This paper studies the intramolecular photoinduced electron-transfer （PET） of covalent bonded azobenzene-perylene diimide （AZO-PDI） in solvents by using steady-state and time-resolved fluorescence spectroscopy tog...This paper studies the intramolecular photoinduced electron-transfer （PET） of covalent bonded azobenzene-perylene diimide （AZO-PDI） in solvents by using steady-state and time-resolved fluorescence spectroscopy together with ultrafast transient absorption spectroscopic techniques. Fast fluorescence quenching is observed when AZO-PDI is excited at characteristic wavelengths of AZO and perylene moieties. Reductive electron-transfer with transfer rate faster than 10^11 s^-1 is found. This PET process is also consolidated by femtosecond transient absorption spectra.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 10504001,60878019,10821062,10934001,60677002 and 10828407)the National Basic Research Program of China (Grant Nos. 2009CB930504,2007CB307001,2006CB921601 and 2006CB806007)
文摘This paper studies the intramolecular photoinduced electron-transfer （PET） of covalent bonded azobenzene-perylene diimide （AZO-PDI） in solvents by using steady-state and time-resolved fluorescence spectroscopy together with ultrafast transient absorption spectroscopic techniques. Fast fluorescence quenching is observed when AZO-PDI is excited at characteristic wavelengths of AZO and perylene moieties. Reductive electron-transfer with transfer rate faster than 10^11 s^-1 is found. This PET process is also consolidated by femtosecond transient absorption spectra.
