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Determination of the Genetic Structure of the Oleaginous <i>Lagenaria siceraria</i>of the Nangui Abrogoua University Germplasm Collection
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作者 Ahou Anique Gbotto Kouamé Kevin Koffi +1 位作者 Jean-Pierre Baudoin Irié Arsène Zoro Bi 《American Journal of Plant Sciences》 2015年第19期3231-3243,共13页
Thirty accessions of Lagenaria siceraria from the Nangui Abrogoua University germplasm collection were analyzed using three microsatellite markers. The average Polymorphism Information Content (PIC) value was 0.61. Th... Thirty accessions of Lagenaria siceraria from the Nangui Abrogoua University germplasm collection were analyzed using three microsatellite markers. The average Polymorphism Information Content (PIC) value was 0.61. The average observed heterozygosity value (H0 = 0.631) compared to the average expected heterozygosity value (He = 0.645) did not show significant differences in the selected accessions, which suggested random mating in the set of accessions. Within accession inbreeding estimate (FIS), was 40% and was not significantly different from zero. The reduction of heterozygotes was likely the result of presence of null alleles. Analysis of Molecular Variance (AMOVA) within and among 30 accessions of L. siceraria revealed that 39% of the total variation resides among accessions and 61% within accessions. Accession structuring pattern derived from Bayesian clustering analysis revealed two clusters. Based on the genetic structure of the accessions analyzed, a sampling strategy to collect and conserve genetic resources of L. siceraria was suggested. 展开更多
关键词 GENETIC Structure Lagenaria siceraria NULL Alleles Oleaginous SSR
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Photocatalytic Decoloration of Methyl Orange by TiO2 in Slurry
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作者 M’Bra Ignace Christian Konan Affoué Tindo Sylvie +4 位作者 Gnagne Essoh Jean Eudes Yves Yacouba Zoungranan Touré Late Arsène Ekou Lynda Ekou Tchirioua 《American Journal of Analytical Chemistry》 CAS 2024年第11期347-356,共10页
The problem of water depollution is gaining importance, especially as regulatory standards concerning drinking water are increasingly strict. The different industries (textile industries) generate chemically stable po... The problem of water depollution is gaining importance, especially as regulatory standards concerning drinking water are increasingly strict. The different industries (textile industries) generate chemically stable pollutants such as methyl orange which make their degradation difficult. It is therefore necessary to find new, more effective techniques for the treatment of these discharges. Among the different solutions proposed to deal with this problem, we find advanced oxidation processes (POAs) which are clean and promising technologies in the field of wastewater depollution. In this regard, heterogeneous photocatalysis was used in an aqueous suspension of titanium oxide (TiO2) using a ultraviolet (UV) lamp as artificial radiation. The objective of this work is to study the influence of some operating parameters such as: the catalyst mass, the initial pollutant concentration, the volume of the solution and the pH of the solution, were examined. The results obtained showed that this photocatalyst made it possible to degrade 99.85% of the initial concentration of methyl orange (10 ppm), after 240 min of irradiation with an optimal mass of 0.50 g of TiO2 for a volume of 200 mL of methyl orange solution at pH = 3.0. 展开更多
关键词 DEPOLLUTION Methyl Orange TIO2 SLURRY
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Physical and Chemical Characterizations of Rubber Latex Cup Bottom Oil
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作者 Kouassi Konan Edmond Abolle Abollé +3 位作者 Aketchi Tanoé Lucien Konan Affoué Tindo Sylvie Boa David Yao Kouassi Benjamin 《Advances in Bioscience and Biotechnology》 CAS 2024年第9期511-521,共11页
Rubber latex is an important economic resource. However, the residues from its harvesting are thrown away, even though they contain lipids that can be recycled. This recovery of the residues from the bottom of the cup... Rubber latex is an important economic resource. However, the residues from its harvesting are thrown away, even though they contain lipids that can be recycled. This recovery of the residues from the bottom of the cup requires first and foremost their characterization. The aim of this study is therefore to determine the main physical and chemical characteristics of rubber latex cup bottom oil. Oil’s physical parameters determination shows that it has a density of 951 kg∙m−3, a kinematic viscosity of 48.57 cSt and a water content of 0.0845%. Chemical parameters, meanwhile, indicate that this cup bottom residue has a fat content of 95.96%, an acid number of 2.805 mg KOH/g and an iodine number of 92.42 g I2/100g. Therefore, rubber latex cup bottom oil can be used in the formulation of biofuels, biolubricants, paints, varnishes, alkyd resins, polishing oils, soaps, and insecticides. 展开更多
