Influence of high concentration Zn^(2+) on floatability of sphalerite in acidic system

The influence of high concentration Zn^(2+) on the floatability of sphalerite in an acidic system was investigated via flotation experiments,zeta potential measurements,contact angle measurements,and X-ray photoelectron spectroscopy.The results indicated that Zn^(2+) was adsorbed on the sphalerite surface and a Zn-hydroxyl complex was formed at a pH of 4 and a Zn^(2+) concentration of 4×10^(-2) mol/L.The zeta potential increased and the contact angle decreased from 84.80°to 36.48°,strongly inhibiting the floatability of sphalerite.When S^(2−) or Cu^(2+) activator was used alone,sphalerite was not activated after Zn^(2+) was adsorbed,and its contact angle did not change significantly.However,by using a combination of S^(2−) and Cu^(2+) activators,its floatability was realized after Zn^(2+) adsorption.This result was attributed to the removal of the Zn-hydroxyl complex on the surface of sphalerite by S^(2-).After this removal,Cu^(2+) was adsorbed on the sphalerite surface to form a Cu_(2)S·S^(0) hydrophobic film.

Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values（Ro） of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ^（13）C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.

Stress response characteristics of BFRP anchors on loess mudstone slope under rainfall conditions

To investigate the stress response characteristics and shear stress transfer mechanism of BFRP(basalt fiber reinforced plastics)anchors under rainfall conditions and to explore the reinforcement effect of BFRP anchors,a comparative indoor physical model test was conducted in this study using loess mudstone slope as a typical case,and multi-attribute response data,such as slope displacement,BFRP anchor strain and axial force,were obtained.Based on the variation law of slope displacement,it can be concluded that the deformation displacement of the slope on the side reinforced by BFRP anchors is smaller than that of slopes reinforced with steel anchors;the bearing capacity of BFRP anchor is given priority in time,and the anchoring effect of BFRP anchor at the top of the slope is given priority,and the axial force value of anchor is characterized by a surface amplification effect in space;the axial force is higher around the anchor head and tends to decay as a negative exponential function as the anchor extends in the direction of the interior of the slope;the shear stress of BFRP anchor and anchorage body are unevenly distributed along the axial direction,with the maximum value occurring in the free section near the slope surface and decreases as the BFRP anchor extends towards the interior of the slope.These results can provide a theoretical basis for the optimal design of BFRP anchors.

Method for determining the position of landslide slip-surface with a typical inclinometric curves

In the actual monitoring of deep hole displacement,the identification of slip surfaces is primarily based on abrupt changes observed in the inclinometric curve.In conventional identification methods,inclinometric curves exhibiting indications of sliding can be categorized into three types:B-type,D-type,and r-type.The position of the slip surface is typically determined by identifying the depth corresponding to the point of maximum displacement mutation.However,this method is sensitive to the interval of measurement points and the observation scale of the coordinate axes and suffers from unclear sliding surfaces and uncertain values.Based on the variation characteristics of these diagonal curves,we classified the landslide into three components:the sliding body,the sliding interval,and the immobile body.Moreover,three different generalization models were established to analyze the relationships between the curve form and the slip surface location based on different physical indicators such as displacement rate,relative displacement,and acceleration.The results show that the displacement rate curves of an r-type slope exhibit a clustering feature in the sliding interval,and by solving for the depth of discrete points within the step phase,it is possible to determine the location of the slip surface.On the other hand,D-type slopes have inflection points in the relative displacement curve located at the slip surface.The acceleration curves of B-type slopes exhibit clustering characteristics during the sliding interval,while the scattered acceleration data demonstrate wandering characteristics.Consequently,the slip surface location can be revealed by solving the depth corresponding to the maximum acceleration with cubic spline interpolation.The approach proposed in this paper was applied to the monitoring data of a landslide in Yunnan Province,China.The results indicate that our approach can accurately identify the slip surface location and enable computability of its position,thereby enhancing applicability and reliability of the deep-hole displacement monitoring data.

