A new strategy for the synthesis of unsymmetrical phosphotriesters was reported: an alcohol was converted to unsymmetrical dialkyl phosphites firstly, which then reacted with the second alcohol or phenol to afford req...A new strategy for the synthesis of unsymmetrical phosphotriesters was reported: an alcohol was converted to unsymmetrical dialkyl phosphites firstly, which then reacted with the second alcohol or phenol to afford required unsymmetrical triesters in the presence of iodine in high yields under exceptionally mild conditions.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 29772047).
文摘A new strategy for the synthesis of unsymmetrical phosphotriesters was reported: an alcohol was converted to unsymmetrical dialkyl phosphites firstly, which then reacted with the second alcohol or phenol to afford required unsymmetrical triesters in the presence of iodine in high yields under exceptionally mild conditions.
