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Interfacial reaction between AZ91D magnesium alloy melt and mild steel under high temperature 被引量:1
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作者 Jia-hong Dai Jian-yue Zhang +5 位作者 Bin Jiang Xiang-jun Xu Zhong-tao Jiang Hong-mei Xie Qing-shan Yang Guo-qing Zhang 《China Foundry》 SCIE EI CAS CSCD 2024年第2期159-167,共9页
The metallurgical quality control of magnesium(Mg)and Mg alloys in melting process is required to ensure a satisfied mechanical and corrosion performance,while the typical used steel crucible introduces impurities and... The metallurgical quality control of magnesium(Mg)and Mg alloys in melting process is required to ensure a satisfied mechanical and corrosion performance,while the typical used steel crucible introduces impurities and interfacial interaction during melting process.Therefore,a systematic study about impurities diffusion and interfacial interaction between molten Mg and steel is necessary.In the present study,the interfacial reaction between molten AZ91D Mg alloy and mild steel during melting process was investigated with the melting temperatures of 700℃,750℃ and 800℃.The results show that Al(Fe,Mn)intermetallic layer is the intermetallic primarily formed at the interfaces of AZ91D melt and mild steel.Meanwhile,Al_(8)(Mn,Fe)5is indexed between Al(Fe,Mn)and AZ91D.AlFe_(3)C appears between the mild steel and Al(Fe,Mn)at 700℃ and 750℃,but absent at 800℃ due to the increased solubility of carbon in Mg matrix.It is found that the growth of the intermetallic layer is controlled by diffusion mechanism,and Al and Mn are the dominant diffusing species in the whole interfacial reaction process.By measuring the thickness of different layers,the growth constant was calculated.It increases from 1.89(±0.03)×10^(-12)m^(2)·s^(-1)at 700℃ to 3.05(±0.05)×10^(-12)m^(2)·s^(-1)at 750℃,and 5.18(±0.05)×10^(-12)m^(2)·s^(-1)at 800℃.Meanwhile,the content of Fe is linearly increased in AZ91D with the increase of holding time at 700℃ and 750℃,while it shows a significantly increment after holding for 8 h at 800℃,indicating holding temperature is more crucial to determine the Fe content of AZ91D than holding time. 展开更多
关键词 AZ91D mild steel interface reaction intermetallic growth KINETICS
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High-throughput screening system of citrus bacterial cankerassociated transcription factors and its application to the regulation of citrus canker resistance
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作者 Jia Fu Jie Fan +8 位作者 Chenxi Zhang Yongyao Fu Baohang Xian Qiyuan Yu Xin Huang Wen Yang Shanchun Chen Yongrui He Qiang Li 《Journal of Integrative Agriculture》 SCIE CSCD 2024年第1期155-165,共11页
One of the main diseases that adversely impacts the global citrus industry is citrus bacterial canker(CBC),caused by the bacteria Xanthomonas citri subsp.citri(Xcc).Response to CBC is a complex process,with both prote... One of the main diseases that adversely impacts the global citrus industry is citrus bacterial canker(CBC),caused by the bacteria Xanthomonas citri subsp.citri(Xcc).Response to CBC is a complex process,with both proteinDNA as well as protein–protein interactions for the regulatory network.To detect such interactions in CBC resistant regulation,a citrus high-throughput screening system with 203 CBC-inducible transcription factors(TFs),were developed.Screening the upstream regulators of target by yeast-one hybrid(Y1H)methods was also performed.A regulatory module of CBC resistance was identified based on this system.One TF(CsDOF5.8)was explored due to its interactions with the 1-kb promoter fragment of CsPrx25,a resistant gene of CBC involved in reactive oxygen species(ROS)homeostasis regulation.Electrophoretic mobility shift assay(EMSA),dual-LUC assays,as well as transient overexpression of CsDOF5.8,further validated the interactions and transcriptional regulation.The CsDOF5.8–CsPrx25 promoter interaction revealed a complex pathway that governs the regulation of CBC resistance via H2O2homeostasis.The high-throughput Y1H/Y2H screening system could be an efficient tool for studying regulatory pathways or network of CBC resistance regulation.In addition,it could highlight the potential of these candidate genes as targets for efforts to breed CBC-resistant citrus varieties. 展开更多
关键词 citrus bacterial canker(CBC) high-throughput screening system transcription factor(TF) yeast-one hybrid(Y1H) CsPrx25
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Exploring the Dynamics of Industrial Convergence Among RCEP Member Countries: An Empirical Study
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作者 Zheng Yuanfang 《Contemporary Social Sciences》 2024年第5期26-50,共25页
