The self-assembly of 1,10-phenanthroline（phen） and 1,3-benzenedicarboxylic acid（H2bdc） with Pb（NO3）2 under solvothermal conditions in N,N-dimethylacetamide（DMA） gives rise to a one-dimensional chain coordinati...The self-assembly of 1,10-phenanthroline（phen） and 1,3-benzenedicarboxylic acid（H2bdc） with Pb（NO3）2 under solvothermal conditions in N,N-dimethylacetamide（DMA） gives rise to a one-dimensional chain coordination polymer, [Pb（phen）（bdc）]（1）, which was characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction. This complex crystallizes in triclinic, space group P1 with a = 7.5595（6）, b = 9.8199（8）, c = 13.1663（11） , α = 69.7590（10）, β = 80.6000（10）, γ = 71.3180（10）o, Z = 2, C20H12N2O4Pb, Mr = 551.51, Dc = 2.112 g/cm3, F（000） = 520 and μ = 9.757 mm-1. The final R = 0.0304 and wR = 0.0763 for 3427 observed reflections with I 〉 2σ（I） and R = 0.0365 and wR = 0.0894 for all data. The structure contains one crystallographic unique Pb（Ⅱ） atom, one phen molecule chelating with a Pb（Ⅱ） atom, and one bdc2- anion, acting as a bidentate bridging ligand linking the Pb（Ⅱ） atoms to form a one-dimensional structure. The two-dimensional layer and three-dimensional stacking structures are formed by C–H···O hydrogen bonding interactions. The thermal stable and fluorescent properties of 1 were investigated. PbO micro-crystal particles are produced by calcination of powder sample of complex 1. The obtained PbO is characterized and observed by XRD and SEM analyses.展开更多
基金supported by Natural Science Foundation of Anhui Province(1208085MB31)University Student Creative Project of China(201310377022)
文摘The self-assembly of 1,10-phenanthroline（phen） and 1,3-benzenedicarboxylic acid（H2bdc） with Pb（NO3）2 under solvothermal conditions in N,N-dimethylacetamide（DMA） gives rise to a one-dimensional chain coordination polymer, [Pb（phen）（bdc）]（1）, which was characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction. This complex crystallizes in triclinic, space group P1 with a = 7.5595（6）, b = 9.8199（8）, c = 13.1663（11） , α = 69.7590（10）, β = 80.6000（10）, γ = 71.3180（10）o, Z = 2, C20H12N2O4Pb, Mr = 551.51, Dc = 2.112 g/cm3, F（000） = 520 and μ = 9.757 mm-1. The final R = 0.0304 and wR = 0.0763 for 3427 observed reflections with I 〉 2σ（I） and R = 0.0365 and wR = 0.0894 for all data. The structure contains one crystallographic unique Pb（Ⅱ） atom, one phen molecule chelating with a Pb（Ⅱ） atom, and one bdc2- anion, acting as a bidentate bridging ligand linking the Pb（Ⅱ） atoms to form a one-dimensional structure. The two-dimensional layer and three-dimensional stacking structures are formed by C–H···O hydrogen bonding interactions. The thermal stable and fluorescent properties of 1 were investigated. PbO micro-crystal particles are produced by calcination of powder sample of complex 1. The obtained PbO is characterized and observed by XRD and SEM analyses.