Shaking table test for reinforcement of soil slope with multiple sliding surfaces by reinforced double-row anti-slide piles

Despite the continuous advancements of engineering construction in high-intensity areas,many engineering landslides are still manufactured with huge thrust force,and double-row piles are effective to control such large landslides.In this study,large shaking table test were performed to test and obtain multi-attribute seismic data such as feature image,acceleration,and dynamic soil pressure.Through the feature image processing analysis,the deformation characteristics for the slope reinforced by double-row piles were revealed.By analyzing the acceleration and the dynamic soil pressure time domain,the spatial dynamic response characteristics were revealed.Using Fast Fourier Transform and half-power bandwidth,the damping ratio of acceleration and dynamic soil pressure was obtained.Following that,the Seism Signal was used to calculate the spectral displacement of the accelerations to obtain the regional differences of spectral displacement.The results showed that the overall deformation mechanism of the slope originates from tension failure in the soil mass.The platform at the back of the slope was caused by seismic subsidence,and the peak acceleration ratio was positively correlated with the relative pile heights.The dynamic soil pressure of the front row piles showed an inverted"K"-shaped distribution,but that of the back row piles showed an"S"-shaped distribution.The predominant frequency of acceleration was 2.16 Hz,and the main frequency band was 0.7-6.87 Hz;for dynamic soil pressure,the two parameters became 1.15 Hz and 0.5-6.59 Hz,respectively.In conclusion,dynamic soil pressure was more sensitive to dampening effects than acceleration.Besides,compared to acceleration,dynamic soil pressure exhibited larger loss factors and lower resonance peaks.Finally,back row pile heads were highly sensitive to spectral displacement compared to front row pile heads.These findings may be of reference value for future seismic designs of double-row piles.

Recent advances in high slope reinforcement in China: Case studies

This paper reviews a number of engineering technologies and workmanships for addressing the challenging issues concerning possible landslides in large-scale slope reinforcement projects in China.It includes:(1) the multi-point anchored piles with a depth of 64 m in the Jietai Temple rehabilitation project,(2) soil nailing strengthened by driven pipe grouting technique covering an area of530 m × 100 m(length × height) in the Xiluodu hydropower project,(3) the cantilever piles extending vertically from the slope toe to stabilize a 300 m high slope at the Xiaowan hydropower station,(4) a new and simple workmanship for building a pile with cross-sectional area of 20 m × 5 m in the Hongjiadu hydropower station,and(5) comprehensive reinforcement scheme proposed for excavation of a 530 m high slope in Jinping I hydropower station.These new technologies can provide valuable experiences for reinforcement of high slopes of similar projects in China and other regions and countries with similar geological conditions.

Effect of climate change and railway embankment on the degradation of underlain permafrost

Because of the global warming and the increasing human activity, the air temperature and the precipitation along the Qinghai-Tibet Railway increased gradually in recent years, which endanger the permafrost table, the embankment of the railway. The statistics of the air temperature, the precipitation and the geothermal temperature in recent 50 years in this dissertation come from the four weather station along the railway, that are Wudaoliang Station, Fenghuo Mountains Sta- tion, Tuotuo River Station and Ando Station. This dissertation analyzes the change of climate along the railway and then develops a research on the effect of the changing geothermal temperature on permafrost table and its countermeasures. The experiment result shows that the air temperature of the permafrost region rise steadily in about 50 years, especially in this century, the tendency of rising temperature is more obvious. The precipitation fluctuates but it is also rising rapidly, for the largest precipitation reached 492.6 mm. For 30 years now, the Qinghai-Tibet Plateau has been in the megathermal period, which also affects the permafrost region along the railway. The condition of permafrost is degrading greatly.

