To compensate for the shortcomings of the thermal and catalytic regeneration of the diesel particulate filter(DPF),a self-designed packed-bed dielectric barrier discharge(DBD)reactor for DPF regeneration was developed...To compensate for the shortcomings of the thermal and catalytic regeneration of the diesel particulate filter(DPF),a self-designed packed-bed dielectric barrier discharge(DBD)reactor for DPF regeneration was developed.The DBD reactor with the main active substance of nonthermal plasma(NTP)as the target parameter was optimized by adjusting the feed gas,packing particles(material or size),and cooling water temperature.Moreover,a set of optimal working parameters(gas source,O_2;packing particles,1.2–1.4 mm ZrO_(2);and cooling water temperature,20℃)was selected to evaluate the effect of different O_(3) concentrations on DPF regeneration.The research results showed that selecting packing particles with high dielectric constant and large particles,as well as reducing the cooling water temperature,with oxygen as the feed gas,contributed to an increase in O_(3) concentration.During DPF regeneration,the following changes were observed:the power of the NTP reactor decreased to lower than 100 W,the O_(3) concentration increased from 15 g m^(-3) to 45 g m^(-3),the CO and CO_2 volume fractions of the particulate matter decomposition products increased,and the peak regeneration temperature increased to 173.4℃.The peak temperature arrival time was 60 min earlier,indicating that the regeneration rate of DPF increased with the increase in O_(3) concentration.However,the O_(3) utilization rate(the amount of carbon deposit removed per unit volume O_(3))initially increased and then decreased;when the O_(3) concentration was set to 25 g m^(-3),the highest O_(3) utilization rate was reached.The packed-bed DBD technology contributed to the increase in the concentration of NTP active substances and the regeneration efficiency of DPF.It provides a theoretical and experimental basis for high-efficiency regeneration of DPF at low temperatures(<200℃).展开更多
Particulate matter(PM)capture tests were carried out on clean diesel particulate filters(DPFs)under different loads(25%,50%,75%and 100%).DPFs were regenerated by a non-thermal plasma(NTP)injection device.Raman spectro...Particulate matter(PM)capture tests were carried out on clean diesel particulate filters(DPFs)under different loads(25%,50%,75%and 100%).DPFs were regenerated by a non-thermal plasma(NTP)injection device.Raman spectroscopy and x-ray photoelectron spectroscopy were used to investigate changes in the microstructure and element occurrence state of the sediment in DPF channel before and after regeneration.The order of the PM samples decreased before NTP treatment as the load increased;the amorphous carbon content was high,and the oxidationactivity was higher.After NTP treatment,the carbon atoms at the edge of the microcrystalline structure in the ash-PM samples were oxidized,and the structure was reorganized;in addition,the amorphous carbon content decreased,and the structure was more diversified.Before NTP,the C element of PM samples was the main component,and the content of the O element was relatively low.The C element occurred in the form of C–C,C–OH,and O–C=O functional groups,and O atoms were mainly combined with C–O.After NTP,the content of Na,P,S,Ca,and other inorganic elements in ash-PM samples was prominent because C atoms were removed by NTP active substances.There were two forms of S element occurrence(SO42-and SO32-);the proportion of SO42-was approximately 40%,and the proportion of SO32-was approximately60%.Study of the microstructure and element occurrence of the residues in the DPF channels improved our understanding of the mechanism of the low-temperature regeneration of DPFfrom NTP.展开更多
Packed-bed reactors(PBRs)hold great promise for environmental applications,but a deeper understanding of the behavior of plasma discharge within PBRs is required.To this end,a partial-discharge alternative equivalent ...Packed-bed reactors(PBRs)hold great promise for environmental applications,but a deeper understanding of the behavior of plasma discharge within PBRs is required.To this end,a partial-discharge alternative equivalent circuit for PBRs was established in this work.Dielectric particles(glass beads or glass sand)were used to place focus on the effects of the particle size and shape on the partial discharge behavior of the oxygen PBRs.Some electrical characterizations were explored(e.g.the effective dielectric capacitance,partial discharge coefficient,and corrected burning voltage)that may differ from long-standing interpretations.The findings indicate that the suppressive effect of surface discharge on filament discharge is stronger with the decrease of the particle size.For partial discharge,the effective dielectric capacitance is always less than the dielectric capacitance.The corrected burning voltage and partial discharge tendency increase with the decrease of the particle size.As compared to an empty reactor,the average electric field in the PBR was found to be improved by 3–4 times,and the ozone energy efficiency and production were promoted by more than 20%and 15%,respectively.The plasma processing capacity can therefore be improved by choosing a relatively large size or a complex,irregularly-shaped packing material that is suitable for the discharge gap.展开更多
