Research on Remote Fault Detection System of Ceramic Kiln Based on 5G and IoT Technologies

In order to overcome the defects of the existing technology that the detection of ceramic electric kiln faults takes a long time and costs a lot,an electric kiln control and fault detection device was designed.The working process of the device includes detection module,control module,start⁃stop module and switch module.The detection module detects the resistance circuit and sends a fault signal to the control module.The control module generates stop signal and fault information according to the fault signal,and starts the electric kiln when the fault signal is not received within the preset time.The start⁃stop module can monitor the internal temperature of the electric kiln and control the closing status of the switch module.The switch module is used to control the connection status of AC power and each resistance circuit in the kiln.Based on the 5G DTU or 5G module,the control module could send the information to mobile terminal under the ultra⁃reliable and low⁃latency communication(uRLLC)technical characteristics of 5G communication.

Coagulation behavior of polyaluminum chloride: Effects of pH and coagulant dosage

Coagulation mechanisms of polyaluminum chloride(PACl) at various dosages were studied using a conventional jar test at different final and initial pH values during treating kaolin suspension. The optimal final pH and dosages for PACl were obtained based on residual turbidity and zeta potential of flocs. The coagulation zones at various PACl dosages and solution p H values were developed and compared with those of alum. It is found that the optimal mechanism under acidic condition is charge neutralization, while alkaline condition will facilitate the coagulation of PACl. Both charge neutralization coagulation and sweep coagulation can achieve high coagulation efficiency under the alkaline condition ranging from final p H 7.0 to 10.0. Stabilization, charge neutralization destabilization, restabilization and sweep zones occur successively with increasing PACl dosages with the final p H values fixed at 7.0 and 8.0, but restabilization zone disappears at final p H 10.0. When the final p H is not controlled and consequently decreases with increasing PACl dosage, no typical sweep zone can be observed and the coagulant efficiency decreases at high PACl dosage. It seems that the final pH is more meaningful than the initial p H for coagulation. Charge neutralization coagulation efficiency is dominated by zeta potential of flocs and PACl precipitates. The charge neutralization and sweep coagulation zones of PACl are broader in the ranges of coagulant dosage and p H than those of alum. The results are helpful for us to treat water and wastewater using PACl and to understand the coagulation process of PACl.

Effects of Slow-Mixing on the Coagulation Performance of Polyaluminum Chloride （PACI）

Conventional jar tests and on-line size monitoring were used to investigate the effects of slow-mixing intensity and duration on residual turbidity and floc size during charge neutralization coagulation and sweep floc- culation with polyaluminum chloride. The compensatory effect of slow-mixing on coagulation performance fol- low!ng inadequate_or excessive rapid-mi_xing was also examined. It is found that slowTmixing intensity has a more marked positive ettect on charge neutralization coas;ulatlon tlaan on sweep tlocculatlon. llle optimal root-mean- square velocity gradient, G, for slow-mixing is 15 s-＇ for both coagulation mechanisms, and charge neutralization coagulation requires a longer slow-mixing duration. The optimal slow-mixing duration, based on residual turbidity,is longer than the time to tbrm the largest mean Ilocs. The optimal product of G and mixing duration, GT, lbr slow-mixing during charge neutralization coagulation （13500） are higher than that during sweep flocculation （4500） and both are less than the range of values recommended by the American Water Works Association （24000-84000）.The optimal GT value under various slow-mixing conditions increases with G. Appropriate extension＇of slow-mixing duration during charge neutralization coagulation can improve coagulation performance after an inadequate or excessive rapid-mixing duration, but during sweep flocculation, appropriate shortening of slow-mixing duration after an excessive rapid-mixing or appropriate extension of slow-mixing duration after an inadequate rapid-mixing is favorable.

Ecologically based landscape pattern optimization in northwest of Beijing

Supported by the technologies of remote sensing(RS) and geographical informa-tion system(GIS),we chose northwest of Beijing as a study area and gave priority to under-standing of the spatial-temporal characteristics of landscape pattern change through visually interpreted Landsat TM images of 1989,1996 and 2005.It is believed that there were a series of landscape ecological problems caused by city expansion:landscape ecological connec-tivity was low;landscape structure was simplified;the fragmentation of green land patch was more obvious on the plain areas,moreover,spatial distribution of green land was unbalanced.For this reason,this study adopted accumulative cost distance model,combined with eco-system services and spatial interactions of landscape types,analyzed the spatial difference of the ecological function and the compactness of landscape structure in the study area,and further discussed the landscape pattern optimization proposal.We find that it is essential to protect and establish ecological sources,to establish urban ecological corridors,and to es-tablish ecological nodes at the landscape ecological strategic positions so as to intensify spatial relationships among landscape elements and maintain continuity of landscape eco-logical process and pattern in the course of city expansion.The methods and final results from this study are expected to be useful for landscape ecological planning in Beijing region.