The evolving dynamics of industrial convergence among the member countries of the Regional Comprehensive Economic Partnership(RCEP)framework have emerged as a significant subject that merits in-depth consideration and... The evolving dynamics of industrial convergence among the member countries of the Regional Comprehensive Economic Partnership(RCEP)framework have emerged as a significant subject that merits in-depth consideration and analysis.This study initially employs multi-regional input-output(MRIO)data and the social network analysis(SNA)method to delineate the levels and variation trends of this industrial convergence across the RCEP member countries.It then delves into the positive effects of this convergence phenomenon on the trade and investment fields of the member countries.The research findings indicate:(a)In 2006 and 2015,before the implementation of the RCEP,the RCEP member countries displayed a relatively close industrial convergence.The convergence levels exhibited a general upward trend on both the supply and the demand sides,but there were significant disparities in the levels of industrial convergence among the member countries.Furthermore,while the convergence in the three economic sectors showed an increasing trend,the development was uneven across the board.(b)Since the implementation of the RCEP,the trade ties among the member countries within the region have strengthened significantly,and the interplay between the countries’industrial and supply chains has been characterized by high-quality collaboration and demonstrated remarkable resilience.In addition,the convergence in the investment fields of the RCEP member countries and their respective industries has unleashed a wave of positive synergies.These findings offer valuable insights that can serve as a robust foundation for formulating effective policies to advance the growth and prosperity of the RCEP region. 展开更多
关键词 RCEP international industrial convergence input-output table social network analysis method
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Extractive distillation: Advances in conceptual design, solvent selection,and separation strategies 被引量:11
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作者 Shirui Sun Liping Lü +2 位作者 Ao Yang Shun'an Wei Weifeng Shen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第6期1247-1256,共10页
Extractive distillation(ED) is one of the most promising approaches for the separation of the azeotropic or closeboiling mixtures in the chemical industry. The purpose of this paper is to provide a broad overview of t... Extractive distillation(ED) is one of the most promising approaches for the separation of the azeotropic or closeboiling mixtures in the chemical industry. The purpose of this paper is to provide a broad overview of the recent development of key aspects in the ED process involving conceptual design, solvent selection, and separation strategies. To obtain the minimum entrainer feed flow rate and reflux ratio for the ED process, the conceptual design of azeotropic mixture separation based on a topological analysis via thermodynamic feasibility insights involving residue curve maps, univolatility lines, and unidistribution curves is presented. The method is applicable to arbitrary multicomponent mixtures and allows direct screening of design alternatives. The determination of a suitable solvent is one of the key steps to ensure an effective and economical ED process. Candidate entrainers can be obtained from heuristics or literature studies while computer aided molecular design(CAMD) has superiority in efficiency and reliability. To achieve optimized extractive distillation systems, a brief review of evaluation method for both entrainer design and selection through CAMD is presented. Extractive distillation can be operated either in continuous extractive distillation(CED) or batch extractive distillation(BED), and both modes have been well-studied depending on the advantages in flexibility and low capital costs. To improve the energy efficiency, several configurations and technological alternatives can be used for both CED and BED depending on strategies and main azeotropic feeds. The challenge and chance of the further ED development involving screening the best potential solvents and exploring the energy-intensive separation strategies are discussed aiming at promoting the industrial application of this environmentally friendly separation technique. 展开更多
关键词 Extractive DISTILLATION SEPARATION STRATEGIES SOLVENT selection CONCEPTUAL design
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Determination of trace elements in high purity nickel by high resolution inductively coupled plasma mass spectrometry 被引量:11
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作者 聂西度 梁逸曾 +1 位作者 唐有根 谢华林 《Journal of Central South University》 SCIE EI CAS 2012年第9期2416-2420,共5页