关键词 Rubber Latex Cup Bottoms Oil Density Viscosity CHARACTERIZATIONS
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Using Optical Tweezers to Study the Friction of the Red Blood Cells
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作者 Edoukoua Jean Michel Konin Pavel Yale +3 位作者 Abadê Ange-Boris N’guessan Kouassi Benoit Kouakou Abaka Michel Kouacou Eugene Megnassan 《Advances in Bioscience and Biotechnology》 CAS 2024年第2期100-111,共12页
In the last two decades the study of red blood cell elasticity using optical tweezers has known a rise appearing in the scientific research with regard to the various works carried out. Despite the various work done, ... In the last two decades the study of red blood cell elasticity using optical tweezers has known a rise appearing in the scientific research with regard to the various works carried out. Despite the various work done, no study has been done so far to study the influence of friction on the red blood cell indentation response using optical tweezers. In this study, we have developed a new approach to determine the coefficient of friction as well as the frictional forces of the red blood cell. This approach therefore allowed us to simultaneously carry out the indentation and traction test, which allowed us to extract the interfacial properties of the microbead red blood cell couple, among other things, the friction coefficient. This property would be extremely important to investigate the survival and mechanical features of cells, which will be of great physiological and pathological significance. But taking into account the hypothesis of friction as defined by the isotropic Coulomb law. The experiment performed for this purpose is the Brinell Hardness Test (DB). 展开更多
关键词 FRICTION INDENTATION Optical Tweezers TRIBOLOGY Red Blood Cells
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Local Plants Potentially Suitable for Phytoremediation of Soils Polluted by Heavy Metals: The Case of Landfill Sites
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作者 Kpan Kpan Kouakou Gains Touré Mamadou +4 位作者 Ouattara Nouffou Doudjo Kouassi Kouadio Claude Ehouman N’guetta Moïse Ouattara Djibril Tiho Seydou 《Journal of Geoscience and Environment Protection》 2024年第7期72-88,共17页
Landfills are contaminated sites that need to be cleaned up to prevent human and environmental exposure to pollutants. This article aims to identify local plants capable of restoring soil polluted by heavy metals. To ... Landfills are contaminated sites that need to be cleaned up to prevent human and environmental exposure to pollutants. This article aims to identify local plants capable of restoring soil polluted by heavy metals. To this end, plant species at the Bonoua landfill were inventoried. X-ray fluorescence spectrometry was used to determine the heavy metal content of soil and plants from the landfill. The bioconcentration factor (BCF) of metals in plants was evaluated. The Bonoua landfill is covered with 62 plant species, comprising 28 botanical families and 50 genera. The BCF varied from 0.08 (titanium) to 2.27 (strontium) for Phyllanthus amarus;from 0.06 (titanium) to 1.83 (copper) for Alternanthera sessilis and from 0.03 (arsenic) to 2.10 (strontium) for Amaranthus spinosus. Phyllanthus amarus, Alternanthera sessilis, and Amaranthus spinosus are strontium-accumulating species (BCF > 1). Similarly, copper BCF values were above 1 for Phyllanthus amarus, and Alternanthera sessilis. These two plant species are therefore copper accumulators. In short, Phyllanthus amarus, Alternanthera sessilis, and Amaranthus spinosus are candidate species for phytoremediation of heavy metal-polluted soils, given their BCF > 1. 展开更多
关键词 Heavy Metals PHYTOREMEDIATION Phyllanthus amarus Alternanthera sessilis Amaranthus spinosus
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Distribution, Mobility, and Health Risks Assessment of Trace Metals in River Sediments from Intense Agricultural Activity Areas in West Africa
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作者 Ahbeauriet Ahmed Ouattara Maley-Pacôme Soro +2 位作者 Albert Brou Kouadio Horo Koné Albert Trokourey 《Journal of Materials Science and Chemical Engineering》 2024年第8期12-42,共31页
The economy of West African countries is mainly based on agriculture. However, the trace metal(loid)s contamination status in rivers is relatively unknown in the region. In this work, 45 surface sediments collected fr... The economy of West African countries is mainly based on agriculture. However, the trace metal(loid)s contamination status in rivers is relatively unknown in the region. In this work, 45 surface sediments collected from the Bandama, Comoé, and Bia Rivers in south and south eastern Côte d’Ivoire (West Africa), were analyzed for total metal concentrations and chemical speciation. The results showed that the river sediments were considerably contaminated by Cd and moderately contaminated by As, Cu, Pb, and Zn. Significant spatial variations were observed among the stations but not between the rivers. Metals Cd and Cu were likely to cause more ecological risks. The speciation analysis unravelled that the metal(loid)s partitioned mainly in the residual fraction, with the potential mobile fraction varying from 14% to 28%. The study calls for establishment of strict policies relative to the application of fertilizers and agrochemicals and mining activities to protect the environment and human health risks. 展开更多