Occurrence Regularity and Green Prevention and Control Technology of Bradysia odoriphaga in Shandong Province

The occurrence regularity,damage characteristics and difficulties in prevention and control of Bradysia odoriphaga in Shandong Province were elaborated,and effective,economic,no residue,simple and feasible green prevention and control technology were put forward,in order to better guide the Chinese chive production.The study would also promote benign development of Chinese chive industry in Shandong Province.

Rigid Subchain Detection Algorithm of Mechanism Kinematic Chain and Realization of Recursive Program

In the process of kinematic chain type synthesis,it is necessary to solve the problems of isomorphism identification and rigid subchain detection.The problem of rigid subchain detection can be reduced to subgraph isomorphism problem,which belongs to NPC problem.This paper introduces the properties,detection methods,algorithm time complexity and program code of rigid subchain of kinematic chain.The detection codes of rigid subchains with different number of links are different.It is necessary to modify the for-loop nesting times of program code according to the change of the link number,so the code reusability is very low.In view of this,the recursive pseudo code of rigid subchain detection algorithm is proposed for the first time,which makes the program can be directly used for rigid subchain detection of any number of links,improves the reusability of the code,and provides a certain reference for the realization and optimization of computer programs for NPC problems in other disciplines.A rigid subchain detection software of kinematic chain was developed,and the rigid subchain detection process of a 16-link kinematic chain was successfully realized in the software.

Design of Remote Monitoring System for Ceramic Electric Kiln

In order to improve the management and control requirements of small electric kilns in ceramic production field.According to the excessive dispersion of electric kilns in porcelain production field,a remote monitoring system based on RS485 bus and Modbus protocol is designed.The system consists of data acquisition,field control,cloud monitoring and communication protocol.MCGS is used as the master station to communicate with the temperature controller,collect and transmit the internal data to Siemens PLC.Through the communication between Siemens PLC and IOT gateway,the kiln working data is uploaded to the cloud platform to realize the remote monitoring for ceramic electric kiln.The experimental results showed this system can accurately collect the working temperature and parameters of the kiln in real time,and can remotely cortrol the kiln.

Scenario analysis on abating industrial process greenhouse gas emissions from adipic acid production in China

Adipic acid is an important petrochemical product,and its production process emits a high concentration of greenhouse gas N_2 O.This paper aims to provide quantitative references for relevant authorities to formulate greenhouse gas control roadmaps.The forecasting method of this paper is consistent with the published national inventory in terms of caliber.Based on the N_2 O abatement technical parameters of adipic acid and the production trend,this paper combines the scenario analysis and provides a measurement of comprehensive N_2 O abatement effect of the entire industry in China.Four future scenarios are assumed.The baseline scenario(BAUS) is a frozen scenario.Three emission abatement scenarios(ANAS,SNAS,and ENAS) are assumed under different strength of abatement driving parameters.The results show that China's adipic acid production process can achieve increasingly significant N_2 O emission abatement effects.Compared to the baseline scenario,by 2030,the N_2 O emission abatements of the three emission abatement scenarios can reach 207-399 kt and the emission abatement ratios can reach 32.5%-62.6%.By 2050,the N_2 O emission abatements for the three emission abatement scenarios can reach 387-540 kt and the emission abatement ratios can reach 71.4%-99.6%.

Non-conjugated polymers as thickness-insensitive electron transport materials in high-performance inverted organic solar cells

Two non-conjugated polymers PEIE-DBO and PEIE-DCO, prepared by quaternization of polyethyleneimine ethoxylate by 1,8-dibromooctane and 1,8-dichlorooctane respectively, are developed as electron transport layer(ETL) in high-performance inverted organic solar cells(OSCs), and the effects of halide ions on polymeric photoelectric performance are fully investigated. PEIE-DBO possesses higher electron mobility(3.68×10-4 cm2 V-1s-1), higher conductivity and more efficient exciton dissociation and electron extraction, attributed to its lower work function(3.94 eV) than that of PEIE-DCO, which results in better photovoltaic performance in OSCs. The inverted OSCs with PTB7-Th: PC71BM as photoactive layer and PEIE-DBO as ETL exhibit higher PCE of 10.52%, 9.45% and 9.09% at the thickness of 9, 35 and 50 nm,respectively. To our knowledge, PEIE-DBO possesses the best thickness-insensitive performance in polymeric ETLs of inverted fullerene-based OSCs. Furthermore, PEIE-DBO was used to fabricate the inverted non-fullerene OSCs(PM6:Y6) and obtained a high PCE of 15.74%, which indicates that PEIE-DBO is effective both in fullerene-based OSCs and fullerene-free OSCs.

