Rare earth phosphate fertilizer (REPF) as base fertilizer (750 kg per hm2) was applied in the western area of China during the "Tenth Five-Year Plan", and the results show as follows: compared with calcium s...Rare earth phosphate fertilizer (REPF) as base fertilizer (750 kg per hm2) was applied in the western area of China during the "Tenth Five-Year Plan", and the results show as follows: compared with calcium superphosphate (CK), REPF increases crops yields for maize by 17.0%, for rice by 10.5%, for wheat by 24.2%, for potato by 18.5%, for cabbage by 16.3%, for Chinese cabbage by 16.4%, for beet by 6.5%; decreases the diseased plant rate for common smut of maize by 1.0%, for maize stalk rot by 1.2%, for wheat take-all disease by 7.8%, for wheat root rot by 3.2%, for potato blackleg disease by 1.4%, for potato late blight by 6.6%; increases the sugar content of beet by 0.9°S.展开更多
The development and prospect of rare earth functional biomaterials (REFB) was discussed. From 1979 to 1985, the simple REFB (salts) has been developed, and the fundamental research including forms, effects, toxicity, ...The development and prospect of rare earth functional biomaterials (REFB) was discussed. From 1979 to 1985, the simple REFB (salts) has been developed, and the fundamental research including forms, effects, toxicity, conversion in soil, and analysis methods had been finished. Then, the RE feed additive materials had been developed, and the fundamental research had also been finished. In 1990s, new REFB including RE phosphate fertilizer additive, RE conversional agricultural film additive, RE water-retraining reagent and RE seed coating reagent had been developed out rapidly. They were extended to 1.36 million hectares and big benefit had been got during the last three years. Recently, it was found that RE has some function of antagonizing heavy metals and degradating organophosphors pesticide, so the REFB will be studied as a focus once more, and will become one of the important methods of guaranteeing food security in the future.展开更多
Using alkalescent ammonium(AAC)as precipitatnt, the diameter of nano La_2O_3 powder with diameter in 80 nm and less was prepared by the method of homogeneous precipitation, and reactant concentration, temperature and ...Using alkalescent ammonium(AAC)as precipitatnt, the diameter of nano La_2O_3 powder with diameter in 80 nm and less was prepared by the method of homogeneous precipitation, and reactant concentration, temperature and pH were studied and confirmed. The best precipitated concentration is from 0.2 to 0.5 mol·L^(-1), and the diameter of compounded powder turns small as the temperature gradually becomes high, and the pH from 6 to 8 is the best and the concentration of precipitant does not affect the diameter of compounded powder significantly. Meanwhile, most experiments lasting for fifty days in the greenhouse, and the results are 0.2 g·kg^(-1) nano La_2O_3 powder is enorgh for increasing biomass by 133% compared with that of the CK.展开更多
Salvia miltiorrhiza bunge(SMB) has been widely used as a traditional Chinese medicine for a long time,and today more and more attention has been paid to the effective components in Chinese traditional medicine,especia...Salvia miltiorrhiza bunge(SMB) has been widely used as a traditional Chinese medicine for a long time,and today more and more attention has been paid to the effective components in Chinese traditional medicine,especially to rare earth elements(REEs).14 kinds of REEs in SMB from different areas were analyzed by the methods of ICP-MS.The results showed that the total concentration of REEs(as REO,the same below) ranged from 8.43(as dry weight,the same below) to 37.30 mg/kg,and the concentrations of La,Ce and Nd were higher than 2 mg/kg except Nd in SMB from Beijing.So the total concentration of REEs in SMB was much higher than that in rice,corn and barley,which could be the mechanism of curative effect of SMB on cardiovascular cerebrovascular system,digestive system,respiratory system,countershock and antibiotic.The character of other elements and the content of REEs in soil from different areas should be responsible for the difference,but the allocation mechanism of REEs in SMB should be further studied.展开更多
Granite belonged to intrusive rock and volcanic was extrusive rock. There may be many differences in their degree of weathering and mineral chemical composition. The present study investigated the minerals properties ...Granite belonged to intrusive rock and volcanic was extrusive rock. There may be many differences in their degree of weathering and mineral chemical composition. The present study investigated the minerals properties and the leaching mechanism of the granitic weathered crust elution-deposited rare earth ore from Longnan Rare Earth Mine area （LN ores） and volcanic weathered crust elution-deposited rare earth ore from Liutang Rare Earth Mine area （LT ores）. The X-ray diffraction （XRD）, Fourier transform infrared spectroscopy （FT-IR） were used to characterize the phase of rare earth ores. The particle size distributions and main composition of the ore were also presented in this paper. The leaching mechanisms of two kinds of rare earth ores were analyzed with different kinetics models and could be described by the shrinking-core model. They were all inner diffusion-controlled leaching processes. The leaching equation of the kinetics of the LN ores could be expressed as：4 LN LN 1.096 10 2/3 0.377 8.314 0 2 3=0.1061 （1 ） Tr e tη η×？？？ ？ ？, leaching equation of kinetics of LT ores was 3 LT LT 4.640 10 2/3 0.411 8.314 0 32 3=8.33 101 （1 ） Tr e tη η×？？ ？×？ ？ ？. The rare earth leaching rate of LT ores was always lower in the same condition, and it would need more time and more （NH4）2SO4 consump-tion to achieve the same rare earth leaching efficiency, which would lead to more serious ammonia-nitrogen pollution. Therefore, magnesium salt was proposed as the leaching agent to eliminate ammonia-nitrogen pollution and further studies would be taken in the future.展开更多
基金Project supported by the National Important Tackling Researoh Foundation of China (2002BA315A-7)
文摘Rare earth phosphate fertilizer (REPF) as base fertilizer (750 kg per hm2) was applied in the western area of China during the "Tenth Five-Year Plan", and the results show as follows: compared with calcium superphosphate (CK), REPF increases crops yields for maize by 17.0%, for rice by 10.5%, for wheat by 24.2%, for potato by 18.5%, for cabbage by 16.3%, for Chinese cabbage by 16.4%, for beet by 6.5%; decreases the diseased plant rate for common smut of maize by 1.0%, for maize stalk rot by 1.2%, for wheat take-all disease by 7.8%, for wheat root rot by 3.2%, for potato blackleg disease by 1.4%, for potato late blight by 6.6%; increases the sugar content of beet by 0.9°S.
