An efficient C–P bond formation reaction was developed by virtue of the synergetic catalysis strategy by merging heterogeneous photocatalysis and nickel catalysis.This platform utilizing cadmium sulfide semiconductor...An efficient C–P bond formation reaction was developed by virtue of the synergetic catalysis strategy by merging heterogeneous photocatalysis and nickel catalysis.This platform utilizing cadmium sulfide semiconductors as heterogeneous photocatalysts and nickel complexes as transition metal catalysts provided a variety of organophosphorus compounds from readily available aryl and vinyl halides,as well as aryl triflates,with generally a good-to-excellent reaction efficiency(31 examples,46%-98%yields).The current protocol features mild reaction conditions,a broad substrate scope,recyclability of photocatalysts,and inexpensive catalysts,thus defining the practical and economic proprieties of the present catalyst system.展开更多
基金the National Science Foundation of China(21822103,21820102003,21772052,21772053,21572074,21472057)the Program of Introducing Talents of Discipline to Universities of China(111 Program,B17019)+1 种基金the Natural Science Foundation of Hubei Province(2017AHB047)the International Joint Research Center for Intelligent Biosensing Technology and Health for support of this research~~
文摘An efficient C–P bond formation reaction was developed by virtue of the synergetic catalysis strategy by merging heterogeneous photocatalysis and nickel catalysis.This platform utilizing cadmium sulfide semiconductors as heterogeneous photocatalysts and nickel complexes as transition metal catalysts provided a variety of organophosphorus compounds from readily available aryl and vinyl halides,as well as aryl triflates,with generally a good-to-excellent reaction efficiency(31 examples,46%-98%yields).The current protocol features mild reaction conditions,a broad substrate scope,recyclability of photocatalysts,and inexpensive catalysts,thus defining the practical and economic proprieties of the present catalyst system.