关键词 River Sediment Trace Metal (Loid)s Multivariate Analysis Potential Ecological Risk Assessments Sequential Extraction Geochemical Indices
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Optimization of Tin-Doped Hybrid Perovskite Solar Cells
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作者 Bakary Coulibaly Abou Ahou Florentine Kokora +2 位作者 Desiré Meledje Boko Aka Bernabé Mari Soucase 《Open Journal of Applied Sciences》 2024年第3期687-706,共20页
Perovskites are a category of materials with a unique crystal structure that allows them to absorb sunlight efficiently. This efficiency is particularly high in the case of CH<sub>3</sub>NH<sub>3<... Perovskites are a category of materials with a unique crystal structure that allows them to absorb sunlight efficiently. This efficiency is particularly high in the case of CH<sub>3</sub>NH<sub>3</sub>Pb<sub>1-x</sub>Sn<sub>x</sub>I<sub>3</sub> mixed perovskites. The combination of lead (Pb) and tin (Sn) in this matrix provides a broad spectrum of sunlight absorption, enabling the generation of a larger voltage and, subsequently, increased power. The primary objective in solar cell development is to maximize the conversion of sunlight into electricity. Mixed perovskites like CH<sub>3</sub>NH<sub>3</sub>Pb<sub>1-x</sub>Sn<sub>x</sub>I<sub>3</sub> have demonstrated significant potential in this regard. Their tunable bandgap, courtesy of varying the Pb: Sn ratio, allows for the optimization of sunlight absorption. The result is solar cells that surpass many conventional counterparts in terms of energy efficiency. Another significant advantage of these mixed perovskite solar cells is their cost-effectiveness. They can be manufactured using solution-based processes, which are less expensive than the high-vacuum methods required for traditional silicon solar cells. While the prospects for mixed perovskite solar cells are undeniably promising, there are concerns about the toxicity of lead, a key component of these cells. Lead is known to have harmful effects on the environment and health. The aim of our work is to reduce or eliminate lead toxicity in the perovskite cell while maintaining its efficiency. Thus, in a theoretical and experimental approach, we obtained following efficiencies of samples: CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> (22.49%) CH<sub>3</sub>NH<sub>3</sub>Pb<sub>0.75</sub>Sn<sub>0.25</sub>I<sub>3</sub> (22.72%), CH<sub>3</sub>NH<sub>3</sub>Pb<sub>0.5</sub>Sn<sub>0.5</sub>I<sub>3</sub> (23.00%) CH<sub>3</sub>NH<sub>3</sub>Pb<sub>0.25</sub>Sn<sub>0.75</sub>I<sub>3</sub> (22.61%), CH<sub>3</sub>NH<sub>3</sub>SnI<sub>3</sub> (22.38%). Doping with 50% tin gives the highest result (23.00%). By replacing a fraction of the lead with tin, the research aims to reduce the environmental footprint of the cells while maintaining their high performance. However, the challenge is to achieve a balance that does not compromise performance while reducing toxicity. . 展开更多
关键词 COST Efficiency Lead/Tin PEROVSKITE TOXICITY
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Quantitative Structure Anti-Cancer Activity Relationship (QSAR) of a Series of Ruthenium Complex Azopyridine by the Density Functional Theory (DFT) Method 被引量:5
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作者 Kouakou Nobel N’guessan Mamadou Guy-Richard Koné +2 位作者 Kafoumba Bamba Ouattara Wawohinlin Patrice Nahossé Ziao 《Computational Molecular Bioscience》 2017年第2期19-31,共13页
A series of ruthenium azopyridine complexes have recently been investigated due to their potential cytotoxic activities against renal cancer (A498), lung cancer (H226), ovarian cancer (IGROV), breast cancer (MCF-7) an... A series of ruthenium azopyridine complexes have recently been investigated due to their potential cytotoxic activities against renal cancer (A498), lung cancer (H226), ovarian cancer (IGROV), breast cancer (MCF-7) and colon cancer (WIDR). Thus, in order to predict the cytotoxic potentials of these compounds, quantitative structure-activity relationship studies were carried out using the methods of quantum chemistry. Five Quantitative Structure Activity Relationship (QSAR) models were obtained from the determined quantum descriptors and the different activities. The models present the following statistical indicators: regression correlation coefficient R2 = 0.986 - 0.905, standard deviation S = 0.516 - 0.153, Fischer test F = 106.718 - 14.220, correlation coefficient of cross-validation = 0.985- 0.895 and = 0.010 - 0.001. The statistical characteristics of the established QSAR models satisfy the acceptance and external validation criteria, thereby accrediting their good performance. The models developed show that the variation of the free enthalpy of reaction , the dipole moment μ and the charge of the ligand in the complex Ql, are the explanatory and predictive quantum descriptors correlated with the values of the anti-cancer activity of the studied complexes. Moreover, the charge of the ligand is the priority descriptor for the prediction of the cytotoxicity of the compounds studied. Furthermore, QSAR models developed are statistically significant and predictive, and could be used for the design and synthesis of new anti-cancer molecules. 展开更多
