四川盆地震旦系灯影组是重要的油气勘探开发层系,复杂的成岩演化和多期流体活动导致多种类型的白云岩形成。揭示震旦系白云岩的形成时代和成因不仅可以为四川盆地震旦系下一步的油气勘探提供更加充实的科学依据,也可为理解全球大规模存...四川盆地震旦系灯影组是重要的油气勘探开发层系,复杂的成岩演化和多期流体活动导致多种类型的白云岩形成。揭示震旦系白云岩的形成时代和成因不仅可以为四川盆地震旦系下一步的油气勘探提供更加充实的科学依据,也可为理解全球大规模存在前寒武纪白云岩的原因提供有益启示。本文针对川中地区震旦系灯影组“葡萄花边”白云岩的形成时代和成因进行了综合研究。岩相学研究表明,“葡萄花边”白云岩充填于藻白云岩的孔隙内,向内对称生长,结晶程度明显好于藻白云岩。在岩相学的基础上,利用激光剥蚀-电感耦合等离子体质谱(LA-ICP-MS)微区原位U-Pb定年确定其形成时代,研究结果表明:川中地区震旦系灯影组“葡萄花边”白云岩形成时代为530±12Ma~502±12Ma,略新于灯影组地层年代。结合微量元素分析以及碳-氧-锶同位素数据,对川中地区震旦系灯影组“葡萄花边”白云岩进行成因分析。结果表明,其稀土元素总量(∑REE)相对较低(0.680×10^(-6)~8.963×10^(-6)),δ13 C VPDB(-0.1‰~1.7‰)略低于与同时期海水沉积白云岩的碳同位素值,δ18 O VPDB(-2.3‰~1.4‰)略高于与同时期海水达到氧同位素平衡的白云岩氧同位素值,87 Sr/86 Sr值(0.70876~0.70909)基本落入同时期海水范围。稀土元素配分总体为水平的模式,所有样品表现出Ce负异常。表明其形成环境既非海水沉积环境,也不完全是表生大气水岩溶条件。综合上述特征,推断川中地区震旦系灯影组“葡萄花边”白云岩是在震旦纪末-寒武纪早期海平面高频低幅度波动这一背景下,灯影组地层多次暴露与淹没,形成岩溶裂缝和孔洞的同时在溶蚀空间内结晶形成。残留孔洞为其后流体活动、油气充注提供了储集空间。本研究为认识川中地区震旦系灯影组“葡萄花边”白云岩成因、震旦纪末-寒武纪早期水化学条件、及超深层油气勘探开发提供了有益参考。展开更多
Coral bleaching has generally been recognized as the main reason for tropical coral reef degradation, but there are few long-term records of coral bleaching events. In this study, trace metals including chromium(Cr), ...Coral bleaching has generally been recognized as the main reason for tropical coral reef degradation, but there are few long-term records of coral bleaching events. In this study, trace metals including chromium(Cr), copper(Cu), molybdenum(Mo), manganese(Mn), lead(Pb), tin(Sn), titanium(Ti), vanadium(V), and yttrium(Y), were analyzed in two Porites corals collected from Meiji Reef in the tropical South China Sea(SCS) to assess differences in trace metal concentrations in bleached compared with unbleached coral growth bands. Ti, V, Cr, and Mo generally showed irregular fluctuations in both corals. Bleached layers contained high concentrations of Mn, Cu, Sn, and Pb. Unbleached layers showed moderately high concentrations of Mn and Cu only. The different distribution of trace metals in Porites may be attributable to different selectivity on the basis of vital utility or toxicity. Ti, V, Cr, and Mo are discriminated against by both coral polyps and zooxanthellae, but Mn, Cu, Sn, and Pb are accumulated by zooxanthellae and only Mn and Cu are accumulated by polyps as essential elements. The marked increase in Cu, Mn, Pb, and Sn are associated with bleaching processes, including mucus secretion, tissue retraction, and zooxanthellae expulsion and occlusion. Variation in these trace elements within the coral skeleton can be used as potential tracers of short-lived bleaching events.展开更多