Application of a new basalt fiber-reinforced polymer anchorage structure in the tunnel–slope system under rainfall action

The application of basalt fiber-reinforced polymer(BFRP)anchors has gained significant attention,particularly in the field of geotechnical anchorage engineering because of its high strength and corrosion resistance.The research on the applicability of BFRP anchor in a tunnel–slope system under rainfall is of practical significance to solve the problem of instability damage to anchored slopes caused by corrosion of steel anchors.In this study,model tests of BFRP and steel anchorage structures were conducted to compare their reinforcement capability in a tunnel–slope system under heavy rainfall.The results show that the BFRP anchorage structure is better than the steel in coordinating slope deformation and stabilizing earth pressure around the tunnel.The deformation of slopes under rainfall is classified into four stages:initial,isokinetic,accelerated,and blocked deformations.BFRP anchors have the same axial strain distribution pattern as the steel anchors,and they are convexly distributed along the axial direction of the anchors.The correlation analysis and Pearson linear correlation analysis of the multi-attribute data of the slope and BFRP anchors showed a positive correlation among BFRP anchor strain,earth pressure inside the slope,slope deformation displacement,and accumulated rainfall.These research results provide a basis and reference for the application of BFRP anchors in the anchorage engineering of the tunnel–slope system under rainfall action.

A system for automated monitoring of embankment deformation along the Qinghai-Tibet Railway in permafrost regions

At present, the monitoring of embankment deformation in permafrost regions along the Qinghai-Tibet Railway is mainly done manually. However, the harsh climate on the plateau affects the results greatly by lowering the observation frequency, so the manual monitoring can barely meet the observational demand. This research develops a system of automated monitoring of embankment deformation, and aims to address the problems caused by the plateau climate and the perma- frost conditions in the region. The equipment consists of a monitoring module, a data collection module, a transmission module, and a data processing module. The field experiments during this program indicate that （1） the combined auto- mated monitoring device overcame the problems associated with the complicated and tough plateau environment by means of wireless transmission and automatic analysis of the embankment settlement data; （2） the calibration of the combined settlement gauge at -20 ℃ was highly accurate, with an error rate always 〈0.5%; （3） the gauge calibration at high-temperature conditions was also highly accurate, with an error rate 〈0.5% even though the surface of the instrument reached more than 50 ℃; and （4） compared with the data manually taken, the data automatically acquired during field monitoring experiments demonstrated that the combined settlement gauge and the automated monitoring system could meet the requirements of the monitoring mission in permafrost regions along the Qinghai-Tibet Railway.

Prevention and management of wind-blown sand damage along Qinghai-Tibet Railway in Cuonahu Lake area

This paper analyzes the characteristics of climate, geology and geomorphology, vegetation, and sand dune distribution in the Cuonahu Lake area beside the Qinghai-Tibet Railway. The types and causes of railway blown-sand hazards are discussed, and the effectiveness of various sand-controlling measures is assessed. From the perspective of integrated management, a sand-controlling system that combines several engineering measures, including nylon net sand barriers, concrete sand barriers, movable-board sand barriers, sand interception ditches, gravel/rock cover, film sandbags, and permanent vegetation is most beneficial.

Groundwater resources survey of tongchuan city using the audio magnetotelluric method

The development of Tongchuan City,Shaanxi Province,located in the northwestern region of China,is restricted by water resources.The direct current resistivity and induced polarization sounding methods are typically applied in finding urban groundwater.These methods,however,are not effective due to their complicated topography and geological conditions.The application practice shows that the audio magnetotelluric(AMT)method has a large depth of exploration,high work effi ciency,and high lateral resolution.To investigate the distribution of groundwater resources,we deployed three audio-frequency magnetotelluric profiles in the city area.The impedance tensor information of AMT data is obtained using SSMT2000.AMT data dimension analysis reveals that the two-dimensional structural features of the observation area are obvious.The main structure of the observation area is about 45°northeast,as indicated by structural trend analysis.A shallow two-dimensional electrical profile of 1 km in Tongchuan City is obtained by two-dimensional nonlinear conjugate gradient inversion.Finally,combined with regional geological information,the geological structure characteristics reflected by the electrical profile were obtained along with the detailed characteristics of water-rich structures in the area.The infl uence of the structure on the groundwater distribution was analyzed,and the water-rich areas were identifi ed.This work contributes to the prospective development of Tongchuan City.

