Study of Technology of Stripping Nickel Coating on NdFeB Permanent Magnet

The influences of category and density of reagents, temperature and the value of pH in the solution of stripping the nickel coating on NdFeB permanent magnet on the stripping result were studied systematically.The practical formular contains mainly the oxidant m-O2NC6H4SO3Na, the complex reagent ( NaOOCCH2 ) 2N( CH2 ) 2N( CH2COOH)2,the reagent of retarding corrosion KF and the calatyze RL-3 was obtained.

Morphology and Mechanical Properties of PS/Al_2O_3 Nanocomposites Based on Selective Laser Sintering

Selective laser sintering （SLS） is a new process to prepare the polystyrene （PS）/Al2O3 nanocomposites. In this paper, with different laser power and other processing parameters unchanged, the morphology, density and mechanical properties of the sintered specimens were investigated. It was found that nano-sized inorganic particles are uniformly located in the PS matrix and the maximum density of the sintered specimens with pure PS powder reaches 1.07 g/cm^3, higher than 1.04 g/cm^3 that of the sintered specimens with mixture powder. Due to strengthening and toughness of the nano-sized Al2O3 inorganic particles, the maximum notched impact strength and tensile strength of the sintered part mixed with nano-sized inorganic particles are improved greatly from 7.5 to 12.1 kJ/m^2 and from 6.5 to 31.2 MPa, respectively, under the same sintering condition.

Research of the Higher-order Finite Element Arithmetic for Radiation Exchange

With the development of aeronautic and astronautic techniques, radiation becomes much more significant while the structure is exposed to the higher and higher temperature. Most of the current finite element software packages treat it using the net-radiation method or absorbed radiation method based on the assumption of isothermal surface with uniform radiation heat flux, which brings the conflict between the precision and the quantity of grids. Using integral method to compute the variable radiation heat flux in higher-order finite element, the precision can be improved greatly while using the same quantity of grids, because it is more consistent with the distribution of real temperature. In this paper, the integral is only processed on the same integral points as those used for solving the finite element equations, so it may be of high efficiency. In an academic testing model, the result is contrast to which get in ANSYS, proving the high precision of the method. Then an actual sandwich panel used in the thermal protection system is analyzed with the method, and the error is comparatively low to the analytical answer while the computation being of high efficiency.

Microstructure and properties of vacuum counter-pressure cast aluminum alloy

The microstructure and properties of vacuum counter-pressure cast aluminum alloy were studied. Results indicated that under the condition of vacuum counter-pressure, liquid melts fill mould cavity under the vacuum and crystallize under high pressure which have very good effect on nucleation and solidification feeding. Compared with gravity casting, the microstructure of vacuum counter-pressure cast aluminum alloy is much finer and more uniformly distributed. Mechanical properties of vacuum counter-pressure cast aluminum alloy are improved significantly.

Role of CO_2 in the initial stage of atmospheric corrosion of AZ91 magne-sium alloy in the presence of NaCl

The effect of CO2 and NaCl on the initial stage of atmospheric corrosion of AZ91 magnesium alloy was studied. The observation of surface morphology by optical microscopy （OM）, scanning electron microscopy （SEM） and the analysis of corrosion products by X-ray diffraction （XRD） were integrated to investigate corrosion evolution. The results showed that NaCl stimulated the corrosion by promoting the formation of thin electrolyte film, increasing the conductivity and breaking the protective film in the absence of CO2. The morphology of the corroded samples with deposited NaCl was more homogenous in the presence of CO2. It was suggested that NaCl-induced corrosion was inhibited in the presence of CO2 by the formation of slightly soluble corrosion products containing hydroxy carbonates and hydroxy chlorides that provided a partly protective layer on the surface of the magnesium alloy.

Large Eddy Simulation of Particle Wake Effect and RANS Simulation of Turbulence Modulation in Gas-Particle Flows

The turbulence enhancement by particle wake effect is studied by large eddy simulation （LES） of turbulent gas flows passing a single particle. The predicted time-averaged and root-mean-square fluctuation velocities behind the particle are in agreement with the Reynolds-averaged Navier-Stokes modeling results and experimental results. A semi-empirical turbulence enhancement model is proposed by the present-authors based on the LES resuits. This model is incorporated into the second-order moment two-phase turbulence model for simulating vertical gas-particle pipe flows and horizontal gas-particle channel flows. The simulation results show that compared with the model not accounting for the particle wake effect, the present model gives simulation results for the gas turbulence modulation in much better agreement with the experimental results.

