The atomizations for ⅠA and ⅡA elements have been reported and classified into thermo-dissociation(atomization) elements (including K, Rb and Cs), the reduction ones (Ca, Sr and Ba)and the transition ones (Li,Na and...The atomizations for ⅠA and ⅡA elements have been reported and classified into thermo-dissociation(atomization) elements (including K, Rb and Cs), the reduction ones (Ca, Sr and Ba)and the transition ones (Li,Na and Mg). In order to characterize the interference three-dimensional tables, some new terms were named in [2], which shows the mutual interferences between thermo-dissociation elements. Besides the whole rule about ionization interferences of ⅠA elements, the blocking and dissociation interferences have been found out. The dissociation interferences of ⅠA chlorides happen only when lithium is determined.展开更多
Atomizations and mutual interferences of alkali metals in flames have been studied perfectly in two dimensions. Three-dimensional studies point out a new way to further develop flame spectrometry. As an example, the m...Atomizations and mutual interferences of alkali metals in flames have been studied perfectly in two dimensions. Three-dimensional studies point out a new way to further develop flame spectrometry. As an example, the method of three-dimensional tables was used to find the regionality and locality of interferences.展开更多
In the measurement of atomic absorption, as compared with the flame emission method, the spectral interference of cotenants are mainly due to the absorption bands of the molecular absorption species. On this subject, ...In the measurement of atomic absorption, as compared with the flame emission method, the spectral interference of cotenants are mainly due to the absorption bands of the molecular absorption species. On this subject, a detailed review has been made by Daidohji Hidehiro before. It has been also reported that there exist two kinds of typical molecular absorption interferences[2-6] which will be discussed in this paper. In air-C2H2 flames, cotenant calcium interferes severely with the determination of barium by atomic absorption. The mechanism was explained in terms of light scatter effect.展开更多
基金Project supported by the National Natural Science Foundation of China
文摘The atomizations for ⅠA and ⅡA elements have been reported and classified into thermo-dissociation(atomization) elements (including K, Rb and Cs), the reduction ones (Ca, Sr and Ba)and the transition ones (Li,Na and Mg). In order to characterize the interference three-dimensional tables, some new terms were named in [2], which shows the mutual interferences between thermo-dissociation elements. Besides the whole rule about ionization interferences of ⅠA elements, the blocking and dissociation interferences have been found out. The dissociation interferences of ⅠA chlorides happen only when lithium is determined.
基金Project supported by the National Natural Science Foundation of China.
文摘Atomizations and mutual interferences of alkali metals in flames have been studied perfectly in two dimensions. Three-dimensional studies point out a new way to further develop flame spectrometry. As an example, the method of three-dimensional tables was used to find the regionality and locality of interferences.
文摘In the measurement of atomic absorption, as compared with the flame emission method, the spectral interference of cotenants are mainly due to the absorption bands of the molecular absorption species. On this subject, a detailed review has been made by Daidohji Hidehiro before. It has been also reported that there exist two kinds of typical molecular absorption interferences[2-6] which will be discussed in this paper. In air-C2H2 flames, cotenant calcium interferes severely with the determination of barium by atomic absorption. The mechanism was explained in terms of light scatter effect.
