The pyrolysis of phytoremediated giant reed(Arundo donax)biomass could cause secondary pollution of heavy metals.The stabilization of heavy metals in the pyrolysis process with external materials such as Al2O3,CaCO3,F...The pyrolysis of phytoremediated giant reed(Arundo donax)biomass could cause secondary pollution of heavy metals.The stabilization of heavy metals in the pyrolysis process with external materials such as Al2O3,CaCO3,FeCl3and NaOH,wasstudied.The results showed that37%As and97%Cd in biochar were stabilized when giant reed powder was pyrolyzed at250°Cwith5%Al2O3for2h.Furthermore,59%Pb in biochar was stabilized at400°C with5%CaCO3for1h.Under biochar produced inoptimized pyrolysis conditions,Cd mainly existed in a residual fraction,while Pb and As mainly existed in oxidizable fraction inBCR analysis.In XRD analysis,As was only found in Ca2As2O7;Cd in biochar mainly existed in Cd(AlCl4)2,CdPbO3or CdSO3;and Pb mainly existed as Pb3O2SO4.展开更多
基金Projects(21577176,41271330) supported by the National Natural Science Foundation of China
文摘The pyrolysis of phytoremediated giant reed(Arundo donax)biomass could cause secondary pollution of heavy metals.The stabilization of heavy metals in the pyrolysis process with external materials such as Al2O3,CaCO3,FeCl3and NaOH,wasstudied.The results showed that37%As and97%Cd in biochar were stabilized when giant reed powder was pyrolyzed at250°Cwith5%Al2O3for2h.Furthermore,59%Pb in biochar was stabilized at400°C with5%CaCO3for1h.Under biochar produced inoptimized pyrolysis conditions,Cd mainly existed in a residual fraction,while Pb and As mainly existed in oxidizable fraction inBCR analysis.In XRD analysis,As was only found in Ca2As2O7;Cd in biochar mainly existed in Cd(AlCl4)2,CdPbO3or CdSO3;and Pb mainly existed as Pb3O2SO4.