关键词 RUTHENIUM Azopyridine Complex ANTI-CANCER QSAR DFT METHOD
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NBO Population Analysis and Electronic Calculation of Four Azopyridine Ruthenium Complexes by DFT Method 被引量:2
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作者 N’Guessan Kouakou Nobel Kafoumba Bamba +1 位作者 Ouattara Wawohinlin Patrice Nahossé Ziao 《Computational Chemistry》 2017年第1期51-64,共14页
The molecular structure, the Natural Bond orbital (NBO) and the Time Dependent-DFT of both isomers cis or γ-Cl and trans or δ-Cl of RuCl2(L)2, where L stands respectively for 2-phenylazopyridine (Azpy), 2,4-dimethyl... The molecular structure, the Natural Bond orbital (NBO) and the Time Dependent-DFT of both isomers cis or γ-Cl and trans or δ-Cl of RuCl2(L)2, where L stands respectively for 2-phenylazopyridine (Azpy), 2,4-dimethyl-6-[phenylazo]pyridine (Dazpy), 2-[(3,5-dimethylphenyl)azopyridine] (Mazpy) and 2-pyridylazonaphtol (Nazpy) were calculated with DFT method at B3LYP/LANL2DZ level. The prediction of the frontier orbitals (Highest Occupied Molecular Orbital or HOMO and Lowest Unoccupied Molecular Orbital or LUMO) shows that the most active complexes suitable for electronic reactions are admitted to be the trans isomers. Moreover, δ-RuCl2 (Azpy)2 is discovered to react more actively as photo-sensitizer since its energy gap is the minimum. Besides, electronic structures of all complexes through NBO calculation indicate that Ru-N bonds are made of delocalization of occupancies from lone pair orbital of N atoms to the ruthenium. Moreover, Ru was assumed to have almost the same charge regardless the structure of the azopyridine ligands in the complex indicating that the ligands provide only a steric effect that is responsible for the ruthenium’s selectivity. Concerning the transition state, NBO analysis also highlights that the transition LP(Ru) π*(N1-N2) does correspond to t2g?π*(L). This transition is assumed to correspond to Metal to Ligand Charge Transfer (MLCT) that is responsible for the photo-sensitiveness of the metallic complex. Besides, TDDFT calculation of complexes showed that δ-RuCl2(Nazpy)2 displays the largest band during the absorption. For that reason, it is admitted to be the best photosensitizer due to a large system of conjugation provided by Nazpy ligand. 展开更多
关键词 Natural Bond ORBITAL (NBO) HOMO LUMO Azopyridine LIGAND MLCT LLCT
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Determination of ETM, Histamine and Mycotoxins in Garba, a Traditional Ivoirian Meal 被引量:2
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作者 Adjo Thérèse Anoman Kouamé Mathias Koffi +1 位作者 Kouassi Narcisse Aboua Marina Koussemon 《American Journal of Analytical Chemistry》 2018年第4期245-256,共12页
The methods of preparation, conservation and sale of Garba, the traditional Ivorian street meal, abundantly consumed in C&ocirc;te d’Ivoire, can be exposed to various infections resulting in the poisoning of cons... The methods of preparation, conservation and sale of Garba, the traditional Ivorian street meal, abundantly consumed in C&ocirc;te d’Ivoire, can be exposed to various infections resulting in the poisoning of consumers. The aim of this study was to evaluate the hygienic quality of Garba through the analysis and the determination of certain toxic chemicals. In three hundred (300) samples of Garba collected in four districts in Abidjan, toxic metals (cadmium, mercury, lead), biogenic amine (histamine) and mycotoxins (aflatoxins and ochratoxin A) were detected and quantified using official standardized methods. Different toxics analyzed were present at various levels in the Garba. The mercury, lead, cadmium and histamine levels in the Garba were respectively 0.19 mg/kg, 0.19 mg/kg, 0.03 mg/kg and 32.69 mg/kg. The detected mycotoxins included aflatoxins B1, B2, G1, G2 and ochratoxin A, with respective average proportions of 3.44 μg/kg, 1.90 μg/kg, 8.07 μg/kg, 0.56 μg/kg and 0.42 μg/kg. The mycotoxins levels in the Garba are higher than the recommended toxic levels, particularly the ones in aflatoxin B1 and G1. This suggests a sanitary risk associated with the consumption of this meal. Consequently, awareness campaigns and training of the Garba sellers in hygiene and a better regulation of this sector by the competent authorities are required. 展开更多
关键词 Garba TOXIC Metals BIOGENIC AMINE Mycotoxins
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An efficient hybrid protection scheme with shared/dedicated backup paths on elastic optical networks 被引量:3
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作者 Nogbou G. Anoh Michel Babri +3 位作者 Ahmed D. Kora Roger M. Faye Boko Aka Claude Lishou 《Digital Communications and Networks》 SCIE 2017年第1期11-18,共8页