The contents ofMg, Al, Si, Ti, Cr, Mn, Fe, Co, Cu, Ga, As, Se, Cd, Sb, Pb and Bi in high purity nickel were determined by high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS). The sample was diss... The contents ofMg, Al, Si, Ti, Cr, Mn, Fe, Co, Cu, Ga, As, Se, Cd, Sb, Pb and Bi in high purity nickel were determined by high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS). The sample was dissolved in HNO3 and HCI by microwave digestion. Most of the spectral interferences could be avoided by measuring in the high resolution mode. The matrix effects because of the presence of excess HC1 and nickel were evaluated. Correction for matrix effects was made using Sc, Rh and T1 as internal standards. The optimum conditions for the determination were tested and discussed. The detection limits range from 0.012 to 1.76 ~tg/g depending on the type of elements. The applicability of the proposed method is also validated by the analysis of high purity nickel reference material (NIST SRM 671). The relative standard deviation (RSD) is less than 3.3%. Results for determination of trace elements in high purity nickel were presented. 展开更多
关键词 high resolution inductively coupled plasma mass spectrometry high purity nickel trace element matrix effect internal standard
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Comparison of continuous homogenous azeotropic and pressure-swing distillation for a minimum azeotropic system ethyl acetate/nhexane separation 被引量:6
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作者 Liping Lü Lin Zhu +2 位作者 Huimin Liu Hang Li Shirui Sun 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第10期2023-2033,共11页
Continuous homogenous azeotropic distillation(CHAD) and pressure-swing distillation(PSD) are explored to separate a minimum-boiling azeotropic system of ethyl acetate and n-hexane. The CHAD process with acetone as the... Continuous homogenous azeotropic distillation(CHAD) and pressure-swing distillation(PSD) are explored to separate a minimum-boiling azeotropic system of ethyl acetate and n-hexane. The CHAD process with acetone as the entrainer and the PSD process with the pressures of 0.1 MPa and 0.6 MPa in two columns are designed and simulated by Aspen Plus. The operating conditions of the two processes are optimized via a sequential modular approach to obtain the minimum total annual cost(TAC). The computational results show that the partially heat integrated pressure-swing distillation(HIPSD) has reduced in the energy cost and TAC by 40.79% and 35.94%, respectively, than the conventional PSD, and has more greatly reduced the energy cost and TAC by 62.61% and 49.26% respectively compared with the CHAD process. The comparison of CHAD process and partially HIPSD process illustrates that the partially HIPSD has more advantages in averting the product pollution, energy saving, and economy. 展开更多
关键词 Continuous homogenous azeotropic distillation Pressure-swing distillation Ethyl acetate/n-hexane Azeotrope
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Support effect of the supported ceria-based catalysts during NH_3-SCR reaction 被引量:17
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作者 Xiaojiang Yao Li Chen +3 位作者 Tingting Kong Shimin Ding Qiong Luo Fumo Yang 《Chinese Journal of Catalysis》 CSCD 北大核心 2017年第8期1423-1430,共8页
To investigate how the physicochemical properties and NH3‐selective catalytic reduction(NH3‐SCR)performance of supported ceria‐based catalysts are influenced as a function of support type,a series of CeO2/SiO2,CeO2... To investigate how the physicochemical properties and NH3‐selective catalytic reduction(NH3‐SCR)performance of supported ceria‐based catalysts are influenced as a function of support type,a series of CeO2/SiO2,CeO2/γ‐Al2O3,CeO2/ZrO2,and CeO2/TiO2catalysts were prepared.The physicochemical properties were probed by means of X‐ray diffraction,Raman spectroscopy,Brunauer‐Emmett‐Teller surface area measurements,X‐ray photoelectron spectroscopy,H2‐temperature programmed reduction,and NH3‐temperature programmed desorption.Furthermore,the supported ceria‐based catalysts'catalytic performance and H2O+SO2tolerance were evaluated by the NH3‐SCR model reaction.The results indicate that out of the supported ceria‐based catalysts studied,the CeO2/γ‐Al2O3catalyst exhibits the highest catalytic activity as a result of having a high relative Ce3+/Ce4+ratio,optimum reduction behavior,and the largest total acid site concentration.Finally,the CeO2/γ‐Al2O3catalyst also presents excellent H2O+SO2tolerance during the NH3‐SCR process. 展开更多
关键词 Support effect Supported ceria‐based catalyst Reduction behavior Surface acidity Ammonia‐selective catalytic reduction
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Discharge properties of Mg-Sn-Y alloys as anodes for Mg-air batteries 被引量:8
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作者 Hua-bao Yang Liang Wu +7 位作者 Bin Jiang Bin Lei Ming Yuan Hong-mei Xie Andrej Atrens Jiang-feng Song Guang-sheng Huang Fu-sheng Pan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2021年第10期1705-1715,共11页
