau and the plain of Tadla, a site of more than 124,000 ha. To achieve the objectives set, we used Landsat-8 OLI (Operational Land Imager) data sharpened to 15 m. The Support Vector Machine (SVM) classifications were applied to the 10-period Normalized Difference Vegetation Index (NDVI) series. Results: It is shown that agriculture in Morocco is highly dependent on irrigation. In the classified map, it can be observed that the southern region, a zone with a semi-arid climate, which generally relies on irrigation, is very developed in agriculture, whereas in the north most of the soil is bared with cereals that mainly depend on rainfall. Conclusion: The possible water shortage in the region puts food availability in Morocco at risk of inadequacy. Food security depends on the availability of water, a natural resource at risk of extinction. Therefore, strategies to reduce the risk of agricultural drought must be at the forefront of Moroccan policies.

Seasonal and Spatial Variations of Phytoplankton in Relation to Physico-Chemical Parameters in Adjin Lagoon, Abidjan, Côte d’Ivoire, West Africa

Investigations were carried out on spatial and seasonal composition, distribution and abundance of phytoplankton in Adjin lagoon located in south-eastern of Côte d’Ivoire. Samples were collected at six stations during the four seasons in 2013 year. Freshwater inflow from Bété, Djibi and Mé Rivers influenced the variability of nutrients concentration in this lagoon. From a seasonal point of view, the parameters studied are significantly affected by freshwater inputs during the rainy season. This period is characterized by high values of turbidity, suspended solids and nutrients in the water. Overall, 66 taxa from six phyla were recorded. The Chlorophyta had the highest species diversity and Cyanobacteria had the highest relative abundance throughout the year. The temporal distribution of phytoplankton showed that the highest values of density were recorded in the long rainy season and the lowest values in the long dry season. Spatially, the highest abundance (297,927 × 103 cells·L-1) of phytoplankton was found in station 3 and the lowest (74,222 × 103 cells·L-1) in the station 5.

Geological,Mineralogical and Geochemical Studies of Pyrite Deposits in the Eastern Part of Douala Sub-Basin(Cameroon,Central Africa)

Pyrite deposit of pK27, Douala sub-basin (Cameroon, Central Africa) was studied in a tropical forest setting physically and using X-ray diffraction and X-ray fluorescence spectrometry (XRF) in order to characterize the mineralization for his industrial utilization. The sedimentary materials from the pyrite deposit were grouped into five (05) main lithofacies, including four claystone facies and one conglomeratic facies. The mineralization occurs along the low slopes of valleys in?light grey claystone facies situated on the bottom of outcrops with 80 to 200 cm thickness. The?particle size distribution of clayey materials host rocks shows that they are essentially constituted of clay and silts fractions. However, their Sorting index (So) more than 4.5 corresponds to poorly sorted sediments and the torrential type;whereas their Coefficient of asymmetry (A) more than 1?indicates that the sorting is carried out towards fine particles. Macroscopically, pyrite in these?materials is in crumbly and consolidated piles with aggregate pyrites in oolithic concretions, and?globular, cubic, octaedric, massive and fossiliferous forms. The mineralogical compositions of?these clayey materials indicate that they are essentially kaolinitic and illitic, followed by goethite, quartz, pyrite, halloysite, anatase and rutile with hematite as accessory minerals. Pyrite in sand fractions is associated with kyanite, grenat, rutile, diopside, muscovite and tourmaline the minerals which?recognize the regional metamorphism. However, the specific chemical signature of SO3content?high in clayey materials and abundant (50.86% - 57.64% SO3) in pyrite is characteristic of the pK27 pyritic formations in the eastern part of Douala sub-basin. Moreover, the Co:Ni ratios of pyrites approximately 0.25 to 0.8 are characteristic of sedimentary pyrites and also suggest an anoxic environment.