Fast recovery and minimum utilization of resources are the two main criteria for determining the protection scheme quality. We address the problem of providing a hybrid protection approach on elastic optical networks ... Fast recovery and minimum utilization of resources are the two main criteria for determining the protection scheme quality. We address the problem of providing a hybrid protection approach on elastic optical networks under contiguity and continuity of available spectrum constraints. Two main hypotheses are used in this paper for backup paths computation. In the first case, it is assumed that backup paths resources are dedicated. In the second case, the assumption is that backup paths resources are available shared resources. The objective of the study is to minimize spectrum utilization to reduce blocking probability on a network. For this purpose, an efficient survivable Hybrid Protection Lightpath (HybPL) algorithm is proposed for providing shared or dedicated backup path protection based on the efficient energy calculation and resource availability. Traditional First-Fit and Best-Fit schemes are employed to search and assign the available spectrum resources. The simulation results show that HybPL presents better performance in terms of blocking probability, compared with the Minimum Resources Utilization Dedicated Protection (MRU-DP) algorithm which offers better performance than the Dedicated Protection (DP) algorithm. 展开更多
关键词 Hybrid protectionElastic Optical NetworksBackup shared resourcesEfficient energy costMinimum resource utilizationModulation format
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SARs Investigation of α-, β-, γ-, δ-, ε-RuCl2(Azpy)2 Complexes as Antitumor Drugs 被引量:2
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作者 Kafoumba Bamba Ouattara Wawohinlin Patrice +1 位作者 N’Guessan Kouakou Nobel Nahossé Ziao 《Computational Chemistry》 2016年第1期1-10,共10页
Structure Activity-Relationships (SARs) of the five possible isomers of RuCl<sub>2</sub>(Azpy)<sub>2</sub> were predicted thanks to DFT method. Azpy stands for 2-phenylazopyridine and the struc... Structure Activity-Relationships (SARs) of the five possible isomers of RuCl<sub>2</sub>(Azpy)<sub>2</sub> were predicted thanks to DFT method. Azpy stands for 2-phenylazopyridine and the structure of the isomers α-RuCl<sub>2</sub>(Azpy)<sub>2</sub>, β-RuCl<sub>2</sub>(Azpy)<sub>2</sub>, γ-RuCl2(Azpy)2, δ-RuCl<sub>2</sub>(Azpy)<sub>2</sub> and ε-RuCl<sub>2</sub>(Azpy)<sub>2</sub> call respectively α-Cl, β-Cl, γ-Cl, δ-Cl and ε-Cl are defined according to chlorine atoms orientations. Hence, they are divided into two groups. In the first group comprising α-Cl, β-Cl and ε-Cl, both chlorine atoms are in cis position and Azpy ligands are intervertical. Whereas the two others isomers (γ-Cl and δ-Cl), they form the second group. Here, both chlorine are in trans position and Azpy are planar. The five synthesized isomers were investigated as potential antitumor agents. Then, regarding the DNA, its bases are stacked by pair. Therefore, complexes are assumed to insert and to stack on them through intercalative mode. So the electronic and geometric structures become more important to describe their SARs. Consequently, group 2 regarding γ-Cl and δ-Cl presents the best structure to allow intercalation between DNA base-pairs. Besides, the energy order of the lower unoccupied molecular orbital (LUMO) of the isomers is ELUMO(β-Cl) > ELUMO(α-Cl) > ELUMO(ε-Cl) > ELUMO(γ-Cl) > ELUMO(δ-Cl). The energy gap between LUMO and HOMO was also sorted as Δ(L-H)(β-Cl) > Δ(L-H)(α-Cl) > Δ(L-H)(ε-Cl) > Δ(L-H)(γ-Cl) > Δ(L-H)(δ-Cl). In addition, the total dipole moment was classified as μ(ε-Cl) > μ(β-Cl) > μ(α-Cl) > μ(γ-Cl) > μ(δ-Cl). Finally, net charge of the ligand Azpy was also classified as QL(δ-Cl) > QL(γ-Cl) > QL(ε-Cl) > QL(α-Cl) > QL(β-Cl). All those parameters show that δ-Cl isomer displays the highest activity as antitumor drug when intercalating between the DNA basepairs Cytosine-Guanine/Cytosine-Guanine (CG/CG). 展开更多
关键词 Structure Activity-Relationship (SARs) Ru (II) Complexes Azpy DFT Lanl2dz DNA-BINDING
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Quantum Chemistry Prediction of Molecular Lipophilicity Using Semi-Empirical AM1 and <i>Ab Initio</i>HF/6-311++G Levels 被引量:1
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作者 Ouanlo Ouattara Nahossé Ziao 《Computational Chemistry》 2017年第1期38-50,共13页
Reliable prediction of lipophilicity in organic compounds involves molecular descriptors determination. In this work, the lipophilicity of a set of twenty-three molecules has been determined using up to eleven quantum... Reliable prediction of lipophilicity in organic compounds involves molecular descriptors determination. In this work, the lipophilicity of a set of twenty-three molecules has been determined using up to eleven quantum various descriptors calculated by means of quantum chemistry methods. According to Quantitative Structure Property Relationship (QSPR) methods, a first set of fourteen molecules was used as training set whereas a second set of nine molecules was used as test set. Calculations made at AM1 and HF/6-311++G theories levels have led to establish a QSPR relation able to predict molecular lipophilicity with over 95% confidence. 展开更多