Mg-Sn-Y alloys with different Sn contents(wt%)were assessed as anode candidates for Mg-air batteries.The relationship between microstructure(including the second phase,grain size,and texture)and discharge properties o... Mg-Sn-Y alloys with different Sn contents(wt%)were assessed as anode candidates for Mg-air batteries.The relationship between microstructure(including the second phase,grain size,and texture)and discharge properties of the Mg-Sn-Y alloys was examined using microstructure observation,electrochemical measurements,and galvanostatic discharge tests.The Mg-0.7Sn-1.4Y alloy had a high steady discharge voltage of 1.5225 V and a high anodic efficiency of 46.6% at 2.5 mA·cm^(-2).These good properties were related to its microstructure:small grain size of 3.8μm,uniform distribution of small second phase particles of 0.6μm,and a high content(vol%)of(1120)/(1010)orientated grains.The scanning Kelvin probe force microscopy(SKPFM)indicated that the Sn_(3)Y_(5) and MgSnY phases were effective cathodes causing micro-galvanic corrosion which promoted the dissolution of Mg matrix during the discharge process. 展开更多
关键词 magnesium-stannum-yttrium alloy microstructure micro-galvanic corrosion discharge properties magnesium-air battery
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Characters and Species Diversity of Torreya fargesii Franch. Community in the Jinfo Mountains 被引量:10
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作者 JIANG Bo WANG Jianhua +1 位作者 SHANG Jin ZHOU Xianrong 《Journal of Landscape Research》 2016年第2期71-74,共4页
This paper aims to study characteristics and biodiversity of the Torreya fargesii community in the Jinfo Mountains to provide baseline information related to the protection of T. fargesii. The results indicated that a... This paper aims to study characteristics and biodiversity of the Torreya fargesii community in the Jinfo Mountains to provide baseline information related to the protection of T. fargesii. The results indicated that among the 5 plots(100 m2 each) set along an altitudinal gradient, 176 species of vascular plants, 136 genera and 64 families were recorded. These included 7 species of pteridophytes, 6 genera and 4 families, 3 species of gymnosperms, 3 genera and 2 families, and 166 species of angiosperms, 127 genera and 58 families. The community physiognomy was mainly dominated by phanerophytes with medium-sized herbaceous and simple leaves. The proportions of phanerophytes among the fl oristic spectrum, frequency spectrum and vegetational spectrum are 68.75%, 73.13% and 67.48% respectively. The vertical structure can be divided into the shrub and herb layers in this community. The dominant species in shrub layer were T. fargesii, Zanthoxylum ovalifolium, Rubus coreanus, Kerria japonica, Cotoneaster horizontalis etc.. The dominant herbs included Miscanthus sinensis, Carex gibba, Artemisia lactifl ora, Pteridium aquilinum var. latiusculum, Pilea notata, Aster ageratoides etc.. Species richness(S) and the Simpson(D), Shannon-Wiener(H') and Pielou evenness(Jsw) indices of shrub layer species richness are higher than those of the herb layer; the distribution of the species in the community is obviously uneven. The species richness and diversity indices increase with the rising altitude. 展开更多
关键词 Torreya fargesii Franch Community character Species diversity the Jinfo Mountains
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ZnIn_2S_4 flowerlike microspheres embedded with carbon quantum dots for efficient photocatalytic reduction of Cr(Ⅵ) 被引量:7
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作者 Baibai Liu Xinjuan Liu +6 位作者 Lei Li Jianwei Li Can Li Yinyan Gong Lengyuan Niu Xinsheng Zhao Chang Q.Sun 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第12期1901-1909,共9页
Development of efficient heterostructured photocatalysts that respond to visible light remains a considerable challenge.We herein show the synthesis of ZnIn2S4/carbon quantum dot hybrid photocatalysts with flowerlike ... Development of efficient heterostructured photocatalysts that respond to visible light remains a considerable challenge.We herein show the synthesis of ZnIn2S4/carbon quantum dot hybrid photocatalysts with flowerlike microspheres via a facile solvothermal method.The ZnIn2S4/carbon quantum dot flowerlike microspheres display enhanced photocatalytic and photoelectrochemical activity compared with that of pure ZnIn2S4.With a content of only 0.5 wt%carbon quantum dots,93%of Cr(VI)is reduced under visible‐light irradiation at 40 min.As a co‐catalyst,the carbon quantum dots improve the light absorption and lengthen the lifetime of charge carriers,consequently enhancing the photocatalytic and photoelectrochemical activity. 展开更多
关键词 ZnIn2S4 Carbon quantum dots Flowerlike microspheres Co‐catalyst Photoelectronchemical
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Allelopathic Effects of Aqueous Extract of Torreya fargesii Aril on Seed Germination and Seedling Growth of Radish, Mustard and Cabbage 被引量:6
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作者 Xiaoling XIE Bo JIANG +3 位作者 Xianrong ZHOU Lianxue ZHAO Jianhua WANG Jin HANG 《Agricultural Biotechnology》 CAS 2016年第4期11-17,共7页
