Preparation and Swelling Kinetic Analysis of Poly (HPMC-co-AA-co-AM) Super Absorbent Resin

Super absorbent resin(SAR)is prepared by aqueous high temperature polymerization using hydroxypropyl methylcellulose(HPMC)as monomer backbone material,acrylic acid(AA)and acrylamide(AM)as the graft copolymer monomer,potassium persulfate(KPS)as the initiator to generate free radicals,and N,N`-methylenebisacrylamide(MBA)as cross-linking agent for cross-linking reaction.Simutaneously,the influence of individual factors on the water absorption is investigated,and these factors are mainly AA,AM,KPS,MBA,HPMC,and reaction temperature.The optimized conditions are obtained by the experiment repeating for several times.The water absorption multiplicity and salt absorption multiplicity under the conditions are 782.4 and 132.5 g/g,respectivity.Furthermore,the effects of different temperatures and salt concentrations on its water absorption,as well as the swelling kinetics of SAR are studied.It is indicated the water-absorbing swelling process is mainly caused by the difference in water osmotic pressure and Na+concentration inside and outside the cross-linked molecular structure of the resin,which is not only consistent with the quasi-secondary kinetic model,but also with the Fick diffusion model.

Enhancement of vertical phase separation in sequentially deposited organic photovoltaics through the independent processing of additives

Herein,the impact of the independent control of processing additives on vertical phase separation in sequentially deposited (SD) organic photovoltaics (OPVs) and its subsequent effects on charge carrier kinetics at the electron donor-acceptor interface are investigated.The film morphology exhibits notable variations,significantly depending on the layer to which 1,8-diiodooctane (DIO) was applied.Grazing incidence wide-angle X-ray scattering analysis reveals distinctly separated donor/acceptor phases and vertical crystallinity details in SD films.Time-of-flight secondary ion mass spectrometry analysis is employed to obtain component distributions in diverse vertical phase structures of SD films depending on additive control.In addition,nanosecond transient absorption spectroscopy shows that DIO control significantly affects the dynamics of separated charges in SD films.In SD OPVs,DIO appears to act through distinct mechanisms with minimal restriction,depending on the applied layer.This study emphasizes the significance of morphological optimization in improving device performance and underscores the importance of independent additive control in the advancement of OPV technology.

Study on the Relationship between Structural Aspects and Aerodynamic Characteristics of Archimedes Spiral Wind Turbines

A combined experimental and numerical research study is conducted to investigate the complex relationship between the structure and the aerodynamic performances of an Archimedes spiral wind turbine(ASWT).Two ASWTs are considered,a prototypical version and an improved version.It is shown that the latter achieves the best aerodynamic performance when the spread angles at the three sets of blades areα_(1)=30°,α_(2)=55°,α3=60°,respectively and the blade thickness is 4 mm.For a velocity V=10 m/s,a tip speed ratio(TSR)=1.58 and 2,the maximum CP values are 0.223 and 0.263 for the prototypical ASWT and improved ASWT,respectively,and the maximum C_(P) enhancement is 17.93%.For V=10 m/s and TSR=2,the CP values of the prototypical ASWT and improved ASWT are 0.225 and 0.263,respectively,with an aerodynamic performance enhancement of 16.88%.Through mutual verification of the test outcomes and numerical results,it is concluded that the proposed approach can effectively lead to aerodynamic performance improvement.

Experimental Study on the Performance of ORC System Based on Ultra-Low Temperature Heat Sources

This paper discussed the experimental results of the performance of an organic Rankine cycle(ORC)system with an ultra-low temperature heat source.The low boiling point working medium R134a was adopted in the system.The simulated heat source temperature(SHST)in this work was set from 39.51°C to 48.60°C by the simulated heat source module.The influence of load percentage of simulated heat source(LPSHS)between 50%and 70%,the rotary valve opening(RVO)between 20%and 100%,the resistive load between 36Ωand 180Ωor the no-load of the generator,as well as the autumn and winter ambient temperature on the system performance were studied.The results showed that the stability of the system was promoted when the generator had a resistive load.The power generation(PG)and generator speed(GS)of the system in autumn were better than in winter,but the expander pressure ratio(EPR)was lower than in winter.Keep RVO unchanged,the SHST,the mass flow rate(MFR)of the working medium,GS,and the PG of the system increased with the increasing of LPSHS for different generator resistance load values.When the RVO was 60%,LPSHS was 70%,the SHST was 44.15°C and the resistive load was 72Ω,the highest PG reached 15.11 W.Finally,a simulation formula was obtained for LPSHS,resistance load,and PG,and its correlation coefficient was between 0.9818 and 0.9901.The formula can accurately predict the PG.The experimental results showed that the standard deviation between the experimental and simulated values was below 0.0792,and the relative error was within±5%.