基金supported by National Natural Science Foundation of China (No. 51806085)China Postdoctoral Science Foundation (No. 2018M642175)+2 种基金Jiangsu Planned Projects for Postdoctoral Research Fund (No. 2018K101C)Open Research Subject of Key Laboratory of Automotive Measurement, Control and Safety (Xihua University) (No. QCCK2021-007)the Graduate Student Innovation Fund Project of Jiangsu Province (No. KYCX21_3354)
文摘To compensate for the shortcomings of the thermal and catalytic regeneration of the diesel particulate filter(DPF),a self-designed packed-bed dielectric barrier discharge(DBD)reactor for DPF regeneration was developed.The DBD reactor with the main active substance of nonthermal plasma(NTP)as the target parameter was optimized by adjusting the feed gas,packing particles(material or size),and cooling water temperature.Moreover,a set of optimal working parameters(gas source,O_2;packing particles,1.2–1.4 mm ZrO_(2);and cooling water temperature,20℃)was selected to evaluate the effect of different O_(3) concentrations on DPF regeneration.The research results showed that selecting packing particles with high dielectric constant and large particles,as well as reducing the cooling water temperature,with oxygen as the feed gas,contributed to an increase in O_(3) concentration.During DPF regeneration,the following changes were observed:the power of the NTP reactor decreased to lower than 100 W,the O_(3) concentration increased from 15 g m^(-3) to 45 g m^(-3),the CO and CO_2 volume fractions of the particulate matter decomposition products increased,and the peak regeneration temperature increased to 173.4℃.The peak temperature arrival time was 60 min earlier,indicating that the regeneration rate of DPF increased with the increase in O_(3) concentration.However,the O_(3) utilization rate(the amount of carbon deposit removed per unit volume O_(3))initially increased and then decreased;when the O_(3) concentration was set to 25 g m^(-3),the highest O_(3) utilization rate was reached.The packed-bed DBD technology contributed to the increase in the concentration of NTP active substances and the regeneration efficiency of DPF.It provides a theoretical and experimental basis for high-efficiency regeneration of DPF at low temperatures(<200℃).
基金supported by National Natural Science Foundation of China(No.51806085)China Postdoctoral Science Foundation(No.2018M642175)+2 种基金Jiangsu Planned Projects for Postdoctoral Research Fund(No.2018K101C)Open Research Subject of Key Laboratory of automotive measurement,control and safety(Xihua University)(No.QCCK2021-007)Graduate Student Innovation Fund Project of Jiangsu Province(No.KYCX213354)。
文摘Particulate matter(PM)capture tests were carried out on clean diesel particulate filters(DPFs)under different loads(25%,50%,75%and 100%).DPFs were regenerated by a non-thermal plasma(NTP)injection device.Raman spectroscopy and x-ray photoelectron spectroscopy were used to investigate changes in the microstructure and element occurrence state of the sediment in DPF channel before and after regeneration.The order of the PM samples decreased before NTP treatment as the load increased;the amorphous carbon content was high,and the oxidationactivity was higher.After NTP treatment,the carbon atoms at the edge of the microcrystalline structure in the ash-PM samples were oxidized,and the structure was reorganized;in addition,the amorphous carbon content decreased,and the structure was more diversified.Before NTP,the C element of PM samples was the main component,and the content of the O element was relatively low.The C element occurred in the form of C–C,C–OH,and O–C=O functional groups,and O atoms were mainly combined with C–O.After NTP,the content of Na,P,S,Ca,and other inorganic elements in ash-PM samples was prominent because C atoms were removed by NTP active substances.There were two forms of S element occurrence(SO42-and SO32-);the proportion of SO42-was approximately 40%,and the proportion of SO32-was approximately60%.Study of the microstructure and element occurrence of the residues in the DPF channels improved our understanding of the mechanism of the low-temperature regeneration of DPFfrom NTP.
基金supported by National Natural Science Foundation of China(Nos.51806085,51676089)China Postdoctoral Science Foundation(2018M642175)the Double Innovation Talents of Jiangsu Province and Jiangsu University Youth Talent Cultivation Program Funded Project
文摘Packed-bed reactors(PBRs)hold great promise for environmental applications,but a deeper understanding of the behavior of plasma discharge within PBRs is required.To this end,a partial-discharge alternative equivalent circuit for PBRs was established in this work.Dielectric particles(glass beads or glass sand)were used to place focus on the effects of the particle size and shape on the partial discharge behavior of the oxygen PBRs.Some electrical characterizations were explored(e.g.the effective dielectric capacitance,partial discharge coefficient,and corrected burning voltage)that may differ from long-standing interpretations.The findings indicate that the suppressive effect of surface discharge on filament discharge is stronger with the decrease of the particle size.For partial discharge,the effective dielectric capacitance is always less than the dielectric capacitance.The corrected burning voltage and partial discharge tendency increase with the decrease of the particle size.As compared to an empty reactor,the average electric field in the PBR was found to be improved by 3–4 times,and the ozone energy efficiency and production were promoted by more than 20%and 15%,respectively.The plasma processing capacity can therefore be improved by choosing a relatively large size or a complex,irregularly-shaped packing material that is suitable for the discharge gap.
