为满足刀具、模具和耐磨件等工具领域的需要,研制了新型TiB2基硬质合金.在TiB2 Fe Mo硬质合金中,利用常规硬质合金生产工艺,研究不同含量的VC对合金晶粒度和性能的影响.与未添加VC的试样相比,添加0.5%VC后,合金中超细TiB2晶粒由38.94%...为满足刀具、模具和耐磨件等工具领域的需要,研制了新型TiB2基硬质合金.在TiB2 Fe Mo硬质合金中,利用常规硬质合金生产工艺,研究不同含量的VC对合金晶粒度和性能的影响.与未添加VC的试样相比,添加0.5%VC后,合金中超细TiB2晶粒由38.94%增加到59.39%;耐磨性提高了53.8%,抗氧化性提高了60%,800℃下抗弯强度比室温抗弯强度仅下降7.3%.表明适量添加VC可以使TiB2 Fe Mo硬质合金的耐磨性、高温强度和高温抗氧化性得到改善;可有效抑制晶粒长大,使硬质相颗粒均匀细化.展开更多
We report electroluminescence in hybrid ZnO and conjugated polymer poly[2-methoxy-5-（3′, 7′-dimethyloctyloxy）- 1,4-phenylenevinylene] （MDMO-PPV） bulk heterojunction photovoltaic cells. Photoluminescence quenchin...We report electroluminescence in hybrid ZnO and conjugated polymer poly[2-methoxy-5-（3′, 7′-dimethyloctyloxy）- 1,4-phenylenevinylene] （MDMO-PPV） bulk heterojunction photovoltaic cells. Photoluminescence quenching experimental results indicate that the ultrafast photoinduced electron transfer occurs from MDMO-PPV to ZnO under illumination. The ultrafast photoinduced electron transfer effect is induced because ZnO has an electron affinity a bout 1.2 e V greater than that of MDMO-PP V. Electron ＇back transfer＇ can occur if the interfacial barrier between ZnO and MDMO-PPV can be overcome by applying a substantial electric field. Therefore, electrolumi- nescence action due to the fact that the back transfer effect can be observed in the ZnO：MDMO-PPV devices since a forward bias is applied. The photovoltaic and electroluminescence actions in the same ZnO：MDMO-PPV device can be induced by different injection ways： photoinjection and electrical injection. The devices are expected to provide an opportunity for dual functionality devices with photovoltaic effect and electroluminescence character.展开更多
Compared to conjugated polymer poly[2-methoxy-5-（3＇ ,7＇-dimethyloctyloxy）-l,4-phenylenevinylene] （MDMO-PPV） solar cells, bulk heterojunction solar cells composed of zinc oxide （ZnO） nanocrystals and MDMO-PPV h...Compared to conjugated polymer poly[2-methoxy-5-（3＇ ,7＇-dimethyloctyloxy）-l,4-phenylenevinylene] （MDMO-PPV） solar cells, bulk heterojunction solar cells composed of zinc oxide （ZnO） nanocrystals and MDMO-PPV have a better energy conversion efficiency. However, ultraviolet （UV） light deteriorates the performance of solar cells composed of ZnO and MDMO-PPV. We propose a model to explain the effect of UV illumination on these ZnO：MDMO-PPV solar cells. According to this model, the degradation from UV illumination is due to a decrease of exciton dissociation efficiency. Our model is based on the experimentM results such as the measurements of current density versus voltage, photoluminescence, and photocurrent.展开更多
文摘为满足刀具、模具和耐磨件等工具领域的需要,研制了新型TiB2基硬质合金.在TiB2 Fe Mo硬质合金中,利用常规硬质合金生产工艺,研究不同含量的VC对合金晶粒度和性能的影响.与未添加VC的试样相比,添加0.5%VC后,合金中超细TiB2晶粒由38.94%增加到59.39%;耐磨性提高了53.8%,抗氧化性提高了60%,800℃下抗弯强度比室温抗弯强度仅下降7.3%.表明适量添加VC可以使TiB2 Fe Mo硬质合金的耐磨性、高温强度和高温抗氧化性得到改善;可有效抑制晶粒长大,使硬质相颗粒均匀细化.
基金Supported by the National Natural Science Foundation of China under Grant Nos 60476002, 60390071, 60576036 and 60276014, the National Basic Research Programme of China under Grant Nos 2006CB202604 and 2006CB604900, and the Hi-Tech Research and Development Programme of China under Grant No 2006AA03Z0408.
文摘We report electroluminescence in hybrid ZnO and conjugated polymer poly[2-methoxy-5-（3′, 7′-dimethyloctyloxy）- 1,4-phenylenevinylene] （MDMO-PPV） bulk heterojunction photovoltaic cells. Photoluminescence quenching experimental results indicate that the ultrafast photoinduced electron transfer occurs from MDMO-PPV to ZnO under illumination. The ultrafast photoinduced electron transfer effect is induced because ZnO has an electron affinity a bout 1.2 e V greater than that of MDMO-PP V. Electron ＇back transfer＇ can occur if the interfacial barrier between ZnO and MDMO-PPV can be overcome by applying a substantial electric field. Therefore, electrolumi- nescence action due to the fact that the back transfer effect can be observed in the ZnO：MDMO-PPV devices since a forward bias is applied. The photovoltaic and electroluminescence actions in the same ZnO：MDMO-PPV device can be induced by different injection ways： photoinjection and electrical injection. The devices are expected to provide an opportunity for dual functionality devices with photovoltaic effect and electroluminescence character.
基金Supported by the National Basic Research Programme of China under Grant Nos 2006GB604900 and 2006GB202604, the National Hi-Tech Research and Development Programme of China under Grant No 2006AA03Z0408, and the National .Natural Science Foundation of China under Granae Nos 60476002, 60390071, 60576036 and 60276014.
文摘Compared to conjugated polymer poly[2-methoxy-5-（3＇ ,7＇-dimethyloctyloxy）-l,4-phenylenevinylene] （MDMO-PPV） solar cells, bulk heterojunction solar cells composed of zinc oxide （ZnO） nanocrystals and MDMO-PPV have a better energy conversion efficiency. However, ultraviolet （UV） light deteriorates the performance of solar cells composed of ZnO and MDMO-PPV. We propose a model to explain the effect of UV illumination on these ZnO：MDMO-PPV solar cells. According to this model, the degradation from UV illumination is due to a decrease of exciton dissociation efficiency. Our model is based on the experimentM results such as the measurements of current density versus voltage, photoluminescence, and photocurrent.
