Characterization of bio-coal briquettes blended from low quality coal and biomass waste treated by Garant■bio-activator and its application for fuel combustion

Experimental research was carried out on the manufacturing of bio-coal briquettes from a blend of two different types of low-quality coal and biomass waste in the absence of coal carbonization,where the third blend of the material was fermented by adding a bio-activator solution before pressurizing the components into briquettes.The coal samples from Caringin-Garut Regency(BB-Garut)had a low calorific value and a high sulfur content(6.57 wt%),whereas the coal samples from Bayah-Lebak Regency(BB-Bayah)had a higher calorific value and a lower sulfur content(0.51 wt%).The biomass added to the coal blend is in the form of fermented cow dung(Bio-Kohe),and it had a calorific value of 4192 kcal/kg and a total sulfur content of 1.56 wt%.The main objective of this study is to determine the total decrease in the sulfur content in a blend of coal and biomass in which a fennentation process was carried out using a bio-activator for 24 h.The used bio-activator was made from Garant■(1:40)+molasses 1 wt%/vol,and its used amount was 0.2 L/kg.Also,the total sulfur content in the blend was 1.00 wt%-1.14 wt%,which fulfills the necessary quality requirements for non-carbonized bio-coal briquettes.The pyritic and sulfate content in the raw coal was dominant,and the organic sulfur,when fermented with Garant■,was found to be less in the produced bio-coal briquettes by 38%-58%.

Surface physicochemical properties of semi-anthracitic coal from Painan-Sumatra during air oxidation

Painan coals of West Sumatra were selected as semi-anthracitic coal sample for studying the physicochemical properties such as measurement, evaluation and description of the changes of surface characteristic of coal sample and their oxidation in the atmospheric air at a temperature ranging from 105 to 400 ℃ for 30 min. Several methods are adopted to analyze and discuss several phenomena of the oxidized Painan coal surface during oxidation process for the change in the physicochemical properties as determined by Atomic Force Microscope （AFM）, contact angle, Fourier Transform Infrared Spectroscopy （FTIR）, Thermogravimetric and Differential Thermal Analysis （TG-DTA） analyses as well as other supporting analytical equipment. AFM analyses revealed some changes in adhesion force and surface morphology with more adhesion force available between 0.6 and 8.6 nN on polished coal surfaces due to the increased oxidation temperature. The study revealed that the extent of hydrophobicity of coal surface decreased with the increased of oxidation temperature expressed as contact angles at about 80° and 20°. Another phenomenon occurred during the experiment was hydrophilicity index of coal surface increase at approximately 1.3 and 2.9. Oxidation of coal that occurred with increased temperature also indicated an increase in oxygen content from 3.8% to 22.9 wt%. Increased oxygen functional group also noted that oxidation of coal took place during the treatment. We also found that oxidation treatment also affected the combustion properties of coal： decreasing ignition temperature between 452.9 and 317.6, lowering the reactivity of coal at maximum combustion rate temperature, and reflecting their char characteristics as burnt out, ranging from 652.3 to 648.5 ℃.

Imaging Rock Density Distribution beneath Liwa Fracture Zone in the Southern Part of the Great Sumatran Fault System, Indonesia

We have imaged rock density distribution beneath Liwa fracture zone in the southern part of the the Sumatran Fault Zone by modelling and inverting Bouguer gravity data in two-and three-dimensional environments, respectively. The purpose of this study is aimed to figure out the subsurface distribution of rock densities associated with subsurface basement structure representing the evidence of trans-tensional tectonic product in the SF. In the gravity modeling, to eliminate distortions to the measured gravity values before modelling and inverting the data, Bouguer anomalies obtained in field measurements are reduced to the horizontal plane of z = +800 m as a representation of the average elevation in Liwa. For the inversion, we used algorithm implementing depth-and minimum volume weighting parameters in order to obtain a smooth model with better vertical resolution. The two-dimensional models show clearly surface topography of the basement rocks and the presence of normal faults. The reduced Bouguer anomaly of +800 m elevation shows the presence of structural lineaments extending primarily in a northwest-southeast direction, parallel to Sumatran Fault Zone and older graben faults showing a negative flower structure. From the three-dimensional inversion, the model illustrates an increase of density contrast, lower values being found near the surface and higher values in the deeper parts. The lower density contrast of 0.15 to 0.3 g/cm3 found in the rock groups at depths of 2 km and less is characteristic of relatively homogeneous and poorly compacted rocks. Rocks with moderate to high density contrast (>1.0 g/cm3) are recognized at depths of over 2 km. This model suggests a change of basement morphology as a function of depth, and delineates structural lineaments extending in northwest-southeast direction. This study supports the previous thought that Liwa area is underlain by graben structures, formed by trans-tensional tectonic events. Higher-density Tertiary volcanic breccia and lower-density Quaternary volcanic products of the Ranau Formation form the basement rocks and the overlying younger sediments, respectively.