The compound [H2(teta)]2+·2Cl-·3H2O (teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis and the structure was determined by sin...The compound [H2(teta)]2+·2Cl-·3H2O (teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis and the structure was determined by single-crystal X-ray diffraction.The crystal belongs to triclinic,space group Pī with a=7.8364(16),b=8.3607(13),c=9.4762(15)?,α=61.900(12),β=78.970(16),γ=80.008(16)°,V=535.06(16)?3,Z=1,ρcalc=1.277g/cm3,F(000)=226.The macrocylic tetraamine cation contains two protonated secondary amine N atoms and two secondary amine N atoms.The water molecules are distinguished by their inequality in structure formation.They are involved in different types of intermolecular hydrogen bonding in the crystal lattice.展开更多
The complex[Ni(teta)(NCS)2](teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis,IR and UV and the structure was determined by single-cry...The complex[Ni(teta)(NCS)2](teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis,IR and UV and the structure was determined by single-crystal X-ray diffraction analysis.The result showed the crystal belonged to triclinic,space group P(1) with a=8.0261(17),b=9.1174(19),c=15.485(3)(A)?,a=94.438(5),β=97.497(6),γ=92.948(5)o,V=1117.9(4)(A)?3,Z=2,Dcalc=1.365g/cm3,F(000)=492.In the crystal there were two independent Ni(Ⅱ)centres.Each Ni(Ⅱ)ion was coordinated by four nitrogen atoms from one teta ligand and two nitrogen atoms from NCS-anions to form a distorted octahedron geometry.展开更多
The complex Cu(teta)(NO3)2 (teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis, IR and UV and the structure was determined by single-cr...The complex Cu(teta)(NO3)2 (teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis, IR and UV and the structure was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group C2/c with α=12.992(9), b=11.639(7), c=15.838(10)*!, β=116.802(8)°, V=2138(2)*!3, Z=4, Gcalc=1.467g/cm3,F(000)=1004. The complex has the centrosymmertric copper(Ⅱ) ion in square planar co-ordination with four nitrogens of the macrocycle.展开更多
文摘The compound [H2(teta)]2+·2Cl-·3H2O (teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis and the structure was determined by single-crystal X-ray diffraction.The crystal belongs to triclinic,space group Pī with a=7.8364(16),b=8.3607(13),c=9.4762(15)?,α=61.900(12),β=78.970(16),γ=80.008(16)°,V=535.06(16)?3,Z=1,ρcalc=1.277g/cm3,F(000)=226.The macrocylic tetraamine cation contains two protonated secondary amine N atoms and two secondary amine N atoms.The water molecules are distinguished by their inequality in structure formation.They are involved in different types of intermolecular hydrogen bonding in the crystal lattice.
文摘The complex[Ni(teta)(NCS)2](teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis,IR and UV and the structure was determined by single-crystal X-ray diffraction analysis.The result showed the crystal belonged to triclinic,space group P(1) with a=8.0261(17),b=9.1174(19),c=15.485(3)(A)?,a=94.438(5),β=97.497(6),γ=92.948(5)o,V=1117.9(4)(A)?3,Z=2,Dcalc=1.365g/cm3,F(000)=492.In the crystal there were two independent Ni(Ⅱ)centres.Each Ni(Ⅱ)ion was coordinated by four nitrogen atoms from one teta ligand and two nitrogen atoms from NCS-anions to form a distorted octahedron geometry.
文摘The complex Cu(teta)(NO3)2 (teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)was synthesized and characterized by elementary analysis, IR and UV and the structure was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group C2/c with α=12.992(9), b=11.639(7), c=15.838(10)*!, β=116.802(8)°, V=2138(2)*!3, Z=4, Gcalc=1.467g/cm3,F(000)=1004. The complex has the centrosymmertric copper(Ⅱ) ion in square planar co-ordination with four nitrogens of the macrocycle.