In order to improve the dispersibility of cellulose nanocrystal(CNC)particles,three different grafted reactions of acetylation,hydroxyethylation and hydroxypropylation were introduced to modify the CNC surface.The mai...In order to improve the dispersibility of cellulose nanocrystal(CNC)particles,three different grafted reactions of acetylation,hydroxyethylation and hydroxypropylation were introduced to modify the CNC surface.The main advan-tages of these methods were the simple and easily controlled reaction conditions,and the dispersibility of the resulting products was distinctly improved.The properties of the modified CNC were characterized by means of Fourier trans-form infrared spectroscopy(FT-IR),13C nuclear magnetic resonance(NMR),transmission electron microscopy(TEM)and thermogravimetric analyses(TGA).The results indicated that after desiccation,the modification products could be dis-persed again in the proper solvents by ultrasonic treatments,and the diameter of their particles had no obvious changes.However,their thermal degradation behaviors were quite dif-ferent.The initial decomposition temperature of the modified products via hydroxyethylation or hydroxypropylation was lower than that of modified products via acetylation.展开更多
The direct electrochemical behavior between the glucose oxidase (GOD) and the multi walled carbon nanotubes (MWNTs) has been studied. Two pairs of cyclic voltammetric peaks corresponding to the two different processe...The direct electrochemical behavior between the glucose oxidase (GOD) and the multi walled carbon nanotubes (MWNTs) has been studied. Two pairs of cyclic voltammetric peaks corresponding to the two different processes, i.e. mass transport and surface reaction of GOD are observed on this MWNTs. The formal potentials with E o′=-0.45 V and E o′=-0.55 V were obtained respectively. The GOD film was observed on the carbon nanotube by the TEM.展开更多
文摘In order to improve the dispersibility of cellulose nanocrystal(CNC)particles,three different grafted reactions of acetylation,hydroxyethylation and hydroxypropylation were introduced to modify the CNC surface.The main advan-tages of these methods were the simple and easily controlled reaction conditions,and the dispersibility of the resulting products was distinctly improved.The properties of the modified CNC were characterized by means of Fourier trans-form infrared spectroscopy(FT-IR),13C nuclear magnetic resonance(NMR),transmission electron microscopy(TEM)and thermogravimetric analyses(TGA).The results indicated that after desiccation,the modification products could be dis-persed again in the proper solvents by ultrasonic treatments,and the diameter of their particles had no obvious changes.However,their thermal degradation behaviors were quite dif-ferent.The initial decomposition temperature of the modified products via hydroxyethylation or hydroxypropylation was lower than that of modified products via acetylation.
文摘The direct electrochemical behavior between the glucose oxidase (GOD) and the multi walled carbon nanotubes (MWNTs) has been studied. Two pairs of cyclic voltammetric peaks corresponding to the two different processes, i.e. mass transport and surface reaction of GOD are observed on this MWNTs. The formal potentials with E o′=-0.45 V and E o′=-0.55 V were obtained respectively. The GOD film was observed on the carbon nanotube by the TEM.