关键词 MOLECULAR LIPOPHILICITY MOLECULAR Descriptors Quantum Chemistry Statistical Analysis
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Theoretical Determination of Influence of the Metallic State of Oxidation toward Cytotoxic Activity: Case of Ruthenium Complexes 被引量:1
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作者 Bamba Kafoumba Ouattara Wawohinlin Patrice +5 位作者 Diarrassouba Fatogoma Lamoussa Ouattara Massapihanhoro Pierre Ouattara Kouakou Nobel N’guessan Ehouman Ahissan Donatien Ziao Nahossé 《Computational Chemistry》 2021年第2期97-119,共23页
Ruthenium complexes present two states of oxidation that are Ru(II) and Ru(III). Both are assumed to present cytotoxic activity at ground state. On the purpose of highlighting their differences, DFT, TD-DFT and NBO ha... Ruthenium complexes present two states of oxidation that are Ru(II) and Ru(III). Both are assumed to present cytotoxic activity at ground state. On the purpose of highlighting their differences, DFT, TD-DFT and NBO have been performed at both Wb97xd/Lanl2dz and B3lyp/Lanl2dz levels. NBO program shows that both groups of ruthenium complexes present almost the same charge of Ru atom. Moreover, they display nearly the same structure of valence orbitals of the ruthenium. However, when it comes to compare their frontier orbitals HOMO and LUMO, we notice that the chloride atom has a great influence on their energy. The lack of Chloride atoms reduces the energy of frontier orbitals regardless of the functional. And the more the number of chloride atoms, the higher the energy. Also, RuCl<sub>3</sub>Terpy and α-RuCl<sub>2</sub>(Azpy)<sub>2</sub> have been discovered to display the best energy suitable for reaction as cytotoxic agents. Yet, both are from groups different. Thus, at ground state, there is practically no difference between both groups. However, regarding TDDFT prediction with the determination of vertical electronic affinity VEA and vertical ionization potential VIP both at ground state S and at exciting T1 state, we notice that Ru(II) complexes are not active either in the presence or absence of <sup>3</sup>O<sub>2</sub> molecule. Here, only Ru(III) complexes are able to react on Guanine through their radical cations or by generating the superoxide radical anion <img src="Edit_17bbaac1-501f-4de4-bc6b-4f8b513cc344.png" alt="" />. Therefore, the Ru(III) complexes are assumed to be active both at a fundamental state and under the effect of light for photodynamic therapy. We come to conclude that Ru(II) complexes are not active by excitation as their valence electrons are paired thereby making these complexes more stable. Besides, <img src="Edit_30d3bea0-3cbe-4e08-8438-551a2fa7de22.png" alt="" /> , a Ru(II) molecule that is not active at ground state owing certainly to its C<sub>3</sub> symmetry or Azpy ligand presents all the same a difficult activity on generating <img src="Edit_758504e6-51fe-4300-baef-d6a9f1c4f535.png" alt="" /> . For the coming paper, we intend to check whether Ru(II) complex can be active under the effect of light if it is in a triplet charge state. 展开更多
关键词 NBO TD-DFT Ru(II) Ru(III) Photo-Dynamic Therapy (PDT)
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Partial Characterization of Bacteriocins from Two <i>Pediococcus acidilactici</i>Strains Isolated during Traditional Sorghum Beer Processing in Côte d’Ivoire 被引量:1
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作者 Solange Aka-Gbezo Florent Kouadio N’Guessan +2 位作者 Théodore N’Dédé Djeni Marcellin Koffi Djè Bassirou Bonfoh 《Advances in Microbiology》 2014年第16期1250-1259,共10页
Two lactic acid bacteria strains (At1BEAE22 and At344E21) isolated during tchapalo production were identified on the basis of phenotypic analyses. Bacteriocins produced by these strains were tested for their antimicro... Two lactic acid bacteria strains (At1BEAE22 and At344E21) isolated during tchapalo production were identified on the basis of phenotypic analyses. Bacteriocins produced by these strains were tested for their antimicrobial activities using well diffusion agar method. Heat resistance, pH sensitivity and enzyme treatments were also analyzed. Results showed that both lactic acid bacteria strains were identified as Pediococcus acidilactici. Their bacteriocins inhibited growth of Lactobacillus delbrueckii F/31, Listeria innocua ATCC 33090, Enterococcus faecalis, Enterococcus faecalis ATCC 29212, Streptococcus sp, Enterococcus faecalis CIP 105042 and Enterococcus faecium ATCC 51558. These bacteriocins were heat stable at 60&degC for 30 min for all indicator bacteria. However, they remained active only against Lactobacillus delbrueckii and Listeria innocua at 121&degC for 60 min. Moreover, they were active in a wide range of pH (3 to 9) with a maximum activity observed at pH 5 and 6 on all indicator bacteria. But, bacteriocin from Pediococcus acidilactici At34E21 was more stable at acidic pH than basic one. The fact that the bacteriocin was inactivated by proteinase K and α-chymotrypsin indicated its proteinaceous nature, a general characteristics of bacteriocins. 展开更多
