黄乃正先生生于1950年11月,籍贯广东台山.1973年以一等荣誉学位毕业于香港中文大学,而后进入英国伦敦大学学院(University College London)师从著名的F.Sondheimer教授进行研究生学习,1976年获博士学位.随后于哈佛大学跟随诺贝尔化学奖...黄乃正先生生于1950年11月,籍贯广东台山.1973年以一等荣誉学位毕业于香港中文大学,而后进入英国伦敦大学学院(University College London)师从著名的F.Sondheimer教授进行研究生学习,1976年获博士学位.随后于哈佛大学跟随诺贝尔化学奖获得者R.B.Woodward教授进行博士后研究,两年后回到英国,开始其独立研究.展开更多
The regioselective ring-opening of epoxides with aniline and p-chlorop niline catalyzed by copper(Ⅱ) triflate provides the corresponding β-amino alcohols in excellent yields.
bState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China cShanghai Hong Kong Joint Laboratory in Chemical Synthesis, Shan...bState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China cShanghai Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China New chiral N,S ligands with oxazoline and thiophenyl substituents at benzene ring and benzylic position have been prepared and applied in palladium catalyzed asymmetric allylic alkylation reaction to provide the product with high yield and entantioselectivity ( 82%-93% ee ).展开更多
文摘黄乃正先生生于1950年11月,籍贯广东台山.1973年以一等荣誉学位毕业于香港中文大学,而后进入英国伦敦大学学院(University College London)师从著名的F.Sondheimer教授进行研究生学习,1976年获博士学位.随后于哈佛大学跟随诺贝尔化学奖获得者R.B.Woodward教授进行博士后研究,两年后回到英国,开始其独立研究.
基金Project (No. 29790127) supported by the National Natural Science Foundation of China
文摘The regioselective ring-opening of epoxides with aniline and p-chlorop niline catalyzed by copper(Ⅱ) triflate provides the corresponding β-amino alcohols in excellent yields.
文摘bState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China cShanghai Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China New chiral N,S ligands with oxazoline and thiophenyl substituents at benzene ring and benzylic position have been prepared and applied in palladium catalyzed asymmetric allylic alkylation reaction to provide the product with high yield and entantioselectivity ( 82%-93% ee ).