[Objective] This study aimed to investigate the allelopathic effects of Torreya fargesii aril. [Method] By indoor bioassay, the effects of different con-centrations (10, 20,40, 80 g/L) of aqueous extract of T... [Objective] This study aimed to investigate the allelopathic effects of Torreya fargesii aril. [Method] By indoor bioassay, the effects of different con-centrations (10, 20,40, 80 g/L) of aqueous extract of T. fargesii aril on seed germination rate, seedling root length, seedling height, fresh weight, chlorophyll content, malondialdehyde (MDA) content and anti oxidative enzyme activities of radish, mustard and cabbage were analyzed and compared. [ Result] Different concentrations of aqueous extract of T. fargesii aril inhibited seed germination and seedling growth of three crops, and the inhibitory effects were enhanced with the increase of concentration. Seedling height and fresh weight of three crops were improved by low concentrations of aqueous extract of T. fargesii aril and inhibited by high concentrations of aqueous extract. Overall, aqueous extract of T. fargesii aril exhibited allelopathic inhibitory effects on three crops, and the level of allelopath-ic inhibitory effects demonstrated a descending order of radish 〉 mustard 〉 cabbage. Compared with the control group, 80 g/L aqueous extract of T. fargesii aril almost significantly reduced seed germination rate, seedling root length, seedling height, fresh weight and chlorophyll content, and significantly improved MDA con-tent and antioxidative enzyme (SOD, CAT, POD) activities of radish, mustard and cabbage (P 〈 0 .0 5 ) . [ Conclusion] Aqueous extract of T. fargesii aril exhibited remarkable allelopathic inhibitory effects on seed germination of radish, mustard and cabbage, which indicated that there might be dormancy-associated germination in-hibiting allelochemicals in T. fargesii aril. This study provided theoretical basis for subsequent clarification of the mechanism of seed dormancy of T. fargesii. 展开更多
关键词 Torreya fargesii Franch. ARIL Aqueous extract Seed germination Allelopathic effect
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COF-based single Li^(+)solid electrolyte accelerates the ion diffusionandrestrains dendritegrowthin quasi-solid-state organic batteries 被引量:4
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作者 Genfu Zhao Zhiyuan Mei +5 位作者 Lingyan Duan Qi An Yongxin Yang Conghui Zhang Xiaoping Tan Hong Guo 《Carbon Energy》 SCIE CSCD 2023年第2期171-183,共13页
A solid-state electrolyte(SSE),which is a solid ionic conductor and electroninsulating material,is known to play a crucial role in adapting a lithium metal anode to a high-capacity cathode in a solid-state battery.Amo... A solid-state electrolyte(SSE),which is a solid ionic conductor and electroninsulating material,is known to play a crucial role in adapting a lithium metal anode to a high-capacity cathode in a solid-state battery.Among the various SSEs,the single Li-ion conductor has advantages in terms of enhancing the ion conductivity,eliminating interfacial side reactions,and broadening the electrochemical window.Covalent organic frameworks(COFs)are optimal platforms for achieving single Li-ion conduction behavior because of wellordered one-dimensional channels and precise chemical modification features.Herein,we study in depth three types of Li-carboxylate COFs(denoted LiOOC-COFn,n=1,2,and 3)as single Li-ion conducting SSEs.Benefiting from well-ordered directional ion channels,the single Li-ion conductor LiOOC-COF3 shows an exceptional ion conductivity of 1.36×10^(-5) S cm^(-1) at room temperature and a high transference number of 0.91.Moreover,it shows excellent electrochemical performance with long-term cycling,high-capacity output,and no dendrites in the quasi-solid-state organic battery,with the organic small molecule cyclohexanehexone(C_(6)O_(6))as the cathode and the Li metal as the anode,and enables effectively avoiding dissolution of the organic electrode by the liquid electrolyte. 展开更多
关键词 covalent organic frameworks quasi-solid-state organic battery single Li-ion conductor solid-state electrolyte
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Tribological behaviors of graphene oxide partly substituted with nano-SiO_(2) as lubricant additives in water for magnesium alloy/steel interfaces 被引量:3
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作者 Hongmei Xie Jiahong Dai Dan Zhou 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2022年第7期1425-1434,共10页
Although graphene oxide(GO)has emerged as an excellent lubricant additive in water,there remain great challenges in their practical application due to high production costs.By taking into account the low cost and also... Although graphene oxide(GO)has emerged as an excellent lubricant additive in water,there remain great challenges in their practical application due to high production costs.By taking into account the low cost and also its excellent tribological properties,it is likely that nano-SiO_(2)can be used as a lubricant additive to partially replace GO.Hence,this paper aims to explore the tribological properties of nano-SiO_(2)incorporated in GO nanofluids for partial GO replacement by investigating the friction coefficient and wear volume of the prepared SiO_(2)/GO hybrid nanofluids for magnesium alloy/steel sliding pairs.The