文摘四川盆地震旦系灯影组是重要的油气勘探开发层系,复杂的成岩演化和多期流体活动导致多种类型的白云岩形成。揭示震旦系白云岩的形成时代和成因不仅可以为四川盆地震旦系下一步的油气勘探提供更加充实的科学依据,也可为理解全球大规模存在前寒武纪白云岩的原因提供有益启示。本文针对川中地区震旦系灯影组“葡萄花边”白云岩的形成时代和成因进行了综合研究。岩相学研究表明,“葡萄花边”白云岩充填于藻白云岩的孔隙内,向内对称生长,结晶程度明显好于藻白云岩。在岩相学的基础上,利用激光剥蚀-电感耦合等离子体质谱(LA-ICP-MS)微区原位U-Pb定年确定其形成时代,研究结果表明:川中地区震旦系灯影组“葡萄花边”白云岩形成时代为530±12Ma~502±12Ma,略新于灯影组地层年代。结合微量元素分析以及碳-氧-锶同位素数据,对川中地区震旦系灯影组“葡萄花边”白云岩进行成因分析。结果表明,其稀土元素总量(∑REE)相对较低(0.680×10^(-6)~8.963×10^(-6)),δ13 C VPDB(-0.1‰~1.7‰)略低于与同时期海水沉积白云岩的碳同位素值,δ18 O VPDB(-2.3‰~1.4‰)略高于与同时期海水达到氧同位素平衡的白云岩氧同位素值,87 Sr/86 Sr值(0.70876~0.70909)基本落入同时期海水范围。稀土元素配分总体为水平的模式,所有样品表现出Ce负异常。表明其形成环境既非海水沉积环境,也不完全是表生大气水岩溶条件。综合上述特征,推断川中地区震旦系灯影组“葡萄花边”白云岩是在震旦纪末-寒武纪早期海平面高频低幅度波动这一背景下,灯影组地层多次暴露与淹没,形成岩溶裂缝和孔洞的同时在溶蚀空间内结晶形成。残留孔洞为其后流体活动、油气充注提供了储集空间。本研究为认识川中地区震旦系灯影组“葡萄花边”白云岩成因、震旦纪末-寒武纪早期水化学条件、及超深层油气勘探开发提供了有益参考。
基金Supported by the National Basic Research Program of China(973 Program)(No.2013CB956103)the National Science Foundation of China(Nos.41306109,41476038)
文摘Coral bleaching has generally been recognized as the main reason for tropical coral reef degradation, but there are few long-term records of coral bleaching events. In this study, trace metals including chromium(Cr), copper(Cu), molybdenum(Mo), manganese(Mn), lead(Pb), tin(Sn), titanium(Ti), vanadium(V), and yttrium(Y), were analyzed in two Porites corals collected from Meiji Reef in the tropical South China Sea(SCS) to assess differences in trace metal concentrations in bleached compared with unbleached coral growth bands. Ti, V, Cr, and Mo generally showed irregular fluctuations in both corals. Bleached layers contained high concentrations of Mn, Cu, Sn, and Pb. Unbleached layers showed moderately high concentrations of Mn and Cu only. The different distribution of trace metals in Porites may be attributable to different selectivity on the basis of vital utility or toxicity. Ti, V, Cr, and Mo are discriminated against by both coral polyps and zooxanthellae, but Mn, Cu, Sn, and Pb are accumulated by zooxanthellae and only Mn and Cu are accumulated by polyps as essential elements. The marked increase in Cu, Mn, Pb, and Sn are associated with bleaching processes, including mucus secretion, tissue retraction, and zooxanthellae expulsion and occlusion. Variation in these trace elements within the coral skeleton can be used as potential tracers of short-lived bleaching events.
