Dilute long period stacking/order(LPSO)-variant phases along the composition gradient in a Mg-Ho-Cu alloy

We have systematically investigated the microstructures of as-cast Mg_(97.49)Ho_(1.99)Cu_(0.43)Zr_(0.09)alloy by atomic resolution high-angle annular dark field scanning transmission electron microscopy(HAADF-STEM), revealing the coexistence of 18R, 14H and 24R long period stacking/order(LPSO) phases with fully coherent interfaces along step-like composition gradient in a blocky intermetallic compound distributed at grain boundary. The short-range order(SRO) L1_(2)-type Cu_(6)Ho_(8)clusters embedded across AB’C’A-stacking fault layers are directly revealed at atomic scale. Importantly, the order degree of SRO clusters in the present dilute alloy is significant lower than previous 6M and 7M in-plane order reported in ternary Mg-TM(transition metal)-RE(rare earth) alloys, which can be well matched by 9M in-plane order. This directly demonstrates that SRO in-plane L1_(2)-type clusters can be expanded into more dilute composition regions bounded along the definite TM/RE ratio of 3/4. In addition, the estimated chemical compositions of solute enriched stacking fault(SESF) in all LPSO variants are almost identical with the ideal SESF composition of 9M in-plane order, regardless of the type of LPSO phases. The results further support the viewpoint that robust L1_(2)-type TM_(6)RE_(8)clusters play an important role in governing LPSO phase formation.

Microstructures and mechanical properties of as-cast Mg-Sm-Zn-Zr alloys with varying Gd contents

The effect of Gd content on the microstructure and tensile properties of as-cast Mg-Sm-Zn-Zr alloy has been systematically investigated.In the Mg-3Sm-0.5Zn-0.5Zr alloy, the intermetallic compounds with multiple morphologies are identified as Mg_(3)Sm phase. In addition to Mg_(3)RE phase, Mg_(5)RE phase originated from Gd addition is observed in Gd-modified alloys. It should be noted that the lattice parameters of all the observed intermetallic compounds are significantly reduced by Zn segregation. The segregation behavior of Zn in Mg_(3)Sm phase is inhibited to some extent by Gd addition due to the electronegativity difference between Sm/Gd and Zn elements. In addition, the increased Gd content effectively leads to much more accumulation of solute atoms in front of the liquid-solid interface during solidification, which can prominently promote nucleation in liquid region and then refine grains. The tensile yield stress of the present alloys is thus improved with increasing Gd addition. Finally, Gd-modified alloys exhibit significantly age-hardening effect, which can be mainly attributed to the high-volume fraction and high density nano-scale precipitates.

Transverse Compressive Properties of Carbon/Glass Hybrid Thermoplastic Composite Rods

Novel carbon/glass hybrid thermoplastic composite rods having different carbon/glass ratios (24K1P,24K2P,and 24K3P) are commercially fabricated.The transverse compressive properties of these three hybrid rods were investigated.The load-displacement curve showed large nonlinear behavior and a complicated shape.In the initial stage,the load gradually increased by increasing the deformation.In the second stage,the load-displacement relation was almost linearly proportional to the displacement (stable deformation region).Subsequently,the slope decreased slightly,before the load-displacement curve showed a clear slope increase as the deformation proceeded.The fracture behavior of the hybrid rods was examined using a digital microscope.The observed fracture paths formed almost straight lines running through the loading point,the center of the cross section of carbon fiber bundles/thermoplastic epoxy,as well as the interface between the glass fiber bundles/thermoplastic epoxy and the carbon fiber bundles/thermoplastic epoxy.