experiments reveal that the SiO_(2)/GO hybrids retain low friction coefficients as compared to individual GO or SiO_(2)at all test conditions in this study.However,as for the bearing capacity test,all samples can provide a low wear volume under the loads of 1 and 3 N.With the increase of the normal load,there is considerable differences in the anti-wear behavior.Compared with that of individual GO nanofluids,the wear volume of the GO/SiO_(2)(mass ratio of 0.3:0.2)hybrid nanofluids was reduced by50.5%at 5 N and by 49.2%at 8 N.Furthermore,the wear volume of the GO/SiO_(2)(mass ratio of 0.3:0.2)hybrid nanofluids was reduced by46.3%under the rigorous conditions,as compared to individual GO nanofluids.The findings provide new insights into developing carbon nanomaterial-based hybrid nanofluids for magnesium alloy formation. 展开更多
关键词 magnesium alloy graphene oxide and nano-silicon dioxide water-based lubricant additive tribological characteristics
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Risk assessment of water inrush in tunnels based on attribute interval recognition theory 被引量:4
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作者 WANG Sheng LI Li-ping +3 位作者 CHENG Shuai HU Hui-jiang ZHANG Ming-guang WEN Tao 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第2期517-530,共14页
Water inrush is one of the most serious geological hazards in underground engineering construction.In order to effectively prevent and control the occurrence of water inrush,a new attribute interval recognition theory... Water inrush is one of the most serious geological hazards in underground engineering construction.In order to effectively prevent and control the occurrence of water inrush,a new attribute interval recognition theory and method is proposed to systematically evaluate the risk of water inrush in karst tunnels.Its innovation mainly includes that the value of evaluation index is an interval rather than a certain value;the single-index attribute evaluation model is improved non-linearly based on the idea of normal distribution;the synthetic attribute interval analysis method based on improved intuitionistic fuzzy theory is proposed.The TFN-AHP method is proposed to analyze the weight of evaluation index.By analyzing geological factors and engineering factors in tunnel zone,a multi-grade hierarchical index system for tunnel water inrush risk assessment is established.The proposed method is applied to ventilation incline of Xiakou tunnel,and its rationality and practicability is verified by comparison with field situation and evaluation results of other methods.In addition,the results evaluated by this method,which considers that water inrush is a complex non-linear system and the geological conditions have spatial variability,are more accurate and reliable.And it has good applicability in solving the problem of certain and uncertain problem. 展开更多
关键词 water inrush risk assessment attribute interval recognition model TFN-AHP
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Polycrystalline cubic boron nitride prepared with cubic-hexagonal boron nitride under high pressure and high temperature 被引量:4
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作者 Ming Yang Zi-Li Kou +8 位作者 Teng Liu Jing-Rui Lu Fang-Ming Liu Yin-Juan Liu Lei Qi Wei Ding Hong-Xia Gong Xiao-Lin Ni Duan-Wei He 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第5期424-429,共6页
Polycrystalline cubic boron nitride(Pc BN)compacts,using the mixture of submicron cubic boron nitride(c BN)powder and hexagonal BN(h BN)powder as starting materials,were sintered at pressures of 6.5–10.0 GPa and temp... Polycrystalline cubic boron nitride(Pc BN)compacts,using the mixture of submicron cubic boron nitride(c BN)powder and hexagonal BN(h BN)powder as starting materials,were sintered at pressures of 6.5–10.0 GPa and temperature of1750℃without additives.In this paper,the sintering behavior and mechanical properties of samples were investigated.The XRD patterns of samples reveal that single cubic phase was observed when the sintering pressure exceeded 7.5 GPa and h BN contents ranged from 20 vol.%to 24 vol.%,which is ascribed to like-internal pressure generated at grain-to-grain contact under high pressure.Transmission electron microscopy(TEM)analysis shows that after high pressure and high temperature(HPHT)treatments,the submicron c BN grains abounded with high-density nanotwins and stacking faults,and this contributed to the outstanding mechanical properties of Pc BN.The pure bulk Pc BN that was obtained at 7.7 GPa/1750℃possessed the outstanding properties,including a high Vickers hardness(~61.5 GPa),thermal stability(~1290℃in air),and high density(~3.46 g/cm^(3)). 展开更多
关键词 PcBN compact high temperature and high pressure sintering PcBN without additive
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Effect of Cr, Mo, and Nb additions on intergranular cohesion of ferritic stainless steel: First-principles determination 被引量:3
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作者 李春霞 党随虎 +2 位作者 王丽萍 张彩丽 韩培德 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第3期457-462,共6页
