Mechanical properties of poly (vinyl chloride) film doped with micro rare earth neodymium are improved notably. Its tensile strength increases from 36 1 to 52 9 MPa, while its flexibility is increased significantly by...Mechanical properties of poly (vinyl chloride) film doped with micro rare earth neodymium are improved notably. Its tensile strength increases from 36 1 to 52 9 MPa, while its flexibility is increased significantly by adding active silanol extracted from water glass. Both ultraviolet and microwave crosslinking result in samples with satisfactory mechanical properties, and the flexibility of the microwave crosslinked samples is much higher than that of the ultraviolet crosslinked ones.展开更多
Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare e...Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare earth - containing composite elastomer. It is found that mechanical performance can be improved remarkably. Analyzed by infrared spectrometry (IR), differential scanning calorimetry (DSC) and cross-linking densitometry, the relationship between structure and performance was discussed.展开更多
Poly(methyl methacrylate) (PMMA) was used to wrap alumina siloxane sol through emulsion polymerization. A kind of suspensions with notable ER effect was produced by fully mixing the prepared microcapsule with silicon...Poly(methyl methacrylate) (PMMA) was used to wrap alumina siloxane sol through emulsion polymerization. A kind of suspensions with notable ER effect was produced by fully mixing the prepared microcapsule with silicon oil. Meanwhile a series of PMMA wrapped alumina-siloxane gel doped with rare earths was obtained and its ER effect was tested, like viscosity of different rare earth ion doped samples in different powder concentrations and at different temperatures, at the same time, leak current density and dielectric constant were measured. Results show that the ER effect of this suspension is remarkable, and its stability is much better. The condition of emulsion polymerization and the mechanism of effect are discussed.展开更多
Nano-SiOdoped with rare earth carboxylate grafting continuous component of functional poly-silicone liquid, a kind of subsidence high-resistance. Electrorheological fluid (ERF) was synthesized. And its viscoelastic pr...Nano-SiOdoped with rare earth carboxylate grafting continuous component of functional poly-silicone liquid, a kind of subsidence high-resistance. Electrorheological fluid (ERF) was synthesized. And its viscoelastic properties were investigated experimentally. The special polarization effect of rare earth in the ERF was also discussed. The forced oscillating behavior was obtained using a rheometer. The variation of the shear modulus of ERF subjected to various stress amplitude and frequency were investigated. The complex shear modulus and storage modulus of ERF were also given at different electric field intensities. Meanwhile, the creep and recovery characteristics of ERF were also measured. The equilibrium compliance Jc and the steady state recoverable compliance JR were investigated as a function of electric field strength and ratio of reactant, and the effect of ERF′s structure was analyzed. With increasing in electric field strength at fixed ratio of reactant, the plastic response diminishes, and the elastic behavior rose.展开更多
The rare earth-containing composite elastomer was obtained by the reaction of vinyl pyridine-SBR (PSBR) latex with rare earth alkoxides, and its thermal oxidation resistance was studied. After aging test, it is found ...The rare earth-containing composite elastomer was obtained by the reaction of vinyl pyridine-SBR (PSBR) latex with rare earth alkoxides, and its thermal oxidation resistance was studied. After aging test, it is found that its retention rate of mechanical properties is far higher than that of the control sample. The results of thermogravimetric analysis show that its thermal-decomposing temperature rises largely. The analysis of oxidation mechanisms indicates that the main reasons for thermal oxidation resistance are that rare earth elements are of the utility to discontinue autoxidation chain reaction and that the formed complex structure has steric hindrance effect on oxidation.展开更多
文摘Mechanical properties of poly (vinyl chloride) film doped with micro rare earth neodymium are improved notably. Its tensile strength increases from 36 1 to 52 9 MPa, while its flexibility is increased significantly by adding active silanol extracted from water glass. Both ultraviolet and microwave crosslinking result in samples with satisfactory mechanical properties, and the flexibility of the microwave crosslinked samples is much higher than that of the ultraviolet crosslinked ones.
文摘Rare earth -containing PSBR sheet was prepared by reaction of rare earth alkoxide with quaternary ammonium salt of pyridine modified SBR (PSBR) latex, and then it was blended with natural rubber (NR) to produce rare earth - containing composite elastomer. It is found that mechanical performance can be improved remarkably. Analyzed by infrared spectrometry (IR), differential scanning calorimetry (DSC) and cross-linking densitometry, the relationship between structure and performance was discussed.
文摘Poly(methyl methacrylate) (PMMA) was used to wrap alumina siloxane sol through emulsion polymerization. A kind of suspensions with notable ER effect was produced by fully mixing the prepared microcapsule with silicon oil. Meanwhile a series of PMMA wrapped alumina-siloxane gel doped with rare earths was obtained and its ER effect was tested, like viscosity of different rare earth ion doped samples in different powder concentrations and at different temperatures, at the same time, leak current density and dielectric constant were measured. Results show that the ER effect of this suspension is remarkable, and its stability is much better. The condition of emulsion polymerization and the mechanism of effect are discussed.
基金NSF (50373034) Physics Chemistry National Key Subject Cultivation Point Grant of Jiangsu Province
文摘Nano-SiOdoped with rare earth carboxylate grafting continuous component of functional poly-silicone liquid, a kind of subsidence high-resistance. Electrorheological fluid (ERF) was synthesized. And its viscoelastic properties were investigated experimentally. The special polarization effect of rare earth in the ERF was also discussed. The forced oscillating behavior was obtained using a rheometer. The variation of the shear modulus of ERF subjected to various stress amplitude and frequency were investigated. The complex shear modulus and storage modulus of ERF were also given at different electric field intensities. Meanwhile, the creep and recovery characteristics of ERF were also measured. The equilibrium compliance Jc and the steady state recoverable compliance JR were investigated as a function of electric field strength and ratio of reactant, and the effect of ERF′s structure was analyzed. With increasing in electric field strength at fixed ratio of reactant, the plastic response diminishes, and the elastic behavior rose.
文摘The rare earth-containing composite elastomer was obtained by the reaction of vinyl pyridine-SBR (PSBR) latex with rare earth alkoxides, and its thermal oxidation resistance was studied. After aging test, it is found that its retention rate of mechanical properties is far higher than that of the control sample. The results of thermogravimetric analysis show that its thermal-decomposing temperature rises largely. The analysis of oxidation mechanisms indicates that the main reasons for thermal oxidation resistance are that rare earth elements are of the utility to discontinue autoxidation chain reaction and that the formed complex structure has steric hindrance effect on oxidation.