Stability Study of Low Voltage Electrical Distribution Network: Audit and Improvement of DJEGBE Mini Solar Photovoltaic Power Plant in the Commune of OUESSE (Benin)

The supply of quality energy is a major concern for distribution network managers. This is the case for the company ASEMI, whose subscribers on the DJEGBE mini-power station network are faced with problems of current instability, voltage drops, and repetitive outages. This work is part of the search for the stability of the electrical distribution network by focusing on the audit of the DJEGBE mini photovoltaic solar power plant electrical network in the commune of OUESSE (Benin). This aims to highlight malfunctions on the low-voltage network to propose solutions for improving current stability among subscribers. Irregularities were noted, notably the overloading of certain lines of the PV network, implying poor distribution of loads by phase, which is the main cause of voltage drops;repetitive outages linked to overvoltage caused by lightning and overcurrent due to overload;faulty meters, absence of earth connection at subscribers. Peaks in consumption were obtained at night, which shows that consumption is greater in the evening. We examined the existing situation and processed the data collected, then simulated the energy consumption profiles with the network analyzer “LANGLOIS 6830” and “Excel”. The power factor value recorded is an average of 1, and the minimum value is 0.85. The daily output is 131.08 kWh, for a daily demand of 120 kWh and the average daily consumption is 109.92 kWh, or 83.86% of the energy produced per day. These results showed that the dysfunctions are linked to the distribution and the use of produced energy. Finally, we proposed possible solutions for improving the electrical distribution network. Thus, measures without investment and those requiring investment have been proposed.

Calculation of the Energy Loss for Tip Leakage Flow in Turbines

A commercial N-S solver has been employed for simulation and investigation ofthe unsteady flow field inside the tip clearance of a turbine rotor. The main objective of thispaper is to introduce a new method of energy loss calculation for the flow field in tip clearanceregion of a turbine rotor blade. This method can be easily used in all kinds of flow fields. Regionsof high viscous effects have been found to be located near the shroud rather than the blade tip. Itis shown that the time-averaged loss of energy in tip leakage flow is dissimilar for differentrotor blades. This result is a helpful hint that can be taken by blade designers to designnon-uniform rotor blades with different geometric and aerodynamic loads to minimize the energy loss.

Harvesting Environment Mechanical Energy by Direct Current Triboelectric Nanogenerators

As hundreds of millions of distributed devices appear in every corner of our lives for information collection and transmission in big data era,the biggest challenge is the energy supply for these devices and the signal transmission of sensors.Triboelectric nanogenerator(TENG)as a new energy technology meets the increasing demand of today’s distributed energy supply due to its ability to convert the ambient mechanical energy into electric energy.Meanwhile,TENG can also be used as a sensing system.Direct current triboelectric nanogenerator(DC-TENG)can directly supply power to electronic devices without additional rectification.It has been one of the most important developments of TENG in recent years.Herein,we review recent progress in the novel structure designs,working mechanism and corresponding method to improve the output performance for DC-TENGs from the aspect of mechanical rectifier,tribovoltaic effect,phase control,mechanical delay switch and air-discharge.The basic theory of each mode,key merits and potential development are discussed in detail.At last,we provide a guideline for future challenges of DC-TENGs,and a strategy for improving the output performance for commercial applications.

Recent Advances of Deep Learning in Geological Hazard Forecasting

Geological hazard is an adverse geological condition that can cause loss of life and property.Accurate prediction and analysis of geological hazards is an important and challenging task.In the past decade,there has been a great expansion of geohazard detection data and advancement in data-driven simulation techniques.In particular,great efforts have been made in applying deep learning to predict geohazards.To understand the recent progress in this field,this paper provides an overview of the commonly used data sources and deep neural networks in the prediction of a variety of geological hazards.