Indices of Water Quality and Pesticide Monitoring Survey in Lake of Western Cote d’Ivoire and Its Human Risk Assessment

The aims of the work were to study the current quality of the water in Lake DOHOU used for drinking water supply through several physical, chemical analyses and using water quality indices (WQI). In addition, the question was whether the populations are at risk after drinking water of lake following a reduction of 50% and 75% in the median and maximum values of pesticides. Thus, the results of the pesticide monitoring program were incorporated into probabilistic human health risk assessment exercises. Water samples were collected over a period of one year. Pesticides were subjected to solid phase extraction and then analyzed using gas chromatography coupled to tandem mass spectroscopy. The other parameters were measured according to conventional methods. The results showed that the most frequently detected pesticides were aldicarb (79%), simazine (79%) and monolinuron (44%). They also showed the mean values of concentrations exceeding 1.5 μg/L. Metoxuron detected at a frequency of 29% showed the maximum average concentration (13.46 μg/L). Nearly 98% of the sampling points had at least one substance with an average concentration above the quality standard (0.1 μg/L) and 80% did not meet the total concentration standards. Cumulative risk quotient estimates after 50% or 75% abatement for frequently identified pesticides were greater than unity when extreme?values for adults and children were considered. To determine the suitability of water for aquatic life, drinking water consumption and drinking water production, the water quality index (WQI), the heavy metal pollution (HPI) and the heavy metal evaluation (HEI) were calculated. The poor quality of the water was mainly related to pesticides, organic matter and microbiological parameters. Most of the nutrients and metals studied were often below the standards of drinking water and aquatic life. The Water Quality Index (WQI) has shown that water quality is degrading for these three modes of use and ranges from poor to marginal. The coupling of monitoring data with probabilistic estimates of human risks could be used by the Ivorian authorities to propose effective pollution management plans.

Activities and Uses of Aghien Lagoon(South-East of Cote d’Ivoire)

This study aims to identify human uses and activities in the watershed Aghien lagoon in nine rural communities located downstream, near the lagoon in rural area, and upstream of the lagoon in the urban area. A sample of two thousand two hundred fifty eight (2258) households is selected by the cluster sampling technique to three degrees. To these persons, a survey was administered. An interview guide was submitted to the various economic operators of these areas. The results show that the lagoon is used by localities near the lagoon for the dishes, laundry, bathing and swimming for more than 80% of households. This resource is also used for fishing, transport, irrigation, consumption and defecation but at low levels and as a receptacle for garbage. In the villages bordering the lagoon, the main economic activity is agriculture, unlike trade in upstream urban areas.

Study of the Hydro-Chemical and Bacteriological Well Water Characteristics of M’Bahiakro (Central-Eastern Cote d’Ivoire)

The use of well water by disadvantaged populations in most African cities often presents health risks. The purpose of this study is to determine the physico-chemical and microbiological quality of M’bahiakro well water. A series of physico-chemical, microbiological and piezometric analyses were carried out on the well water in the area. The results of these analyses were processed using Piper and Schoeller-Berkaloff diagrams and the software R 3.1.2 for Principal Component Analysis. Physico-chemical analysis results show that the water has an average temperature of 28&#176C. They are acidic, with a pH that generally varies from 4 to 6. M’bahiakro well waters are highly mineralized, with an average electrical conductivity of 369.1 μS/cm and 984.1 μS/cm and pass from sodium and potassium chlorinated facies in the dry season (February) to sodium chlorinated facies in the rainy season (October) with K+, Na+ and NO3- ions dominating. These ions would be the result of soil rainfall and the intervention of anthropogenic activities in the pollution of shallow groundwater. Bacteriological results exploitation shows that the well waters studied host high densities of enteritis bacteria (E. coli, Fecal streptococcus, and Clostridium perfringens) during the rainy period (October). M’Bahiakro’s well water is of poor quality and unsuitable for human consumption without prior treatment. However, they deserve particular attention and would require further treatment in rainy periods.

Mapping of Pollution Risk of Surface Waters by Runoff from Watershed: Case of Aghien Lagoon (South of C&#244;te d’Ivoire)

The operating capacity of the Abidjan’s groundwater became insufficient. The deficit in drinking water resources in the District of Abidjan remains the major concern of the decision maker. The Aghien lagoon stands as one of the most interesting alternatives. However, studies show the levels of pollutions of this resource without lighting out on the causes and sources of these pollutions. The present study extends over the entire catchment of the Aghien lagoon which reveals the presence of urban areas and agricultural activity areas. This raises real concerns for the Ivorian authorities. This study suggests making cartography of the risk levels of pollution on the Aghien lagoon by the surface runoff on the watershed to enlighten the decision-makers on the possible measures to be taken for the protection of this resource. It emerges from it that the risk of contamination of the lagoon is very likely. Agricultural and domestic best practices inside the pouring pond are compulsory to fight against the pollutions of this resource.

