Two phase extraction methods which are based separately on phase-stepping and shifting curve are mainly used in phase-sensitive imaging in gating interferometry to determine the x-ray phase shift induced by an object ...Two phase extraction methods which are based separately on phase-stepping and shifting curve are mainly used in phase-sensitive imaging in gating interferometry to determine the x-ray phase shift induced by an object in the beam.In this paper,the authors perform a full comparative analysis and present the main virtues and limitations of these two methods according to the theoretical analysis of the grating interferometry.展开更多
The hierarchical structure of the composite cathodes brings in significant chemical complexity related to the interfaces,such as cathode electrolyte interphase.These interfaces account for only a small fraction of the...The hierarchical structure of the composite cathodes brings in significant chemical complexity related to the interfaces,such as cathode electrolyte interphase.These interfaces account for only a small fraction of the volume and mass,they could,however,have profound impacts on the cell-level electrochemistry.As the investigation of these interfaces becomes a crucial topic in the battery research,there is a need to properly study the surface chemistry,particularly to eliminate the biased,incomplete characterization provided by techniques that assume the homogeneous surface chemistry.Herein,we utilize nano-resolution spatially-resolved x-ray spectroscopic tools to probe the heterogeneity of the surface chemistry on LiNi0.8Mn0.1Co0.1O2 layered cathode secondary particles.Informed by the nano-resolution mapping of the Ni valance state,which serves as a measurement of the local surface chemistry,we construct a conceptual model to elucidate the electrochemical consequence of the inhomogeneous local impedance over the particle surface.Going beyond the implication in battery science,our work highlights a balance between the high-resolution probing the local chemistry and the statistical representativeness,which is particularly vital in the study of the highly complex material systems.展开更多
基金Project supported by the Key Program of the National Natural Science Foundation of China(Grant Nos.10490194 and 10734070) the National Natural Science Foundation of China(Grant Nos.10504033,10774144 and 10979055)+2 种基金the Knowledge Innovation Program of the Chinese Academy of Sciences(Grant No.KJCX2-YW-N42)the National Basic Research Program of China (Grant No.2009CB930804)the National Outstanding Youth Fund(Grant No.10125523)
文摘Two phase extraction methods which are based separately on phase-stepping and shifting curve are mainly used in phase-sensitive imaging in gating interferometry to determine the x-ray phase shift induced by an object in the beam.In this paper,the authors perform a full comparative analysis and present the main virtues and limitations of these two methods according to the theoretical analysis of the grating interferometry.
基金Project supported by U.S.Department of Energy,Office of Science,Office of Basic Energy Sciences under Contract No.DE-AC02-76SF00515National Science Foundation under Grant No.DMR-1832613.
文摘The hierarchical structure of the composite cathodes brings in significant chemical complexity related to the interfaces,such as cathode electrolyte interphase.These interfaces account for only a small fraction of the volume and mass,they could,however,have profound impacts on the cell-level electrochemistry.As the investigation of these interfaces becomes a crucial topic in the battery research,there is a need to properly study the surface chemistry,particularly to eliminate the biased,incomplete characterization provided by techniques that assume the homogeneous surface chemistry.Herein,we utilize nano-resolution spatially-resolved x-ray spectroscopic tools to probe the heterogeneity of the surface chemistry on LiNi0.8Mn0.1Co0.1O2 layered cathode secondary particles.Informed by the nano-resolution mapping of the Ni valance state,which serves as a measurement of the local surface chemistry,we construct a conceptual model to elucidate the electrochemical consequence of the inhomogeneous local impedance over the particle surface.Going beyond the implication in battery science,our work highlights a balance between the high-resolution probing the local chemistry and the statistical representativeness,which is particularly vital in the study of the highly complex material systems.