Performance Analysis of Multi-Energy Hybrid System Based on Molten Salt Energy Storage

This paper briefly summarizes the current status of typical solar thermal power plant system,including system composition,thermal energy storage medium and performance.The thermo-physical properties of the storage medium are some of the most important factors that affect overall efficiency of the system,because some renewable energy sources such as solar and wind are unpredictable.A thermal storage system is therefore necessary to store energy for continuous usage.Based on the form of storage or the mode of system connection,heat exchangers of a thermal storage system can produce different temperature ranges of heat transfer fluid to realize energy cascade utilization.Founded upon the review,a small hybrid energy system with a molten-salt energy storage system is proposed to solve the problems of heating,cooling,and electricity consumption of a 1000 m2 training hall at school.The system uses molten-salt storage tank,water tank and steam generator to change the temperature of heat transfer fluid,in order to realize thermal energy cascade utilization.Compared to the existing heating and cooling system,the proposed system needs more renewable energy and less municipal energy to achieve the same results according to simulation analysis.Furthermore,by improving the original heating and cooling system,PMV has been improved.The comprehensive efficiency of solar energy utilization has been increased to 83%.

Molecular Dynamics Simulation of Interface Properties between Water-Based Inorganic Zinc Silicate Coating Modified by Organosilicone and Iron Substrate

The interface properties of Fe(101)/zinc silicate modified by organo-siloxane(KH-570)was studied by using the method of molecular dynamics simulation.By calculating the temperature and energy fluctuation of equilibrium state,equilibrium concentration distribution,MSD of layer and different groups,and interaction energy of two interface models,the influencing mechanism on the interface properties of adding organosiloxane into coating system was studied at the atomic scale.It shows that the temperature and energy of interface oscillated in a small range and it was exited in a state of dynamic equilibrium within the initial simulation stage(t<20 ps).It can be seen from the multiple peak states of concentration distribution that the iron substrate,organo-siloxane and zinc silicate are distributed in the form of a concentration gradient in the real environment.The rapid diffusion of free zinc powder in zinc silicate coating was the essential reason that affected the comprehensive properties of coating.The interface thickness decreased from 7.45 to 6.82Å,the MSD of free zinc powder was effectively reduced,and the interfacial energy was increased from 104.667 to 347.158 kcal/mol after being modified by organo-siloxane.

Numerical Simulation Investigation on Parameter Optimization of Deep-Sea Mining Vehicles

The four-track walking mining vehicle can better cope with the complex terrain of cobalt-rich crusts on the seabed.To explore the influence of different parameters on the obstacle-crossing ability of mining vehicles,this paper took a certain type of mine vehicle as an example and establish a mechanical model of the mine vehicle.Through this model,the vehicle's traction coefficient variation could be analyzed during the obstacle-crossing process.It also reflected the relationship between the obstacle-crossing ability and the required traction coefficient.Many parameters were used for this analysis including the radius of the guide wheel radius,ground clearance of the driving wheel,the dip angle of the approaching angular and the position of centroid.The result showed that the ability to cross the obstacles requires adhesion coefficient as support.When the ratio between obstacle height and ground clearance of the guide wheel was greater than 0.7,the required adhesion coefficient increased sharply.The ability to cross obstacles will decrease,if the radius of the guide wheel increases,the height of the driving wheel increases or the dip angle of the approaching angular increases.It was most beneficial to cross the obstacle when-the ratio of the distance between the center of mass and the front driving wheel to the wheelbase is between 0.450.48.The results of this paper could provide reference for structural parameter design and performance research for mining vehicles.

Simulation experiment of AE-based localization damage and deformation characteristic on covering rock in mined-out area

The localization damage and deformation characteristics of multiple rock in mined-out area under thick soil layer were investigated by acoustic emission （AE）-based physical similar simulation experiment and damage test combined with the AE theory on rock damage. During different mining courses, the degree of wall rock suffered from mining disturbed process in mined-out area was different, so did the AE density of initial damage and fracture. Some characteristic parameters, including large events, total events, and energy rate, presented fluctuations with temporal and spatial change and take on a certain extent statistic relation. Subsequently, the percent of damage degree was defined and divided into 4 stages, and the localization damage and deformation characteristics of surrounding rock in mined-out area and coal pillars were analyzed quantitatively.