关键词 BACTERIOCIN PEDIOCOCCUS acidilactici LACTIC Acid Bacteria Tchapalo Production
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Laterite, Sandstone and Shale as Adsorbents for the Removal of Arsenic from Water 被引量:1
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作者 N’Da Akoua Alice Koua-Koffi Lassina Sandotin Coulibaly +1 位作者 Drissa Sangare Lacina Coulibaly 《American Journal of Analytical Chemistry》 2018年第7期340-352,共13页
This study aims at exploring arsenite (As (III)) removal from water using naturally available rocks (laterite, sandstone and shale) in C?te d’Ivoire. The study focused on the adsorbent dose, operating pH, contact tim... This study aims at exploring arsenite (As (III)) removal from water using naturally available rocks (laterite, sandstone and shale) in C?te d’Ivoire. The study focused on the adsorbent dose, operating pH, contact time, initial arsenite concentration, and modelisation on the removal of arsenite by performing batch adsorption experiment with well water. The optimal dosage related to an initial As (III) concentration of 5 mg/L was about 50, 75 and 145 g/L for laterite, sandstone and shale respectively. Laterite has a better adsorption capacity in comparison to sandstone and shale. On the other hand, kinetic study reveals that the equilibrium times are 5 h for laterite, 3 h for sandstone and 8 h for shale. Results showed that laterite, sandstone and shale could remove the arsenic in groundwater at initial arsenic concentrations below 5 mg/L, satisfying the World Health Organization (WHO) standard for drinking water. Moreover, kinetics study showed that the overall adsorption rate of arsenite was described by the pseudo-second-order kinetic model. 展开更多
关键词 Adsorption ARSENITE REMOVAL LATERITE SANDSTONE SHALE
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Effect of Indigenous Phytase-Producing Yeast Cultures on Growth Performance, Digestion and Health of Rabbits (Oryctolagus cuniculus) 被引量:1
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作者 N’sa Koky Marc Celaire Ake Moussan Désirée Francine +2 位作者 Kimse Moussa Dje Koffi Marcellin Djeni N’Dede Theodore 《Advances in Bioscience and Biotechnology》 2022年第2期73-91,共19页
This study investigated the effects of dietary supplementation of indigenous phytase producing live yeast cultures on growth performance, phytate degradation and blood biochemical parameters of weanling rabbits. Fifty... This study investigated the effects of dietary supplementation of indigenous phytase producing live yeast cultures on growth performance, phytate degradation and blood biochemical parameters of weanling rabbits. Fifty-six rabbits (28 males and 28 females) were allotted randomly into four groups containing a control and three groups administrated each with the yeasts Saccharomyces cerevisiae ADR1B1, Hanseniaspora jakobsenii ADR3E1, Hanseniaspora guilliermondii RD31 during 8 weeks. The results showed that the administration of the three yeast strains accelerated the weight gain and improved rabbits growth performance in comparison to the control group, but did not affect the serum biochemical and hematological parameters. The highest weight gain (1715.95 ± 236 g), and phytate degradation rate (73.82% ± 0.92%) and the lowest biochemical parameters (triglycerides, cholesterol, HDL and LDL) were observed on rabbits fed with the yeast Hanseniaspora jakobsenii ADR3E1. This indigenous yeast species, which is used for the first time in animal feeding provided the best beneficial effects in rabbit breeding. Therefore, based on this finding, Hanseniaspora jakobsenii ADR3E1 can be recommended to supplement rabbit diets for growth performance and profitability enhancement. 展开更多
关键词 Feed Growth Performance Indigenous Yeasts Phytate Digestion RABBIT
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Use of Fluorescence and Reflectance Spectra for Predicting Okra (<i>Abelmoschus esculentus</i>) Yield and Macronutrient Contents of Leaves 被引量:1
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作者 Wilfried G. Dibi Jocelyne Bosson +2 位作者 Irié Casimir Zobi Bi Tra Tié Jérémie T. Zoueu 《Open Journal of Applied Sciences》 2017年第10期537-558,共22页
In-field proximal sensing of most major crops nutrients still remains an economical and technical challenge. For this purpose, the use of effective multi-excitation fluorescence and reflectance wavelengths is explored... In-field proximal sensing of most major crops nutrients still remains an economical and technical challenge. For this purpose, the use of effective multi-excitation fluorescence and reflectance wavelengths is explored in this work on Okra plant. Visible-near infrared (400 - 1000 nm) reflectance and multi-fluorescence data were collected at leaf scale in a chemically fertilized field by using an USB spectrometer mounted with an Arduino-based LED driver clip. N, P, K and Ca content of samples leaves were measured using reference methods. Average pods yield and leaves macronutrients content were calibrated using IRIV-PLS regression after