文摘The development and prospect of rare earth functional biomaterials (REFB) was discussed. From 1979 to 1985, the simple REFB (salts) has been developed, and the fundamental research including forms, effects, toxicity, conversion in soil, and analysis methods had been finished. Then, the RE feed additive materials had been developed, and the fundamental research had also been finished. In 1990s, new REFB including RE phosphate fertilizer additive, RE conversional agricultural film additive, RE water-retraining reagent and RE seed coating reagent had been developed out rapidly. They were extended to 1.36 million hectares and big benefit had been got during the last three years. Recently, it was found that RE has some function of antagonizing heavy metals and degradating organophosphors pesticide, so the REFB will be studied as a focus once more, and will become one of the important methods of guaranteeing food security in the future.
文摘Using alkalescent ammonium(AAC)as precipitatnt, the diameter of nano La_2O_3 powder with diameter in 80 nm and less was prepared by the method of homogeneous precipitation, and reactant concentration, temperature and pH were studied and confirmed. The best precipitated concentration is from 0.2 to 0.5 mol·L^(-1), and the diameter of compounded powder turns small as the temperature gradually becomes high, and the pH from 6 to 8 is the best and the concentration of precipitant does not affect the diameter of compounded powder significantly. Meanwhile, most experiments lasting for fifty days in the greenhouse, and the results are 0.2 g·kg^(-1) nano La_2O_3 powder is enorgh for increasing biomass by 133% compared with that of the CK.
基金Project supported by Foundation of Key Laboratory of Nuclear Analysis Techniques,Institute of High Energy Physics,Chinese Academy of Sciences (K139)Youth Foundation of General Research Institutes for Nonferrous Metals (83218)
文摘Salvia miltiorrhiza bunge(SMB) has been widely used as a traditional Chinese medicine for a long time,and today more and more attention has been paid to the effective components in Chinese traditional medicine,especially to rare earth elements(REEs).14 kinds of REEs in SMB from different areas were analyzed by the methods of ICP-MS.The results showed that the total concentration of REEs(as REO,the same below) ranged from 8.43(as dry weight,the same below) to 37.30 mg/kg,and the concentrations of La,Ce and Nd were higher than 2 mg/kg except Nd in SMB from Beijing.So the total concentration of REEs in SMB was much higher than that in rice,corn and barley,which could be the mechanism of curative effect of SMB on cardiovascular cerebrovascular system,digestive system,respiratory system,countershock and antibiotic.The character of other elements and the content of REEs in soil from different areas should be responsible for the difference,but the allocation mechanism of REEs in SMB should be further studied.
基金Project supported by the National Science and Technology Support Program of China(2012BAE01B02)
文摘Granite belonged to intrusive rock and volcanic was extrusive rock. There may be many differences in their degree of weathering and mineral chemical composition. The present study investigated the minerals properties and the leaching mechanism of the granitic weathered crust elution-deposited rare earth ore from Longnan Rare Earth Mine area （LN ores） and volcanic weathered crust elution-deposited rare earth ore from Liutang Rare Earth Mine area （LT ores）. The X-ray diffraction （XRD）, Fourier transform infrared spectroscopy （FT-IR） were used to characterize the phase of rare earth ores. The particle size distributions and main composition of the ore were also presented in this paper. The leaching mechanisms of two kinds of rare earth ores were analyzed with different kinetics models and could be described by the shrinking-core model. They were all inner diffusion-controlled leaching processes. The leaching equation of the kinetics of the LN ores could be expressed as：4 LN LN 1.096 10 2/3 0.377 8.314 0 2 3=0.1061 （1 ） Tr e tη η×？？？ ？ ？, leaching equation of kinetics of LT ores was 3 LT LT 4.640 10 2/3 0.411 8.314 0 32 3=8.33 101 （1 ） Tr e tη η×？？ ？×？ ？ ？. The rare earth leaching rate of LT ores was always lower in the same condition, and it would need more time and more （NH4）2SO4 consump-tion to achieve the same rare earth leaching efficiency, which would lead to more serious ammonia-nitrogen pollution. Therefore, magnesium salt was proposed as the leaching agent to eliminate ammonia-nitrogen pollution and further studies would be taken in the future.
