Perylene nanocrystals with different sizes(10-250 nm) were prepared by reprecipitation. Compared with the absorption spectrum of perylene acetone solution, a new J aggregate absorption peak appeared in the absorption ...Perylene nanocrystals with different sizes(10-250 nm) were prepared by reprecipitation. Compared with the absorption spectrum of perylene acetone solution, a new J aggregate absorption peak appeared in the absorption spectra of nanocrystals. With the decrease of perylene nanocrystals size, it shows a blue shift in the absorption spectra. This blue shift is due to the size dependent property. The perylene concentration of initial acetone solution or the amount of solution injected into water, the aging time of organic nanocrystal dispersion and the adding of surfactant were the influencing factors of nanocrystal growth. We can gain the required microcrystals of different sizes by controlling the conditions of growth.展开更多
Femtosecond time-resolved fluorescence non-collinear optical parametric amplification spectroscopy （FNOPAS） is a versatile technique with advantages of high sensitivity, broad detection bandwidth, and intrinsic spec...Femtosecond time-resolved fluorescence non-collinear optical parametric amplification spectroscopy （FNOPAS） is a versatile technique with advantages of high sensitivity, broad detection bandwidth, and intrinsic spectrum correction func- tion. These advantages should benefit the study of coherent emission, such as measurement oflasing dynamics. In this letter, the FNOPAS was used to trace the lasing process in Rhodamine 6G （R6G） solution and organic semiconductor nano-wires. High-quality transient emission spectra and lasing dynamic traces were acquired, which demonstrates the applicability of FNOPAS in the study of lasing dynamics. Our work extends the application scope of the FNOPAS technique.展开更多
文摘Perylene nanocrystals with different sizes(10-250 nm) were prepared by reprecipitation. Compared with the absorption spectrum of perylene acetone solution, a new J aggregate absorption peak appeared in the absorption spectra of nanocrystals. With the decrease of perylene nanocrystals size, it shows a blue shift in the absorption spectra. This blue shift is due to the size dependent property. The perylene concentration of initial acetone solution or the amount of solution injected into water, the aging time of organic nanocrystal dispersion and the adding of surfactant were the influencing factors of nanocrystal growth. We can gain the required microcrystals of different sizes by controlling the conditions of growth.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.20925313 and 21503066)the Innovation Program of Chinese Academy of Sciences(Grant No.KJCX2-YW-W25)+1 种基金the Postdoctoral Project of Hebei University,Chinathe Project of Science and Technology Bureau of Baoding City,China(Grant No.15ZG029)
文摘Femtosecond time-resolved fluorescence non-collinear optical parametric amplification spectroscopy （FNOPAS） is a versatile technique with advantages of high sensitivity, broad detection bandwidth, and intrinsic spectrum correction func- tion. These advantages should benefit the study of coherent emission, such as measurement oflasing dynamics. In this letter, the FNOPAS was used to trace the lasing process in Rhodamine 6G （R6G） solution and organic semiconductor nano-wires. High-quality transient emission spectra and lasing dynamic traces were acquired, which demonstrates the applicability of FNOPAS in the study of lasing dynamics. Our work extends the application scope of the FNOPAS technique.