Comprehensive evaluation of high-steep slope stability and optimal high-steep slope design by 3D physical modeling

High-steep slope stability and its optimal excavation design in Shuichang open pit iron mine were analyzed based on a large 3D physical simulation technique. An optimal excavation scheme with a relatively steeper slope angle was successfully implemented at the northwest wall between Nos. 4 and 5 exploration lines of Shuichang Iron Mine, taking into account the 3D scale effect. The phys-ico-mechanical properties of rock materials were obtained by laboratory tests conducted on sample cores from exploration drilling directly from the iron mine. A porous rock-like composite material was formed for the model, and the mechanical parameters of the material were assessed experimentally;specifically, the effect of water on the sample was quantitatively determined. We adopted an experimental setup using stiff modular applied static loading to carry out a visual excavation of the slope at a random depth. The setup was equipped with acous-tic emission （AE） sensors, and the experiments were monitored by crack optical acquirement, ground penetrating radar, and close-field pho-togrammetry to investigate the mechanisms of rock-mass destabilization in the high-steep slope. For the complex study area, the model re-sults indicated a clear correlation between the model＇s destabilization resulting from slope excavation and the collected monitoring informa-tion. During the model simulation, the overall angle of the slope increased by 1-6 degrees in different sections. Dramatically, the modeled excavation scheme saved over 80 million tons of rock from extraction, generating enormous economic and ecological benefits.

Comparative study of mining methods for reserves beneath end slope in flat surface mines with ultra-thick coal seams

The paper aims to identify a reasonable method for mining ultra-thick coal seams in an end-slope in surface mine, With a case study of Heidaigou surface coal mine(HSCM), the paper conducted a comparative research on three mining methods, namely Underground Mining Method(UMM), Highwall Mining System(HMS) and Local Steep Slope Mining Method(LSSMM). A model was firstly established to simulate the impact that UMM and HMS exert on monitoring points and surface deformation. The way that stripping and excavation amount varies with different slope angle, and the corresponding end slope stability were analyzed in the mode of LSSMM. Then a TOPSIS model was established by taking into account six indicators such as recovery ratio, technical complexity and adaptability, the impact on surface mining production, production safety and economic benefits. Finally, LSSMM was determined as the best mining method for mining ultra-thick coal seams in end slope in HSCM.

Experimental Study and Property Analysis of Seal-filling Hydrogel Material for Hermetic Wall in Coal Mine

The effects of monomer, crosslinker, and accelerator content on the mechanical property of seal-filling hydrogel material for building hermetic wall were analyzed through a series of single-direction compression experiments. Grey predication by GM（1,1） model was also used to analyze the persistent property of hydrogel material. The results showed that the elastic modulus and strength of seal-filling hydrogel increased, and the elastic tended to reduce with the growth of monomer and crosslinker content. In comparison, the effect of accelerator content was diametrically opposed. At the same time, staggered change of elastic modulus occurred and its demarcation point generally appeared at the point of 50% of vertical deformation value. In addition, through the testing of correlation degree, the accuracy of the grey prediction model to test the persistent stability of hydrogel material can be proved. As the concentration of hydrophilic monomer in hydrogel material increased, the stability was improved. The energy originated from explosion shock wave can be absorbed by seal-filling hydrogel through deformation.

Characteristics of ground behavior of fully mechanized caving faces in hard thick seams

It is showed in practice that the support load and its fluctuation is large, the periodic weighting is obvious and can be divided into two kinds, the large and small pressure, sometimes the behavior of the large pressure is very violent in hard thick seam caving faces. These are obviously different from those of the generally soft or medium hard seam caving feces. All above these are summarized, and the causes aroused these are researched. Finally the powered support selection of hard thick seam caving faces is discussed.