Development of a model to simulate soil heavy metals lateral migration quantity based on SWAT in Huanjiang watershed,China

Lateral transportation of soil heavy metals in rainfall events could significantly increase the scope of pollution. Therefore, it is necessary to develop a model with high accuracy to simulate the migration quantity of heavy metals. A model for heavy metal migration simulation was developed based on the SWAT(Soil and Water Assessment Tool) model. This model took into consideration the influence of soil p H value, soil particle size, runoff volume, sediment amount,concentration of water-soluble heavy metals dissolved in runoff and insoluble absorbed to the soil particles. This model was reasonable in Huanjiang watershed, Guangxi Zhuang Autonomous Region, south China, covering an area of 273 km^2. The optimal drainage area threshold was determined by analyzing the effects of watershed subdivision on the simulation results to ensure the simulation accuracy. The main conclusions of this paper were:(1) watershed subdivision could affect simulation migration quantity of heavy metals;(2) the quantity of heavy metals transported by sediment accounted for 97%–99% of the total migration quantity in the study watershed. Therefore, sediment played the most important role in heavy metal migration;(3) the optimal drainage area threshold percentage to ensure high simulation accuracy was determined to be 2.01% of the total watershed;(4) with the optimal threshold percentage, this model could simulate the migration quantity of As, Pb and Cd accurately at the total watershed and subwatershed level. The results of this paper were useful for identifying the key regions with heavy metal migration.

Screening and degrading characteristics and community structure of a high molecular weight polycyclic aromatic hydrocarbon-degrading bacterial consortium from contaminated soil

Inoculation with efficient microbes had been proved to be the most important way for the bioremediation of polluted environments. For the treatment of abandoned site of Beijing Coking Chemical Plant contaminated with high level of high-molecular-weight polycyclic aromatic hydrocarbons （HMW-PAHs）, a bacterial consortium capable of degrading HMW-PAHs, designated 1-18-1, was enriched and screened from HMW-PAHs contaminated soil. Its degrading ability was analyzed by high performance liquid chromatography （HPLC）, and the community structure was investigated by construction and analyses of the 16S rRNA gene clone libraries （A, B and F） at different transfers. The results indicated that 1-18-1 was able to utilize pyrene, fluoranthene and benzo[a]pyrene as sole carbon and energy source for growth. The degradation rate of pyrene and fluoranthene reached 82.8% and 96.2% after incubation for 8 days at 30℃, respectively; while the degradation rate of benzo[a]pyrene was only 65.1% after incubation for 28 days at 30℃. Totally, 108, 100 and 100 valid clones were randomly selected and sequenced from the libraries A, B, and E Phylogenetic analyses showed that all the clones could be divided into 5 groups, Bacteroidetes, ct-Proteobacteria, Actinobacteria, β-Proteobacteda and γ- Proteobacteria. Sequence similarity analyses showed total 39 operational taxonomic units （OTUs） in the libraries. The predominant bacterial groups were α-Proteobacteria （19 OTUs, 48.7%）, γ-Proteobacteria （90TUs, 23.1%） and β-Proteobacteria （80TUs, 20.5%）. During the transfer process, the proportions of α-Proteobacteria and β-Proteobacteria increased greatly （from 47% to 93%）, while γ-Proteobacteda decreased from 32% （library A） to 6% （library F）; and Bacteroidetes group disappeared in libraries B and F.