Energy‐based analysis of seismic damage mechanism of multi‐anchor piles in tunnel crossing landslide area

To study the damage mechanism of multi‐anchor piles in tunnel crossing landslide area under earthquake,the damping performance of multi‐anchor piles was discussed.The energy dissipation springs were used as the optimization device of the anchor head to carry out the shaking table comparison test on the reinforced slope.The Hilbert spectrum and Hilbert marginal spectrum were proposed to analyze the seismic damage mechanism of the multi‐anchor piles,and the peak Fourier spectrum amplitude(PFSA)was used to verify the effectiveness of the method.The results show that the seismic energy is concentrated in the high‐frequency component(30-40Hz)of the Hilbert spectrum and the low‐frequency component(12-30 Hz)of the marginal spectrum.This indicates that they can be combined with the distribution law of the PFSA to identify the overall and local dynamic responses of the multi‐anchored piles,respectively.The stretchable deformation of the energy‐dissipation springs improves the coordination of the multi‐anchor piles,resulting in better pile integrity.The damage mechanism of the multi‐anchor piles is elucidated based on the energy method:local damage at the top and middle areas of the multi‐anchor piles is mainly caused by the low‐frequency component(12-30 Hz)of the marginal spectrum under the action of 0.15g and 0.20g seismic intensities.As the seismic intensity increases to 0.30g,the dynamic response of the slope is further amplified by the high‐frequency component(30-40 Hz)of the Hilbert energy spectrum,which leads to the overall damage of the multi‐anchor piles.

Effect of Sulfurization Temperature on Thioetherification Performance of Mo-Ni/Al_2O_3 Catalyst

The Mo modified Ni/Al_2O_3 catalysts were prepared and sulfided at different temperatures, and their catalytic activity for thioetherification of mercaptans and olefins(or dienes), hydrogenation of dienes and olefins in the thioetherification process using fluidized catalytic cracking(FCC) naphtha as the feedstock was investigated. In order to disclose the correlation between the physicochemical characteristics of catalysts and their catalytic activity, the surface structures and properties of the catalysts sulfided at different temperatures were characterized by the high resolution transmission electronic microscopy(HRTEM), X-ray photoelectron spectroscopy(XPS) and H2-temperature programmed reduction(H_2-TPR) technique. The results showed that an increase of sulfurization temperature not only could promote the sulfurization degree of active metals on the catalysts, but also could adjust the micro-morphology of active species. These changes could improve the catalytic performance of thioetherification, and hydrogenation of dienes and olefins. However, an excess sulfurization temperature was more easily to upgrade the ability of the catalyst for hydrogenation of olefins, which could lead to a decrease of the octane number of the product. It was also showed that a moderate sulfurization temperature not only could improve the catalytic performance of thioetherification and hydrogenation of dienes but also could control hydrogenation of olefins.

Dynamic analysis on methanation reactor using a double-input–multi-output linearized model

A double-input–multi-output linearized system is developed using the state-space method for dynamic analysis of methanation process of coke oven gas.The stability of reactor alone and reactor with feed-effluent heat exchanger is compared through the dominant poles of the system transfer functions.With single or double disturbance of temperature and CO concentration at the reactor inlet,typical dynamic behavior in the reactor,including fast concentration response,slow temperature response and inverse response,is revealed for further understanding of the counteraction and synergy effects caused by simultaneous variation of concentration and temperature.Analysis results show that the stability of the reactor loop is more sensitive than that of reactor alone due to the positive heat feedback.Remarkably,with the decrease of heat exchange efficiency,the reactor system may display limit cycle behavior for a pair of complex conjugate poles across the imaginary axis.

Shaking table test and cumulative deformation evaluation analysis of a tunnel across the hauling sliding surface

To explore the cumulative deformation effect of the dynamic response of a tunnel crossing the hauling sliding surface under earthquakes,the shaking table test was conducted in this study.Combined with the numerical calculations,this study proposed magnification of the Arias intensity(MIa)to characterize the overall local deformation damage of the tunnel lining in terms of the deformation characteristics,frequency domain,and energy.Using the time‐domain analysis method,the plastic effect coefficient(PEC)was proposed to characterize the degree of plastic deformation,and the applicability of the seismic cumulative failure effect(SCFE)was discussed.The results show that the low‐frequency component(f1 and f2≤10 Hz)and the high‐frequency component(f3 and f4>10 Hz)acceleration mainly cause global and local deformation of the tunnel lining.The local deformation caused by the high‐frequency wave has an important effect on the seismic damage of the lining.The physical meaning of PEC is more clearly defined than that of the residual strain,and the SCFE of the tunnel lining can also be defined.The SCFE of the tunnel lining includes the elastic deformation effect stage(<0.15g),the elastic–plastic deformation effect stage(0.15g–0.30g),and the plastic deformation effect stage(0.30g–0.40g).This study can provide valuable theoretical and technical support for the construction of traffic tunnels in high‐intensity earthquake areas.