Numerical simulation of influence of Langmuir adsorption constant on gas drainage radius of drilling in coal seam

To determine reasonable distance of gas pre-drainage drillings in coal seams, a solid–gas coupling model that takes gas adsorption effect into account was constructed. In view of different adsorption constants,the paper conducted the numerical simulation of pre-drainage gas in drillings along coal seam, studied the relationship of adsorption constants and permeability, gas pressure, and effective drainage radius of coal seams, and applied the approach to the layout of pre-drainage gas drillings in coal seams. The results show that the permeability of coal seams is on the gradual increase with time, which is divided into three sections according to the increase rate: the drainage time 0–30 d is the sharp increase section;30–220 d is the gradual increase section; and the time above 200 d is the stable section. The permeability of coal seams is in negative linear and positive exponent relation with volume adsorption constant VLand pressure adsorption constant PL, respectively. The effective drainage radius is in negative linear relation with VLand in positive exponent relation with PL. Compared with the former design scheme, the engineering quantity of drilling could be reduced by 25%.

Research on time structure characteristic of gas concentration sequence in the working face

In the procedure of coal industry production, the losses of the persons and economy caused by the gas explosion accidents are most serious, therefore, prevention and control of the gas explosion accident of the coal mines is an important issue needed to be solved urgently in the safety production work of our coal mines. The characteristic of time structure variation index characteristic was analyzed about gas concentration sequence of three measure points in the NO. 1I 1024 working face. It was found that the value of time variation about three measure points was mostly 1〈δ≤1.5, and gas emission presented consistently strong-clustering state twice, and the value of time variation presented continuous variation state in the active stage of gas concentration. Complex characteristics of the value indicated gas emission was continuously variable in time or space and presented the complex nonlinear characteristics. So the characteristic about gas emission system was correctly depicted and analyzed to gas emission system according to the relation of its state variation and essential of nonlinear system. The result also provided reliable warranty for its continued nonlinear research on gas emission.

Multi-factor dynamic analysis of the deformation of a coal bunker in a coal preparation plant

To assess the deformation of a coal bunker and propose effective preventative measures for such,a real-time monitoring system was designed.Moreover,methods were proposed for monitoring the coal-bunker inclination,settlement,groundwater level,temperature,and material level.By using a vector autoregression model and time-series data for the coal-bunker deformation,a long-term equilibrium relationship was derived between the coal-bunker inclination and settlement and their influencing factors.The dynamic effects of each factor on the coal-bunker inclination and settlement and how the contribution of each factor changes were revealed by using an impulse response function and variance decomposition.The results show that the coal-bunker inclination and settlement vary hysteretically.Groundwater level has constant and small negative effects on the coal-bunker inclination and settlement,and temperature has continuous and significant negative effects;however,material level has constant positive effects on the coal-bunker settlement and slightly influences the eastward inclination while significantly influencing the northward inclination of the coal bunker.Also,unbalanced loading has little influence on the coal-bunker settlement and eastward inclination but significant influence on its northward inclination.Therefore,monitoring of the coal-bunker deformation should be strengthened in summer,and sudden changes in material level and unbalanced loading should be avoided during production.Moreover,the coal-bunker inclination can be adjusted by unbalanced loading in the reverse direction.

Monte-Carlo simulation of pinhole collimator of a small field of view gamma camera for small animal imaging

Needs in scintimammography applications,especially for small animal cardiac imaging,lead to develop a small field of view,high spatial resolution gamma camera with a pinhole collimator.However the ideal pinhole collimator must keep a compromise between spatial resolution and sensitivity.In order to design a pinhole collimator with an optimized sensitivity and spatial resolution,the spatial resolution and the geometric sensitivity response as a function of the source to collimator distance has been obtained by means of Monte-Carlo simulation for a small field of view gamma camera with a pinhole collimator of various-hole diameters.The results show that the camera with pinhole of 1 mm,1.5 mm and 2 mm diameter has respectively spatial resolution of 1.5 mm,2.25 mm and 3 mm and geometric sensitivity of 0.016%,0.022%and 0.036%,while the source to collimator distance is 3 cm.We chose the pinhole collimator with hole diameter size of 1.2 mm for our the gamma camera designed based on the trade-off between sensitivity and resolution.