Distribution of methylsiloxanes in benthic mollusks from the Chinese Bohai Sea

Methylsiloxanes are a class of silicone compounds that have been widely used in various industrial processes and personal care products for several decades. This study investigated the spatial distribution of three cyclic methylsiloxanes(D4–D6) and twelve linear methylsiloxanes(L5–L16) in mollusks collected from seven cities along the Bohai Sea. D4–D6(df = 71%–81%) and L8–L16(df = 32%–40%) were frequently detectable in the mollusk samples, while L5–L7 were not found in any mollusk samples. Cyclic methylsiloxanes(D4–D6) were found in mollusks with the mean concentrations of 15.7 ± 12.3 ng/g ww for D4,24.6 ± 15.8 ng/g ww for D5 and 34.0 ± 23.0 ng/g ww for D6. Among the seven sampling cities, the cyclic methylsiloxanes were predominant in mollusks, with the total cyclic methylsiloxanes(sum of D4–D6, ∑ CMS) accounting for 74.2%–80.7% of the total methylsiloxanes. ∑ CMS along the coastline demonstrated a clear gradient, with the highest concentrations in mollusks at the sampling sites located in the western part of the Bohai Sea and the lowest concentrations in mollusks from cities located in the eastern part of the Bohai Sea. The biota-sediment accumulation factors for cyclic methylsiloxanes(D4–D6) and linear methylsiloxanes(L8–L16) were estimated as 0.42 ± 0.06–0.53 ± 0.06 and0.13 ± 0.03–0.19 ± 0.05, respectively.

Hydrolysis of polyaluminum chloride prior to coagulation:Effects on coagulation behavior and implications for improving coagulation performance

The effects of polyaluminum chloride（PACl） hydrolysis prior to coagulation on both the coagulation zone and coagulation performance of a kaolin suspension were investigated by a novel jar test named the ＂reversed coagulation test＂.The tests showed that PACl hydrolysis prior to coagulation decreased the performance of charge neutralization coagulation in the case of short-time slow mixing（10 min;G = 15 sec-1） and increased the optimal dosage for charge neutralization and sweep coagulation.Moreover,the hydrolysis time had insignificant effects on the size and zeta potential of PACl precipitates and the residual turbidity of the raw water.However,PACl hydrolysis prior to coagulation and the size of PACl precipitates had a negligible effect on the performance of sweep coagulation.The results imply that,in practice,preparing a PACl solution with deionized water,rather than tap water or the outlet water from a wastewater treatment unit,can significantly save PACl consumption and improve the performance of charge neutralization coagulation,while preparing the PACl solution with tap or outlet water would not affect the performance of sweep coagulation.In addition,the optimal rapid mixing intensity appears to be determined by a balance between the degree of coagulant hydrolysis before contacting the primary particles and the average size of flocs in the rapid mixing period.These results provide new insights into the role of PACl hydrolysis and will be useful for improving coagulation efficiency.

Peroxymonosulfate assisted mechanochemical method for the degradation of phenanthrene in contaminated soils

In recent years,mechanochemical method has received attention in the field of degrading pollutants,especially for persistent organic pollutants.In this study,peroxymonosulfate(PMS)as a co-grinding reagent,coupled with contaminated soil were placed in a ball mill for mechanochemical reaction.Through investigating the influences of ball-milling parameters on the degradation efficiency,the reaction conditions were optimized.Under the optimal condition(mass ratio of soil to oxidant is 10:1,mass ratio of ball to material is 30:1,rotation speed of ball mill is 400 rpm),more than 98%phenanthrene(PHE)in contaminated soil could be degraded within 4 h.Meanwhile,the effects of soil organic matter content and soil type on the degradation efficiency were investigated.The results showed that the organic matter content was negatively correlated with the degradation efficiency.XPS analysis provided evidence for the breakage of the CeC bond and confirmed that Fe in soil was an important factor in activating PMS.XRD further verified the destruction of PHE structure.GC-MS analysis was performed to identify the intermediates and possible pathways were proposed.

Removal of high concentrations of polycyclic aromatic hydrocarbons from contaminated soil by biodiesel

Solubilizing experiments were carried out to evaluate the ability of biodiesel to remove polycyclic aromatic hydrocarbons(PAHs)from highly contaminated manufactured gas plant(MGP)and PAHs spiked soils with hydroxypropyl-β-cyclodextrin(HPCD)and tween 80 as comparisons.Biodiesel displayed the highest solubilities of phenanthrene(420.7 mg·L^(-1)),pyrene(541.0 mg·L^(-1)),and benzo(a)pyrene(436.3 mg·L^(-1)).These corresponded to several fold increases relative to 10%HPCD and tween 80.Biodiesel showed a good efficiency for PAH removal from the spiked and MGP soils for both low molecular weight and high molecular weight PAHs at high concentrations.Biodiesel was the best agent for PAH removal from the spiked soils as compared with HPCD and tween 80;as over 77.9%of individual PAH were removed by biodiesel.Tween 80 also showed comparable capability with biodiesel for PAH solubilization at a concentration of 10%for the spiked soils.Biodiesel solubilized a wider range of PAHs as compared to HPCD and tween 80 for the MPG soils.At PAH concentrations of 229.6 and 996.9 mg·kg^(-1),biodiesel showed obvious advantage over the 10%HPCD and tween 80,because it removed higher than 80%of total PAH.In this study,a significant difference between PAH removals from the spiked and field MGP soils was observed;PAH removals from the MGP soil by HPCD and tween 80 were much lower than those from the spiked soil.These results demonstrate that the potential for utilizing biodiesel for remediation of highly PAH-contaminated soil has been established.