Microdistortion behavior of Al alloy reinforced by SiC_p

Al alloy reinforced with SiCp was fabricated by the method of pressureless infiltration.The effects of factors such as SiCp size,volume fraction,matrix material and heat treatment process on microdistortion behavior of Al alloy were investigated.The results show that microdistortion decreases along with lessening of SiCp size and increasing of SiCp volume fraction.Matrix material has influence on the microdistortion behavior,and solution-aging can improve the microdistortion behavior.Stress and residual strain related to microdistortion behavior were simulated by FEM.It is found that the distribution of strain and stress is not symmetrical; residual strain and stress at interface are higher than those at the other places;at the sharp-angled area of a particle,matrix has the highest strain and stress where plastic distortion is caused at first;the microdistortion and stress far from the interface are smaller.

Simulation of fuzzy control systems for nonferrous alloy vacuum counter-pressure casting

Through simulation analyses of vacuum counter-pressure casting fuzzy control systems based on MATLAB, fuzzy control systems designed by simulation can track technical route established well. When transmission functions of vacuum counter-pressure casting controlled objects are changed in operation, fuzzy control systems can carry on self-regulation and stabilize quickly, and embody the advantages of fleet response velocity and little adjusting quantity. The design of vacuum counter-pressure casting fuzzy control systems is accelerated and improved greatly by simulation based on MATLAB. Meanwhile, their design is accurate and reliable. Moreover, microstructure and properties of thin-wall aluminum alloy castings are improved effectively by using fuzzy control systems.

Preparation of montmorillonite modif ied phenolic resin for shell process

The development of montmorillonite modified phenolic resin under microwave irradiation heating was investigated.The effect of montmorillonite content and stirring time on the structure and morphology of synthetic resin was analyzed.The optimum processing procedure was found to be 45 min stirring time with 5.4% montmorillonite addition.Further,the platelet spacing increases with stirring time till montmorillonite exfoliated to nanoscales platelet.When montmorillonite is exfoliated,layered structure at nanoscale can be uniformly distributed in the resin.The overall performance of montmorillonite modi fied phenolic resin is improved remarkably,such as flow ability,tensile strength and toughness property of resin coated sand.However,the gelation speed decreased slightly by adding montmorillonite.

Transient oxidation behavior of nanocrystalline CoCrAlY coating at 1050 ℃

Nanocrystalline CoCrAlY overlay coating was prepared on M38G superalloy by magnetron sputtering deposition. To investigate the oxidation behavior and phase transformation of alumina during oxidation, the oxidation experiments were conducted at 1 050 ℃ for various time in the range of 5?180 min. The phase compositions of the oxide scales were investigated by using glancing angle X-ray diffraction(XRD). The microstructure analysis of oxide scales was carried out by means of scanning electron microscopy(SEM). The growth process of metastable alumina at the grain boundaries and transformation to stable alumina were discussed. The results show that at the initial oxidation stage the mixture of δ-Al2O3, γ-Al2O3 and α-Al2O3 is formed on the sample surface rapidly. Especially, δ-Al2O3 and γ-Al2O3 prefer growing at the grain boundaries of CoCrAlY coating. With increasing oxidation time, δ-Al2O3 and γ-Al2O3 transform to θ-Al2O3, afterwards θ-Al2O3 transforms to α-Al2O3 gradually. After 180 min oxidation, θ-Al2O3 transforms into α-Al2O3 completely.

Evolution of Quantum State for Mesoscopic Circuits with Dissipation

Based on the maximum entropy principle, we present a density matrix of mesoscopic RLC circuit to make it possible to analyze the connection of the initial condition with temperature. Our results show that the quantum state evolution is closely related to the initial condition, and that the system evolves to generalized coherent state if it is in ground state initially, and evolves to squeezed state if it is in excited state initially.