spectra pretreatments. Single informative wavelengths bands in reflectance, red and far-red fluorescences were selected for building yield and macronutrient content models. We showed that flowering stage was more suitable for yield prediction. Moderately useful macronutrient models were found in Ca content (RPDval = 1.93, rP = 0.818) and potassium content with RPDval = 1.8, rP = 0.88. P and N yielding prediction performance of RPDval = 1.61 (rP = 0.718 ) and RPDval = 1.46 (rP = 0.56) respectively were less accurate. This study demonstrates potentiality of fluorescence and reflectance spectroscopy for accurate estimation of leaf macronutrient content and crop yield. High selectivity obtained from resulted spectral bands could lead to the development of reliable, rapid and cost-effective devices for nutrient diagnosis. 展开更多
关键词 Proximal Sensing FLUORESCENCE and Reflectance Fertilized Field MACRONUTRIENTS Content Pods YIELD
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Potential Groundwater Pollution Risks by Heavy Metals from Agricultural Soil in Songon Area(Abidjan,Cote d’Ivoire) 被引量:1
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作者 Innocent K.Kouame Lazare K.Kouassi +5 位作者 Brou Dibi Kouame M.Adou Ioan D.Rascanu Gheorghe Romanescu Issiaka Savane Ion Sandu 《Journal of Environmental Protection》 2013年第12期1441-1448,共8页
The soil samples were collected taking into account the land use in Songon area. The hydraulic conductivity (K) of soils was characterized in-situ when specific yield (Sy), pHw and concentrations of Cooper, Iron, Zinc... The soil samples were collected taking into account the land use in Songon area. The hydraulic conductivity (K) of soils was characterized in-situ when specific yield (Sy), pHw and concentrations of Cooper, Iron, Zinc, Cadmium, Chromium and Lead were measured in the laboratory. Pollution load indices (PLI) were calculated to evaluate the soil contamination levels. The soils were neutral and alkaline (6.7≤ pH ≤ 9.20), permeable (1.9 í 10-5?m·s-1?≤ K ≤ 8.2 í 10-4?m·s-1), with a high specific yield (13.33% ≤ Sy ≤ 33.33%) which can favor the pollutants transfer. The heavy metals (Fe, Cu, Zn, Cd, Cr and Pb) have very high concentrations in soils. The integrated pollution indices (PLI) indicate that almost 70% of Songon soils are moderately contaminated by the investigated heavy metals, with windows presenting high indices of pollution related to the intensive use of fertilizers and pesticides. The establishment of new boreholes in the Songon area should consider these heavy metals, so as to avoid the risk of groundwater pollution due to the physical properties of soils. 展开更多
关键词 Songon SOIL Heavy Metals Pollution Indices Groundwater Pollution Risk ABIDJAN
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Assessment of the Physicochemical Quality of Irrigation Water and Soil for Sustainable Irrigated Rice Cultivation:Case of Irrigated Perimeter of M’Bahiakro(Central-East of Cote d’Ivoire) 被引量:1
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作者 Ruth Bai Innocent K.Kouame +2 位作者 Lazare K.Kouassi Seraphin K.Konan Herve A.N’Cho 《Journal of Environmental Protection》 2019年第11期1536-1552,共17页
This study aims to assess the physico-chemical quality of irrigation water and soil in the irrigated area of M’Bahiakro. Seasonal campaigns to measure in situ the physical parameters (pH, temperature, salinity, elect... This study aims to assess the physico-chemical quality of irrigation water and soil in the irrigated area of M’Bahiakro. Seasonal campaigns to measure in situ the physical parameters (pH, temperature, salinity, electrical conductivity and total dissolved solids) of the N’Zi River were carried out, followed by sampling (water and soil) for chemical analyses. The physico-chemical quality of irrigation water was assessed on the basis of four (4) parameters, namely Dry Residue (SR), Osmotic Pressure (π), Kelly Coefficient (KCR), Sodium Absorption Rate (SAR) and Wilcox Diagram. In terms of soil quality, the parameters (pH, N, P, P, K, MO, CEC and ESP) were determined. Overall, the results show a good physical-chemical quality of the irrigation water and soil. Indeed, the irrigation waters studied show good physico-chemistry and low to medium salinity depending on the seasons of the year. As for the soils, they have a clayey-silt texture, a slightly acidic pH, favourable to rice cultivation and a good organic matter content, which best maintains an active microbial life. In addition, the major elements (nitrogen, phosphorus and potassium) present in irrigation water and soils could be enough to optimize the yield of rice cultivation. These results then lead to the conclusion that the irrigation water from the N’Zi River and the soils of the irrigated perimeter of M’Bahiakro are naturally suitable for agricultural use, particularly for rice cultivation. As a result, an additional supply of fertilizer (NPK) would not necessarily be necessary during the exploitation phase of the rice area. 展开更多
关键词 IRRIGATION Sustainable Rice Cultivation Water and Soil Management M’Bahiakro
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