Effects of Cr, Mo, and Nb on the ferritic stainless steel ]2(210) grain boundary and intragranularity are investigated using the first-principles principle. Different positions of solute atoms are considered. Struct... Effects of Cr, Mo, and Nb on the ferritic stainless steel ]2(210) grain boundary and intragranularity are investigated using the first-principles principle. Different positions of solute atoms are considered. Structural stability is lowered by Cr doping and enhanced by Mo and Nb doping. A ranking on the effect of solute atoms enhancing the cohesive strength of the grain boundary, from the strongest to the weakest is Cr, Mo, and Nb. Cr clearly prefers to locate in the intragranular region of Fe rather than in the grain boundary, while Mo and Nb tend to segregate to the grain boundary. Solute Mo and Nb atoms possess a strong driving force for segregation to the grain boundary from the intragranular region, which increases the grain boundary embrittlement. For Mo- and Nb-doped systems, a remarkable quantity of electrons accumulate in the region close to Mo (Nb). Therefore, the bond strength may increase. With Cr, Mo, and Nb additions, an anti-parallel island is formed around the center of the grain boundary. 展开更多
关键词 first-principles principle grain boundary cohesion electronic properties ferritic stainless steel
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Determination of trace impurity elements in MnZn ferrite powder by direct current glow discharge mass spectrometry 被引量:3
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作者 FU Liang MA Jun-cai SHI Shu-yun 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第7期1590-1597,共8页
An analytical method for the determination of 26 impurity elements (such as Li, Be, Na, Mg, Al, Si, P, S, K, Ca, Sc, Ti, V, Cr, Co, Ni, Ga, Ge, Y, Nb, Mo, Ag, Cd, Sb, W and Pb) in MnZn ferrite powder by direct curre... An analytical method for the determination of 26 impurity elements (such as Li, Be, Na, Mg, Al, Si, P, S, K, Ca, Sc, Ti, V, Cr, Co, Ni, Ga, Ge, Y, Nb, Mo, Ag, Cd, Sb, W and Pb) in MnZn ferrite powder by direct current glow discharge mass spectrometry (GD-MS) was established. MnZn ferrite powder was mixed with copper powder, used as a conductor, and pressed. The effects of MnZn ferrite powder preparation conditions and glow discharge parameters for the sensitivity and stability of signal analysis were investigated. By determining the choice of isotope and the application of the mass resolutions of 4000 (MR, medium resolution) and 10000 (HR, high resolution), mass spectral interference was eliminated. The contents of impurity elements in MnZn ferrite powder was calculated by subtraction after normalizing the total signal of Mn, Zn, Fe, O and Cu. The results showed that the detection limit of 26 kinds of impurity elements was between 0.002 and 0.57 μg/g, and the relative standard deviation (RSD) was between 3.33% and 32.35%. The accuracy of this method was verified by the ICP-MS. The method was simple and practical, which is applied to the determination of impurity elements in MnZn ferrite powder. 展开更多
关键词 MnZn ferrite powder glow discharge mass spectrometry impurity elements copper powder
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Trace amounts of impurities in electrolytic manganese metal by sector field inductively coupled plasma mass spectrometry 被引量:2
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作者 聂西度 梁逸曾 +1 位作者 唐有根 谢华林 《Journal of Central South University》 SCIE EI CAS 2013年第12期3385-3390,共6页
An analytical method, using sector field inductively coupled plasma mass spectrometry (SF-ICP-MS) for rapid simultaneous determination of Be, Na, Mg, Si, Ca, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, As, Sn, Sb, Pb and Bi in e... An analytical method, using sector field inductively coupled plasma mass spectrometry (SF-ICP-MS) for rapid simultaneous determination of Be, Na, Mg, Si, Ca, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, As, Sn, Sb, Pb and Bi in electrolytic manganese metal, was described. At the beginning, the samples were decomposed by HNO3 and H2504, and then analyzed by SF-ICP-MS. Most of the spectral interferences could be avoided by measuring in different mass resolution modes. The matrix effects due to the excess of sulfuric acid and Mn were evaluated. Correction of matrix effects was conducted by using the internal standard elements. The optimum condition for the determination was investigated and discussed. The detection limit is in the range of 0.001-0.169 gg/L. The current method is applied to the determination of trace impurities in electrolytic manganese metal. And experiments show that good results can be obtained much faster, more accurately and conveniently by current method. 展开更多
关键词 sector field inductively coupled plasma mass spectrometry electrolytic manganese IMPURITIES spectral interferences matrix effects