Preparation and Methanol Decomposition Activity of RutheniumSupported Ce-Doped Mesoporous TiO_2 Oxide

Mesoporous TiO2-CeO2 mixed oxide(m-TiO2-CeO2) were synthesized using n-cetylpyridinium chloride (C16PyCl) as a structure-directing agent under the neutral conditions and room temperature. The synthesized mesoporous samples were characterized by FT-IR, XRD, and N2 adsorption BET methods. The incorporation of Ce3+ ions into the channel wall improves the stability of the mesoporous structure obviously. After ruthenium being loaded by the impregnating method, the Ru particle strongly interacts with the mesoporous mixed supports. Although a part of the particles are possible to block the support pores, the catalytic activity of ruthenium supported on the m-TiO2-CeO2 for methanol decomposition to carbon monoxide and hydrogen is significantly higher than that of ruthenium supported on m-TiO2. A synergistic effect between CeO2 and TiO2 was observed for promoting the catalytic properties of Ru.

Thermal stability of cold worked microstructure of MP159 alloy

In order to know the longest permissible thermal exposure time during which the cold worked (CW) microstructure would remain unchanged, the effect of the thermal exposure at temperatures ranging from 910?℃ to 1?070?℃ on the microstructure was investigated for MP159 alloy by optical microscopy and transmission electron microscopy (TEM). Such a study can provide guidance for determining reasonable hot forging parameters of fasteners. The results indicate that the intersecting network of fine platelets in CW microstructure are thermal stable when thermal exposure temperature does not exceed 920?℃. When thermal exposure temperature exceed 920?℃, the intersecting network of fine platelets will dissolve, but the thermal exposure temperature has the longest permissible thermal exposure time during which the intersecting network of fine platelets will not dissolve.

Effect of residual-stress on microyield behavior of Al alloy reinforced by SiC_p

Because of the difference in the coefficient of thermal expansion of Al alloy and SiC_p, the residual-stress generates during the process of fabricating Al alloy reinforced by SiC_p. The analyzing residual-stress quantitatively by XRD shows that residual-stress is essential character of Al alloy reinforced by SiC_p, and the residual-stress in Al alloy matrix is tensile stress. The residual-stress decreases along with lessening of SiC_p size, which shows better microyield behavior. In annealing, the residual-stress of LY12+150#SiC_p is lower than that of ZL101+150#SiC, thus it has better microyield behavior. The residual-stress of solution-aging is bigger than that of annealing. The microyield behavior is also explained from the parameter change of microstructure to microyield behavior. Space-group relative microdistortion of Al alloy reinforced decreases along with lessening of SiC_p size, which has good microyield behavior.

Mathematical model of determination of die bearing length in design of aluminum profile extrusion die

Based on the finite element simulation of profile extrusion process, the effect of local extrusion ratio, die bearing area and the distance between extrusion cylindrical center and local die orfice center on mental flow velocity was investigated. The laws of deformed metal flow on profile extrusion process were obtained. The smaller the local extrusion ratio, the faster the metal flow velocity; the smaller the area of die bearing, the faster the metal flow velocity; the smaller the distance of position of local die orifice(the closer the distance of position of local die orifice from extrusion cylindrical axis), the faster the metal flow velocity. The effect of main parameters of die structure on metal flow velocity was integrated and the mathematical model of determination of die bearing length in design of aluminum profile extrusion die was proposed. The calculated results with proposed model were well compared with the experimental results. The proposed model can be applied to determine die bearing length in design of aluminum profile extrusion die.

Fabrication of nano-crystalline W-Ni-Fe alloy with Mo and rare earth element additives

Three kinds of nano-crystalline high density alloys(86W-7Ni-3Fe-4Mo, 90W-4Ni-2Fe-4Mo and 90W4Ni-2Fe-3.8Mo-0.2RE) were fabricated by a technique combining lower temperature vacuum sintering with highenergy ball milling mechanical alloying. The crystalline size and microstructures of the specimens sintered at different sintering temperatures were examined by X-ray diffraction(XRD) and scanning electron microscope(SEM). The results show that the optimal sintering temperature of 86W-7Ni-3Fe-4Mo, 90W-4Ni-2Fe-4Mo and 90W-4Ni-2Fe3.8Mo-0.2RE alloys are 1 300 - 1 350 ℃. When they are sintered at 1 300 ℃ for 75 min, the hardness of three kinds of specimens can reach above HRC30, the relative density can reach above 96%,and 90W-4Ni-2Fe-3.8Mo-0.2RE alloy possesses the best integrated properties, its hardness is HRC35 and its relative density is 98%.

