Efficient blue small molecular phosphorescent fight-emitting diodes with a blue phosphorescent dye bis(3,5- difluoro-2-(2-pyridyl)-phenyl-(2-carboxypride) iridium (Ⅲ) (Flrpic) doped into a novel small-molecu...Efficient blue small molecular phosphorescent fight-emitting diodes with a blue phosphorescent dye bis(3,5- difluoro-2-(2-pyridyl)-phenyl-(2-carboxypride) iridium (Ⅲ) (Flrpic) doped into a novel small-molecule host 9,9- bis[4-(3,6-di-tert-butylcarbazol-9-yl)phenyl] fluorene (TBCPF) as the light-emitting layer have been fabricated by spin-coating. The host TBCPF can form homogeneous amorphous films by spin-coating and has triplet energy higher than that of the blue phosphorescent dye Flrpic. All the devices with different Flrpic concentration in the emitting layer give emission from Flrpic indicating complete energy transfer from TBCPF to Flrpic. The device shows the best performance with a peak brightness of 8050 cd/m^2 at 10.2 V and the maximum current efficiency up to 3.52 cd/A, when the Flrpic doped concentration is as high as 16%.展开更多
文摘Efficient blue small molecular phosphorescent fight-emitting diodes with a blue phosphorescent dye bis(3,5- difluoro-2-(2-pyridyl)-phenyl-(2-carboxypride) iridium (Ⅲ) (Flrpic) doped into a novel small-molecule host 9,9- bis[4-(3,6-di-tert-butylcarbazol-9-yl)phenyl] fluorene (TBCPF) as the light-emitting layer have been fabricated by spin-coating. The host TBCPF can form homogeneous amorphous films by spin-coating and has triplet energy higher than that of the blue phosphorescent dye Flrpic. All the devices with different Flrpic concentration in the emitting layer give emission from Flrpic indicating complete energy transfer from TBCPF to Flrpic. The device shows the best performance with a peak brightness of 8050 cd/m^2 at 10.2 V and the maximum current efficiency up to 3.52 cd/A, when the Flrpic doped concentration is as high as 16%.