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Cloning and characterization of proliferating cell nuclear antigen gene of Alexandrium catenella (Dinoflagellate) with respect to cell growth 被引量:2
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作者 HUANG Jian LIANG Shan +2 位作者 SUI Zhenghong MAO Yunxiang GUO Hao 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2010年第3期90-96,共7页
Harmful algal blooms (HABs) have been affecting negatively the shellfish and aquaculture industries around the world. Though a lot of efforts have been made to disclose the changes of environmental factors involved ... Harmful algal blooms (HABs) have been affecting negatively the shellfish and aquaculture industries around the world. Though a lot of efforts have been made to disclose the changes of environmental factors involved and their effects on the HABs events, the molecular mechanism of this process remains unclear. To address this problem, proliferating cell nuclear antigen gene (pcna) was isolated and characterized from Alexandrium catenella. It showed high homology to those of other dinoflagellates (89% and 91% homology to Pfiesteria piscicid and Pyrocystis lunula, respectively), and also 42%–43% homology to those of plant and animals. The expression level of pcna revealed by quantitative real time PCR was the lowest at the late lagging cell growth phase, increased to the highest at the late exponential phase, and then decreased at the stationary phase. Though the cell growth rate was also changing, no positive correlation between pcna expression level and cell growth rate was displayed throughout the whole cell growth stages (r 2 =0.024 6). However, the pcna expression level had the similar trend with the change of cell growth rate throughout the whole growing process, e.g., from increasing at the earlier cell growth stage to decreasing at the following stages, though slightly lagging to the latter. 展开更多
关键词 Alexandrium catenella GENE GROWTH harmful algal blooms proliferating cell nuclear antigen
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Responses of Leaf Functional Traits of Torreya fargesii to the Altitudinal Variation 被引量:3
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作者 Jin SHANG Bo JIANG +3 位作者 Yonghong ZHENG Jianhua WANG Xianrong ZHOU Jianhui LI 《Agricultural Science & Technology》 CAS 2017年第11期2179-2184,共6页
[Objective] To reveal the leaf functional traits and adaptive strategy of Torreya fargesii at different altitude gradients.[Method] Leaves of T. fargesii were selected from the altitudes of 1 570, 1 700, 1 900, 2 125 ... [Objective] To reveal the leaf functional traits and adaptive strategy of Torreya fargesii at different altitude gradients.[Method] Leaves of T. fargesii were selected from the altitudes of 1 570, 1 700, 1 900, 2 125 and 2 360 m in Jiajinshan forest area of Sichuan Baoxing County, and the altitudes of 1 000, 1 200, 1 450, and 1 700 m in Hua'eshan Mountain Nature Reserve of Sichuan Wanyuan County as the research materials. Leaf blade traits such as leaf length, leaf width, leaf girth, leaf area and leaf dry weight were determined, and the influence of altitude on each index and correlation between characters were analyzed. [Result] For the leaves from both Baoxing County and Wanyuan County, leaf length, leaf width, leaf girth, leaf aspect ratio and leaf area decreased with the increase of altitude. There was no significant difference in the changes of leaf width, leaf girth and leaf aspect ratio among different altitudes(P>0.05), while the difference was significant in leaf length between high altitude and low attitude(P<0.05), and the difference was also significant in leaf area for the leaves from Baoxing County between high altitude and low altitude. However, there was no obvious correlation between leaf width and altitude, which could be considered as a relatively stable parameter. Leaf thickness and leaf dry weight increased first and then decreased with altitude,while the specific leaf area decreased first and then increased. In leaf length, leaf girth, leaf width and leaf area parameters, except for leaf width and leaf area for the T. fargesii from Wanyuan County, any two parameters reached significant or very significant positive correlation level(P<0.01). Leaf dry weight and leaf thickness had significant or very significant positive correlation, leaf dry weight and leaf area had a certain positive correlation but not significant. There existed no significant positive correlation between specific leaf area and leaf area, while specific leaf area was in negative correlation with leaf dry weight, and the negative correlation of specific leaf area with leaf area of T. fargesii from Wanyuan County reached the significant level.[Conclusion] T. fargesii adapted to different altitudes by changing leaf dry weight, leaf area and leaf area ratio, and the most suitable altitudes for the growth of T. fargesii were 1 900 and 1 450 m in Baoxing and Wanyuan area respectively. 展开更多
关键词 Torreya fargesii Franch. Altitude gradient Leaf traits CORRELATION
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