The polyaniline micro/nanostructure was prepared by a self-assembly process with molybdic acid as dopants in the presence of ammonium persulfate as the oxidant. It was found that the morphology of PANI micro/nanostruc...The polyaniline micro/nanostructure was prepared by a self-assembly process with molybdic acid as dopants in the presence of ammonium persulfate as the oxidant. It was found that the morphology of PANI micro/nanostruc- ture was affected by the concentration of the dopant, that is, the morphology of PANI changed from nanofibers to co-existence of nanofibers and microspheres as the molar ratio of molybdic acid to aniline varied from 0.01 to 1.5. Under the same condition it was also found that the conductivity value of PANI enhanced from 4.58 × 10^-3 S·cm^-1 to 3.8×10^-1 S·cm^-1. The structure of PANI was characterized by FTIR and XRD which confirmed the presence of the molybdic acid in the PANI. The electrochemical characteristics of the PANI nanofibers were investigated by means of cyclic voltammetry. The morphology of PAN1 in the process of polymerization was characterized by SEM It was found that when the molar ratio of molybdic acid to aniline was 0.3, the morphology of PANI was co-existence of nanofibers and microspheres and the formation of microspheres was ahead of the nanofibers.展开更多
基金Project supported by the National Natural Science Foundation of China （No. 20961001）, and the Education Department Foundation of Guangxu Province （No. 2010LX306）.
文摘The polyaniline micro/nanostructure was prepared by a self-assembly process with molybdic acid as dopants in the presence of ammonium persulfate as the oxidant. It was found that the morphology of PANI micro/nanostruc- ture was affected by the concentration of the dopant, that is, the morphology of PANI changed from nanofibers to co-existence of nanofibers and microspheres as the molar ratio of molybdic acid to aniline varied from 0.01 to 1.5. Under the same condition it was also found that the conductivity value of PANI enhanced from 4.58 × 10^-3 S·cm^-1 to 3.8×10^-1 S·cm^-1. The structure of PANI was characterized by FTIR and XRD which confirmed the presence of the molybdic acid in the PANI. The electrochemical characteristics of the PANI nanofibers were investigated by means of cyclic voltammetry. The morphology of PAN1 in the process of polymerization was characterized by SEM It was found that when the molar ratio of molybdic acid to aniline was 0.3, the morphology of PANI was co-existence of nanofibers and microspheres and the formation of microspheres was ahead of the nanofibers.
