Preparation and Swelling Kinetic Analysis of Poly (HPMC-co-AA-co-AM) Super Absorbent Resin

Super absorbent resin(SAR)is prepared by aqueous high temperature polymerization using hydroxypropyl methylcellulose(HPMC)as monomer backbone material,acrylic acid(AA)and acrylamide(AM)as the graft copolymer monomer,potassium persulfate(KPS)as the initiator to generate free radicals,and N,N`-methylenebisacrylamide(MBA)as cross-linking agent for cross-linking reaction.Simutaneously,the influence of individual factors on the water absorption is investigated,and these factors are mainly AA,AM,KPS,MBA,HPMC,and reaction temperature.The optimized conditions are obtained by the experiment repeating for several times.The water absorption multiplicity and salt absorption multiplicity under the conditions are 782.4 and 132.5 g/g,respectivity.Furthermore,the effects of different temperatures and salt concentrations on its water absorption,as well as the swelling kinetics of SAR are studied.It is indicated the water-absorbing swelling process is mainly caused by the difference in water osmotic pressure and Na+concentration inside and outside the cross-linked molecular structure of the resin,which is not only consistent with the quasi-secondary kinetic model,but also with the Fick diffusion model.

Analysis on air-leakage law of goal in condition of ascending mining for top-coal caving

Using the Jisan Coalmine's top-coal caving for the 3down coal seam with ascending mining as the project background, the air-leakage characteristics of the goaf wasanalyzed. Through data fitting of the in situ observation, the models of gas seepage, diffusion and air-leakage in the goaf were established in ascending mining. The ComputationFluid Dynamics software Fluent was used to simulate the air-leakage law of the goaf. Theresults of the numerical simulation provide a basis for the use of the technology of ventilation and fire prevention in the working face of an ascending mining, which ensures thesafety in production in the working face of the top-coal caving for 3_down coal seam in theJisan Coalmine.

Study and application of a new type of foamed concrete wall in coal mines

A new type of airtight wall with the combination of foamed concrete and pier support was designed in this study. Based on the theories and models related to the foamed concrete and blasting shock load, using the numerical analysis method, this study obtains the new material＇s mechanical and destruction laws through analyzing its reaction to different conditions of load （mining and shock waves）, airtight wall thickness （1.2, 1.5, 1.8, 2.1 m） and steel pipe diameters （400, 450, 500 and 600 mm）. The results show that： ①foamed concrete can have very good suspension, and the pier column support is the main carrier of roof pressure; ② the damaged area of foamed concrete decreases as the foamed concrete thickness increases. Under impact loading, the thickness of the foamed concrete wall plays a more obvious role in retaining its integrity; ③under the same mining pressure, the damage area increases as the steel pipe diameter increases; ④ with additional mining stress increase, under whether static load or impact load, the stress on the foamed concrete and steel pipe will also increase gradually, therefore the actual airtight wall design will need to be based on specific circumstances in steel stress.

Stability of coal pillar in gob-side entry driving under unstable overlying strata and its coupling support control technique

Considering the situation that it is difficult to control the stability of narrow coal pillar in gob-side entry driving under unstable overlying strata, the finite difference numerical simulation method was adopted to analyze the inner stress distribution and its evolution regularity, as well as the deformation characteristics of narrow coal pillar in gob-side entry driving, in the whole process from entry driving of last working face to the present working face mining. A new method of narrow coal pillar control based on the triune coupling support technique (TCST), which includes that high-strength prestressed thread steel bolt is used to strain the coal on the goaf side, and that short bolt to control the integrity of global displacement zone in coal pillar on the entry side, and that long grouting cable to fix anchor point to constrain the bed separation between global displacement zone and fixed zone, is thereby generated and applied to the field production. The result indicates that after entry excavating along the gob under unstable overlying strata, the supporting structure left on the gob side of narrow coal pillar is basically invalid to maintain the coal-pillar stability, and the large deformation of the pillar on the gob side is evident. Except for the significant dynamic pressure appearing in the coal mining of last working face and overlying strata stabilizing process, the stress variation inside the coal pillar in other stages are rather steady, however, the stress expansion is obvious and the coal pillar continues to deform. Once the gob-side entry driving is completed, a global displacement zone on the entry side appears in the shallow part of the pillar, whereas, a relatively steady fixed zone staying almost still in gob-side entry driving and present working face mining is found in the deep part of the pillar. The application of TCST can not only avoid the failure of pillar supporting structure, but exert the supporting capacity of the bolting structure left in the pillar of last sublevel entry, thus to jointly maintain the stability of coal pillar.

Mechanics analysis on the conditions of rock burst occurrence in the coal mass of roadway rib

According to the rock burst features occurred in the coal mass of roadway rib in one mine,the mechanics model of coal mass and roof structure system along the edge of goaf was founded to analyze the stress of roof rock layer,so the subside curve of roof rock layer was deduced.Furthermore,the stability of coal and rock system were analyzed,the critical load and critical resistance zone were used to judge the danger degree of rock burst occurrence.The influence of coal mass strength,brittleness degree,coal seam thickness,roof thickness,suspending length,equivalent shear module on the critical load, critical resistance zone was confirmed.So the rock burst occurrence conditions of coal mass in roadway rib mainly depend on mining depth,coal seam thickness and hard roof and floor,which are decided by the above studies,and successfully applied in prediction and prevention of rock burst in this mine.

High Chrome Containing Refractories for Coal Slurry Gasifier

Water, oxygen and coal are converted into CO, H2, methane in the coal slurry gasifier. Under the condition of high temperature and high pressure, high chromecontaining refractories are used as hot face lining. The collapse of refractories from corrosion and spalling is mainly attributed to liquid deslagging. Refractories for coal slurry gasifier, destruction mechanism and solutions are analyzed.

Application of fiber Bragg grating sensor network in aluminum reduction tank shell temperature monitoring

A fiber Bragg grating temperature sensor network was designed to implement the real-time health monitoring of the aluminum reduction cell. The heat transfer process was simulated using software ANSYS, and an on-line shell monitoring system was established based on optical sensing technology. According to aluminum reduction cell heat transfer theory, the 2D slice finite element model was developed. The relationship between shell temperature and cell status was discussed. Fiber Bragg grating （FBG） was chosen as the temperature sensor in light of its unique advantages. The accuracy of designed FBG temperature sensors exceeds 2 ~C, and good repeatability was exhibited. An interrogation system with 104 sensors based on VPG （volume phase grating） filter was established. Through the long-term monitoring on running state, the status of the aluminum reduction cell, including security and fatigue life could be acquired and estimated exactly. The obtained results provide the foundation for the production status monitoring and fault diagnosis. Long-term test results show good stability and repeatability which are compatible with electrolysis process.

FBG-based ultrasonic wave detection and acoustic emission linear location system

The ultrasonic (US) wave detection and an acoustic emission (AE) linear location system are proposed, which employ fiber Bragg gratings (FBGs) as US wave sensors. In the theoretical analysis, the FBG sensor response to longitudinal US wave is investigated. The result indicates that the FBG wavelength can be modulated as static case when the grating length is much shorter than US wavelength. The experimental results of standard sinusoidal and spindle wave test agree well with the generated signal. Further research using two FBGs for realizing linear location is also achieved. The maximum linear location error is obtained as less than 5 mm. FBG-based US wave sensor and AE linear location provide useful tools for specific requirements.