The title complex has been synthesized with 2,2＇-biphenyl dicarboxylic acid and 1,10-phenanthroline（phen）in the solvent mixture of water and methanol.It crystallizes（C38H28CuN4O6,Mr = 700.1）in triclinic,space gro...The title complex has been synthesized with 2,2＇-biphenyl dicarboxylic acid and 1,10-phenanthroline（phen）in the solvent mixture of water and methanol.It crystallizes（C38H28CuN4O6,Mr = 700.1）in triclinic,space group P1 with a = 1.0868（2）,b = 1.2175（2）,c = 1.6206（3）nm,α = 110.161（2）,β = 102.605（3）,γ = 93.667（2）o,V = 1941.6（6）nm3,Dc = 1.198 g/cm3,Z = 2,F（000）= 722,R = 0.0558 and wR = 0.1208.The crystal structure shows that the copper atom is coordinated with one oxygen atom from 2,2＇-bphenyl dicarboxylic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules,forming a distorted square-pyramidal coordination.The TG analysis shows that the title complex is stable under 160.0 ℃.展开更多
A new manganese(Ⅱ) complex [Mn(C_(14)H_(9)O_(3))_(2)(C_(12)H_(8)N_(2))_(2)]·4H_(2)O(1) was synthesized with o-benzoylbenzoic acid, manganese sulfate and 1,10-phenanthroline(phen) in the mixture of acetonitrile a...A new manganese(Ⅱ) complex [Mn(C_(14)H_(9)O_(3))_(2)(C_(12)H_(8)N_(2))_(2)]·4H_(2)O(1) was synthesized with o-benzoylbenzoic acid, manganese sulfate and 1,10-phenanthroline(phen) in the mixture of acetonitrile and water solvent. It crystallizes(C_(52)H_(42)MnN_(4)O_(10), M_(r) = 937.83) in monoclinic, space group P2_(1/n) with a = 13.3528(5), b = 17.6963(6), c = 19.7889(7) A, β = 109.647(4)o, V = 4403.8(3) A3, D_(c) = 1.415 g/cm^(3), Z = 4, F(000) = 1948, μ(Mo Kα) = 0.368 mm^(-1), R = 0.0404 and w R = 0.0956. The crystal structure shows that the manganese ion is coordinated with two oxygen atoms from two o-benzoylbenzoic acid molecules and four nitrogen atoms from two phen molecules, forming a distorted octahedral coordination geometry. The TG, spectrum analysis and magnetic properties of 1 were studied.展开更多
基金Supported by the Natural Science Foundation of Hunan Province (No.11JJ9006)Science and Technology Committee of Hunan Province (2009FJ3101)Science and Technology Committee of Hengyang (2011kj25)
文摘The title complex has been synthesized with 2,2＇-biphenyl dicarboxylic acid and 1,10-phenanthroline（phen）in the solvent mixture of water and methanol.It crystallizes（C38H28CuN4O6,Mr = 700.1）in triclinic,space group P1 with a = 1.0868（2）,b = 1.2175（2）,c = 1.6206（3）nm,α = 110.161（2）,β = 102.605（3）,γ = 93.667（2）o,V = 1941.6（6）nm3,Dc = 1.198 g/cm3,Z = 2,F（000）= 722,R = 0.0558 and wR = 0.1208.The crystal structure shows that the copper atom is coordinated with one oxygen atom from 2,2＇-bphenyl dicarboxylic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules,forming a distorted square-pyramidal coordination.The TG analysis shows that the title complex is stable under 160.0 ℃.
基金Supported by the Natural Science Foundation of Hunan Province(2019JJ60021)Industry and Research Key Project of Hengyang City(2019jhzx1093)。
文摘A new manganese(Ⅱ) complex [Mn(C_(14)H_(9)O_(3))_(2)(C_(12)H_(8)N_(2))_(2)]·4H_(2)O(1) was synthesized with o-benzoylbenzoic acid, manganese sulfate and 1,10-phenanthroline(phen) in the mixture of acetonitrile and water solvent. It crystallizes(C_(52)H_(42)MnN_(4)O_(10), M_(r) = 937.83) in monoclinic, space group P2_(1/n) with a = 13.3528(5), b = 17.6963(6), c = 19.7889(7) A, β = 109.647(4)o, V = 4403.8(3) A3, D_(c) = 1.415 g/cm^(3), Z = 4, F(000) = 1948, μ(Mo Kα) = 0.368 mm^(-1), R = 0.0404 and w R = 0.0956. The crystal structure shows that the manganese ion is coordinated with two oxygen atoms from two o-benzoylbenzoic acid molecules and four nitrogen atoms from two phen molecules, forming a distorted octahedral coordination geometry. The TG, spectrum analysis and magnetic properties of 1 were studied.