Contribution of a Geographical Information System to the Study of Soil Loss Dynamics in the Lobo Catchment (Côte d’Ivoire)

The Lobo watershed is highly anthropogenic since it has become the main production area for cocoa and coffee in C?te d’Ivoire. It therefore seems important to quantify soil loss by water erosion in this region. The Wischmeier modeling was used to model the main factors involved in erosive phenomena. Crosscutting of thematic maps and the application of the USLE formulas made possible to evaluate the erosion rate at the watershed scale in 1986 and 2014. Although soil is susceptible to erosion and erosivity is increased, the results indicate a growth in soil loss estimated at 90.12%. Some agroforestry efforts are still possible to help reducing those soil losses.

Use of the Inverse Slope Method for the Characterization of Geometry of Basement Aquifers: Case of the Department of Bouna (Ivory Coast)

The inverse slope method (ISM) was used to interpret electric sounding data to determine the geoelectric parameters of the alteration zones (continuous media) and rocky environments (discontinuous environments) of the Bouna Department. Having both qualitative and quantitative interpretation, the inverse slope method (ISM) has the ability to determine the different geoelectric layers while characterizing their resistivities and true thicknesses. In the Bouna department, this method allowed us to count a maximum of four (4) geoelectric layers with a total thickness ranging from 12.99 m to 24.66 m. The alteration thicknesses calculated by the ISM in comparison with those measured in the boreholes showed a linear agreement of the coefficient of determination R2 = 0.8269 with the support of the Nash criterion which showed that this method gave thicknesses of alteration close to 76.76% of that obtained during the drillings.

Sanitation By-Products Used for Lettuce (<i>Lactuca sativa</i>L.) Production: Quantitative Microbial Risk Assessment

Sanitation by-products (i.e. greywater, human urine and toilet compost) reuse for agriculture presents an opportunity to enhance food security while overcoming water scarcity and fertilizers issues in developing countries. However, the risks to health from farmers and consumers’ exposure to pathogenic micro-organisms persistent in sanitation by-products has hindered their popularity in these regions. This study was conducted to apply a quantitative microbial risk assessment to estimate the annual risk probability of Salmonella infection associated with these sanitation by-products reuse for lettuce production and explore options for health risk reduction. Risk was performed a Monte Carlo simulation for farmers and consumers. The exposure routes were contaminated soil ingestion, urine/greywater/compost ingestion and lettuce consumption without washing. Results showed that the annual infection risks of Salmonella through ingestion contaminated soil associated with urine and compost were typical scenario: 9.04 × per-person-per-year (pppy) and 2.97 × pppy, respectively, are higher than the WHO benchmark (≤1.0 × pppy). Conversely, those contaminated from greywater were 6.83 × pppy are meet the WHO benchmark. On the other hand, annual risks through lettuce consumption fertilized with urine (1.20 × pppy) were less than the risks from compost (6.20 × pppy) and greywater (7.76 × pppy). Moreover, the annual risks of infection from greywater ingestion (1.77 × pppy) exhibits a much higher risk than that urine ingestion (6.20 × pppy) approximately two orders of magnitude, and which are higher than the WHO tolerable limit of risk. The risk assessment outcomes of using sanitation by-products to lettuce production should be promoted with proper awareness of the risk by farmers and consumers.

Anionic Surfactants Levels in M’Koa Lake Water (Jacqueville, Cote d’Ivoire)

In this study, anionic surfactants concentrations and other physico-chemical parameters of surface water quality were assessed in the water of M’Koa Lake in the city of Jacqueville (C?te d’Ivoire). Three sampling campaigns were conducted at different seasons at six (6) sampling stations, identified in M’koa Lake by taking into account potential sources of pollution. The analyses of physico-chemical parameters were carried out using both the French AFNOR standard and the methods described by Rodier. The anionic surfactants concentrations were performed by using the methylene blue colorimetric method. The average concentrations of anionic surfactants in the water of M’koa Lake ranged from 0.23 ± 0.04 mg·L-1 to 1.43 ± 0.68 mg·L-1. They are high compared to both population density and socio-economic activities of Jacqueville’s town. These values can be explained by the characteristics of the studied Lake that do not allow enough dilution of the discharged effluent. The results indicate that M’koa Lake is subjected to harmful pollution by anionic surfactants. And among the physicochemical parameters studied, only turbidity and transparency values show water quality deterioration, favoured by wastewater discharge and direct human activities around the Lake.