Hydrogen-based compounds have attracted significant attention in recent years due to the discovery of conventional superconductivity with high critical temperature under high pressure,rekindling hopes for finding room...Hydrogen-based compounds have attracted significant attention in recent years due to the discovery of conventional superconductivity with high critical temperature under high pressure,rekindling hopes for finding roomtemperature superconductors.In this study,we investigated the vibrational and superconducting properties of H_(3)Sein the Im￣3m phase under pressures of 50-200GPa.Our approach combines the stochastic self-consistent harmonic approximation and first-principles calculations to account for the quantum and anharmonic effects of ions.According to the results,these effects significantly modify the crystal structure,increasing the inner pressure by approximately 8GPa compared to situations in which they are ignored.The phonon spectra suggest that when these effects are considered,the crystal stabilizes at pressures as low as approximately 61GPa,which is significantly lower than the previously predicted value of over 100GPa.Our calculations also highlight the critical role of quantum and anharmonic effects on the electron-phonon coupling properties.Neglecting these factors can result in a significant overestimation of the superconducting critical temperature(T_(c))by approximately 4K(200GPa)to 25K(125GPa).With anharmonic phonons,the T_(c) calculated from the Migdal-Eliashberg equations reaches 200K(μ⋆=0.1,λ=4.1)as the pressure decreases to 64GPa,indicating that the crystal is a rare high-Tc superconductor at moderate pressures.展开更多
Luminescent properties of Tm^(3+)-doped GdYTaO_(4) are studied for exploring their potential applications in temperature and pressure sensing.Two main emission peaks from ^(3)H_(4)→^(3)H_(6) transition of Tm^(3+)are ...Luminescent properties of Tm^(3+)-doped GdYTaO_(4) are studied for exploring their potential applications in temperature and pressure sensing.Two main emission peaks from ^(3)H_(4)→^(3)H_(6) transition of Tm^(3+)are investigated.Intensity ratio between the two peaks evolves exponentially with temperature and has a highest sensitivity of 0.014 K^(−1) at 32 K.The energy difference between the two peaks increases linearly with pressure increasing at a rate of 0.38 meV/GPa.Intensity ratio between the two peaks and their emission lifetimes are also analyzed for discussing the pressure-induced variation of the sample structure.Moreover,Raman spectra recorded under high pressures indicate an isostructural phase transition of GdYTaO_(4) occurring at 4.46 GPa.展开更多
基金Natural Science Foundation Project(Grant No.20230101280JC)of Jilin Provincial Department of Science and Technology.
文摘Hydrogen-based compounds have attracted significant attention in recent years due to the discovery of conventional superconductivity with high critical temperature under high pressure,rekindling hopes for finding roomtemperature superconductors.In this study,we investigated the vibrational and superconducting properties of H_(3)Sein the Im￣3m phase under pressures of 50-200GPa.Our approach combines the stochastic self-consistent harmonic approximation and first-principles calculations to account for the quantum and anharmonic effects of ions.According to the results,these effects significantly modify the crystal structure,increasing the inner pressure by approximately 8GPa compared to situations in which they are ignored.The phonon spectra suggest that when these effects are considered,the crystal stabilizes at pressures as low as approximately 61GPa,which is significantly lower than the previously predicted value of over 100GPa.Our calculations also highlight the critical role of quantum and anharmonic effects on the electron-phonon coupling properties.Neglecting these factors can result in a significant overestimation of the superconducting critical temperature(T_(c))by approximately 4K(200GPa)to 25K(125GPa).With anharmonic phonons,the T_(c) calculated from the Migdal-Eliashberg equations reaches 200K(μ⋆=0.1,λ=4.1)as the pressure decreases to 64GPa,indicating that the crystal is a rare high-Tc superconductor at moderate pressures.
基金the National Natural Science Foundation of China(Grant No.11804047)the Science and Technology Development Program of Jilin City,China(Grant No.201831733).
文摘Luminescent properties of Tm^(3+)-doped GdYTaO_(4) are studied for exploring their potential applications in temperature and pressure sensing.Two main emission peaks from ^(3)H_(4)→^(3)H_(6) transition of Tm^(3+)are investigated.Intensity ratio between the two peaks evolves exponentially with temperature and has a highest sensitivity of 0.014 K^(−1) at 32 K.The energy difference between the two peaks increases linearly with pressure increasing at a rate of 0.38 meV/GPa.Intensity ratio between the two peaks and their emission lifetimes are also analyzed for discussing the pressure-induced variation of the sample structure.Moreover,Raman spectra recorded under high pressures indicate an isostructural phase transition of GdYTaO_(4) occurring at 4.46 GPa.