A New Method of Recognizing Polygons under Perspective Transformation

Existing methods for recognizing polygons can be improved. A new concept ＂homograph＂ and then a new method for recognizing polygons based on the principle of homograph are proposed. First, five topological characteristics and geometrical characteristics are introduced that are invariant to describe polygon under perspective transformation. Then, the new concept of homograph is defined in terms of five topological characteristics and geometrical characteristics. Based on this definition, a new algorithm is proposed for recognizing that two polygons are homograph. The topological structure is introduced to analyze homograph qualitatively and the algorithm is insensitive to noises; and the geometrical structure is introduced to analyze homograph quantitatively, thus the algorithms can show tiny differences between polygons. It can not only recognize the objects with different shapes but also distinguish between objects with same shape but with different sizes and scales. Comparing with other recognition algorithms, the algorithm presented showed apparent improvement. The effectiveness of the algorithm is demonstrated by experiments.

ELECTROCHEMICAL POLYMERIZATION OF 5-CYANOINDOLE IN MIXED ELECTROLYTES OF BORON TRIFLUORIDE DIETHYL ETHERATE AND DIETHYL ETHER

High quality poly（5-cyanoindole） （P5CI） films were electrosynthesized by direct anodic oxidation of 5-cyanoindole on stainless steel sheet in the mixed electrolytes of boron trifluoride diethyl etherate （BFEE） and diethyl ether （EE） （by volume 1：1） ＋ 0,05 mol L^-1 Bu4NBF4. The film formed can be peeled off the electrode into freestanding films, The addition of EE into BFEE can improve the solubility of monomer. P5CI films obtained from this medium showed excellent electrochemical behavior with conductivity of 10^-2 S cm^-1, Structural studies showed that the polymerization of 5-cyanoindole occurred at the 2,3 position. As-formed P5CI films were thoroughly soluble in strong polar organic solvent dimethyl sulfoxide （DMSO） while partly soluble in tetrahydrofuran （THF） or acetone. Fluorescence spectral studies indicated that P5CI was a good blue-ight emitter.

SECOND-ORDER MOMENT MODEL FOR DENSE TWO-PHASE TURBULENT FLOW OF BINGHAM FLUID WITH PARTICLES

The USM-θ model of Bingham fluid for dense two-phase turbulent flow was developed, which combines the second-order moment model for two-phase turbulence with the particle kinetic theory for the inter-particle collision. In this model, phases interaction and the extra term of Bingham fluid yield stress are taken into account. An algorithm for USM-θ model in dense two-phase flow was proposed, in which the influence of particle volume fraction is accounted for. This model was used to simulate turbulent flow of Bingham fluid single-phase and dense liquid-particle two-phase in pipe. It is shown USM-θ model has better prediction result than the five-equation model, in which the particle-particle collision is modeled by the particle kinetic theory, while the turbulence of both phase is simulated by the two-equation turbulence model. The USM-θ model was then used to simulate the dense two-phase turbulent up flow of Bingham fluid with particles. With the increasing of the yield stress, the velocities of Bingham and particle decrease near the pipe centre. Comparing the two-phase flow of Bingham-particle with that of liquid-particle, it is found the source term of yield stress has significant effect on flow.

ANALYSIS OF SIMPLE SHEAR ENDOCHRONIC EQUATIONSFOR FINITE PLASTIC DEFORMATION

Jaumann rate, generalized Jaumann rate,Fu rate and Wu rate were incorporated into endochronic equations for finite plastic deformation to analyze simple shear finite deformation. The results show that an oscillatory shear stress and normal stress response to a monotonically increasing shear strain occurs when Jaumann rate objective model is adopted for hypoelastic or endochronic materials. The oscillatory response is dependent on objective rate adopted,independent on elastoplastic models. Normal stress is unequal to zero during simple shear finite deformation.