Identifying factors that influence soil heavy metals by using categorical regression analysis:A case study in Beijing,China

Identifying the factors that influence the heavy metal contents of soil could reveal the sources of soil heavy metal pollution.In this study,a categorical regression was used to identify the factors that influence soil heavy metals.First,environmental factors were associated with soil heavy metal data,and then,the degree of influence of different factors on the soil heavy metal contents in Beijing was analyzed using a categorical regression.The results showed that the soil parent material,soil type,land use type,and industrial activity were the main influencing factors,which suggested that these four factors were important sources of soil heavy metals in Beijing.In addition,population density had a certain influence on the soil Pb and Zn contents.The distribution of soil As,Cd,Pb,and Zn was markedly influenced by interactions,such as traffic activity and land use type,industrial activity and population density.The spatial distribution of soil heavy metal hotspots corresponded well with the influencing factors,such as industrial activity,population density,and soil parent material.In this study,the main factors affecting soil heavy metals were identified,and the degree of their influence was ranked.A categorical regression represents a suitable method for identifying the factors that influence soil heavy metal contents and could be used to study the genetic process of regional soil heavy metal pollution.

Drinking water treatment using a submerged internal-circulation membrane coagulation reactor coupled with permanganate oxidation

A submerged internal circulating membrane coagulation reactor （MCR） was used to treat surface water to produce drinking water. Polyaluminum chloride （PAC1） was used as coagulant, and a hydrophilic polyvinylidene fluoride （PVDF） submerged hollow fiber microfiltration membrane was employed. The influences of trans-membrane pressure （TMP）, zeta potential （ZP） of the suspended particles in raw water, and KMnO4 dosing on water flux and the removal of turbidity and organic matter were systematically investigated. Continuous bench-scale experiments showed that the permeate quality of the MCR satisfied the requirement for a centralized water supply, according to the Standards for Drinking Water Quality of China （GB B749-2006）, as evaluated by turbidity （〈1 NTU） and total organic carbon （TOC） （〈5 mE/L） measurements. Besides water flux, the removal of turbidity, TOC and dissolved organic carbon （DOC） in the raw water also increased with increasing TMP in the range of 0.01-0.05 MPa. High ZP induced by PAC1, such as 5-9 mY, led to an increase in the number of fine and total particles in the MCR, and consequently caused serious membrane fouling and high permeate turbidity. However, the removal of TOC and DOC increased with increasing ZP. A slightly positive ZP, such as 1-2 mV, corresponding to charge neutralization coagulation, was favorable for membrane fouling control. Moreover, dosing with KMnO4 could further improve the removal of turbidity and DOC, thereby mitigating membrane fouling. The results are helpful for the application of the MCR in producing drinking water and also beneficial to the research and application of other coagulation and membrane separation hybrid processes.

Amorphous cobalt hydroxysulfide nanosheets with regulated electronic structure for high-performance electrochemical energy storage

Pseudocapacitors with high power density,longterm durability,as well as reliable safety,play a key role in energy conversion and storage.Designing electrode materials combing the features of high specific capacitance,excellent rate performance,and outstanding mechanical stability is still a challenge.Herein,a facile partial sulfurization strategy has been developed to modulate the electronic structure and crystalline texture of cobalt hydroxide nanosheets(denoted as Co(OH)2)at room temperature.The resultant cobalt hydroxysulfide nanosheet(denoted as Co SOH)electrode with abundant low-valence cobalt species and amorphous structure,exhibits a high specific capacitance of 2110 F g^-1at1 A g^-1with an excellent capability retention rate of 92.1%at10 A g^-1,which is much larger than that of Co(OH)2 precursor(916 F g^-1at 1 A g^-1 and 80%retention at 10 A g^-1).Furthermore,the fabricated asymmetric supercapacitor device constructed with Co SOH and active carbon displays a considerable high energy density of 44.9 W h kg^-1at a power density of 400 W kg^-1,and exceptional stability after 8000cycles.