Super-resolution amplification of bitmap images based on 3D modeling theory

As a general format of the image,bitmap(BMP)image has wide applications,and consequently it is an important part of image processing.By segmenting the bitmap and combining the three-dimesional(3D)model of the discrete algorithm with the scanning line compensation algorithm,a mathematical model is built.According to the topological relations between several control points on the model surface,the surface of the model is discretized,and a planar triangle sequence is used to describe 3D objects.Finally,the bitmap is enlarged by combining the borrowing compensation based on 3D modeling principle of discrete algorithm with the scanning line compensation algorithm of binary lattice image,thus getting a relatively clear enlarged BMP image.

Response of Grassland Biomass to Soil Moisture in the Arid Mountainous Area of the Qilian Mountains

The Pailugou watershed of the Qilian Mountains in the arid region of northeast China was selected for research to analyze the species, height, and biomass in typical mountain grassland with an altitude of 2,700–3,000 m and measure soil moisture, so as to explore the seasonal characteristics of grassland biomass as altitude increases and the relationship between grassland biomass and soil moisture. The results showed that:(1) with a mean value of 135.36 g/m^2, grassland aboveground biomass showed a unimodal distribution from rise to decline as altitude increased, and reached its maximum of 176.79 ± 28.37 g/m^2 at an altitude of 2,900 m; with a mean value of 946.13 g/m^2, grassland underground biomass showed an uptrend as altitude increased, and reached its maximum of 1,301.19 ± 68.24 g/m^2 at an altitude of 3,000 m;(2) the difference between aboveground biomass and underground biomass in the grassland at different altitudes was significant;(3) values of root shoot ratio of the arid mountain grassland varied between 4.14–11.95;(4) values of soil moisture content of the arid mountain grassland varied between 9.23%–31.31%;(5) there was a positive correlation between aboveground biomass and underground biomass and the mean soil moisture content(p < 0.05), with a correlation coefficient of 0.778 4 and 0.784 3 respectively, soil layers with different moisture content made different contributions to grassland biomass, and moisture content in the soil layer where over-60-cm root systems were located was of significance to grassland biomass.

Investigation and Analysis on New Harmful Features Related to Frozen Ground in Permafrost Regions in Qinghai-Tibet Railway

At first, the forming conditions and developing characteristics of several kinds of typical harmful features related to frozen ground are discussed in the paper, such as flooding ice, icing mound, frost mound, thick ground ice, thaw slumping, thermokarst lake and swampland. Secondly, the investigating results of new harmful permafrost features in winter along Qinghai-Tibet Railway are analysed and summarized. Lastly, some data and suggestions will be provided to designing and construction departments.

Discussion on Theoretical Analysis and Calculation of Settlement and Cracking in Subgrade in Permafrost of the Qinghai-Tibet Plateau

This paper carries on the theoretical analysis on characteristic of settlement and cracking in subgrade in permafrost of the Qinghai-Tibet Plateau, proposed mechanism of settlement and cracking in subgrade in permafrost on the Qinghai-Tibet Railway. Based on the slices divide of section of subgrade, proposes that it is rotated according to artificial permafrost table, and then the cracking of thaw settlement is calculated. Based on the theoretical of V.A. Kudriavtsev about permafrost, calculated distance of frost crack in subgrade. Aim at characteristics of settlement and cracking in subgrade in permafrost of the plateau the principle of unequal migration of unfrozen water and deformation caused by thermo sieve effect is firstly used. Considering the relationship between deformation and time, the theoretical mode of calculating cracking is in the paper.