In-Situ Corrosion Monitoring of Scratched Epoxy Coated Carbon Steel in Saturated Ca(OH)2 with or without 3% NaCl by Scanning Electrochemical Microscopy and Electrochemical Impedance Spectroscopy

The present work is investigated the in-situ monitoring of local corrosion process of scratched epoxy coated carbon steel in saturated Ca(OH)2 with and without 3% NaCl using SECM and correlated with EIS. The results obtained from EIS analysis showed that the corrosion resistance of scratched epoxy coated carbon steel decreases in Cl- containing solution as the increase in wet/ dry corrosion cycles. This was indicated by decrease in film resistance (Rf) and charge transfer resistance (Rct), while the coated steel maintain the resistance values in saturated Ca(OH)2, most of which recovered after drying. The corrosion process was monitored using SECM by setting the tip potential at -0.70 V vs Ag/AgCl, where the consumption of dissolved oxygen occurred at the surface of test sample. The consumption of dissolved oxygen current (I’oxy-c) values was increased during the immersion in a solution with 3% NaCl. However, in wet/dry corrosion cycles, I’oxy-c was decreased due to the coverage of hydroxides/oxides at scratch area which suppressed the consumption of dissolved O2. It was found that the continuous decrease in corrosion was mainly attributed to continuous formation of corrosion products at anodic spots.

{332}<113>孪晶与等温ω相的组合对不同O含量Ti-15Mo合金力学性能的影响

利用OM、XRD、TEM、DSC、Vickers硬度计和拉伸试验机等研究了拉伸预变形诱发{332}<113>孪晶与随后时效析出等温w相对不同O含量(0.1%~0.5%,质量分数)β型Ti-15Mo合金力学性能的影响。结果表明,随着合金中O含量的增加,机械孪晶的形成以及等温w相的析出受到了抑制,且拉伸预变形诱发孪晶对等温w相析出的影响较小。经拉伸预变形和随后时效处理,低O含量合金呈现出较高的屈服强度和较好的均匀伸长率,而高O含量合金发生脆性断裂。孪生与位错滑移的耦合塑性变形使得低O含量合金呈现出良好的强度和塑性匹配,其高的屈服强度主要受位错滑移主导,良好的均匀伸长率主要归因于预变形诱发孪晶的静态晶粒细化以及后续孪生变形导致的动态晶粒细化效应。这些结果表明,通过对合金元素O的有效利用,以及合理的预变形与热处理制度,能够改变塑性变形方式和相析出行为,从而在较大范围内调控β型钛合金的强度和塑性匹配。

Effect of Pre-cold Rolling-Induced Twins and Subsequent Precipitated x-Phase on Mechanical Properties in a β-Type Ti–Mo Alloy

This paper reported an effectiveness of pre-cold rolling-induced{332}／113[twins combined with subsequent isothermal x-phase formation for enhancement of uniform elongation in a b-type Ti–15Mo alloy with high yield strength level.Mechanical{332}／113[twins were induced by cold rolling with an thickness reduction of 5%,which had little effect on x-phase precipitation after aging at 573 K for 3.6 ks.Twinning after the cold rolling was further activated during tensile deformation,even with the presence of isothermal x-phase.This combination of twins and x-phase enhanced uniform elongation from 0 to 9%at yield strength level of 890 MPa.The high yield strength was mainly dominated by dislocation slip due to the isothermal x-phase formation,and early onset of plastic instability after yielding was hindered due to the pre-cold rolling-induced twins.Dynamic microstructural refinement was induced by further twinning activation during deformation,which resulted in high work hardening rate corresponding enhancement of uniform elongation.

Mechanical properties of Fe-rich Si alloy from Hamiltonian

The physical origins of the mechanical properties of Fe-rich Si alloys are investigated by combining electronic structure calculations with statistical mechanics means such as the cluster variation method,molecular dynamics simulation,etc,applied to homogeneous and heterogeneous systems.Firstly,we examined the elastic properties based on electronic structure calculations in a homogeneous system and attributed the physical origin of the loss of ductility with increasing Si content to the combined effects of magneto-volume and D03 ordering.As a typical example of a heterogeneity forming a microstructure,we focus on grain boundaries,and segregation behavior of Si atoms is studied through high-precision electronic structure calculations.Two kinds of segregation sites are identified:looser and tighter sites.Depending on the site,different segregation mechanisms are revealed.Finally,the dislocation behavior in the Fe-Si alloy is investigated mainly by molecular dynamics simulations combined with electronic structure calculations.The solid-solution hardening and softening are interpreted in terms of two kinds of energy barriers for kink nucleation and migration on a screw dislocation line.Furthermore,the clue to the peculiar work hardening behavior is discussed based on kinetic Monte Carlo simulations by focusing on the preferential selection of slip planes triggered by kink nucleation.