Electromagnetic interference(EMI)and radiation of electronic devices are ubiquitous,which are potentially hazardous to the normal operation of electronic equipment and human health.MXenes are extremely attractive in t...Electromagnetic interference(EMI)and radiation of electronic devices are ubiquitous,which are potentially hazardous to the normal operation of electronic equipment and human health.MXenes are extremely attractive in the preparation of EMI shielding materials due to their excellent metallic conductivity and tunable surface chemistry.Herein,by virtue of the designed nanostructure and regulation of interface interactions,we fabricated flexible Fe_(3)O_(4)@Ti_(3)C_(2)Tx MXene/3,4-dihydroxyphenylacetic acid(DOPAC)-epoxidized natural rubber(ENR)elastomers(FMDE)with 3D segregated interconnected structures.The elaborately designed metalligand coordination crosslinking between Fe_(3)O_(4)nanoparticles and DOPAC ligand molecules provides strong interfacial interactions,resulting in significantly reinforced mechanical properties.Compared with Ti_(3)C_(2)Tx/ENR elastomers,the maximum tensile strength and toughness of FMDE are elevadted by~306%and 475%,respectively.Moreover,the 3D segregated conductive network constructed by Fe_(3)O_(4)@Ti_(3)C_(2)Tx nanoflakes resulted from volume exclusion effect of ENR latex and the introduction of magnetic Fe_(3)O_(4)nanoparticles with enhanced electromagnetic wave absorption greatly improved the EMI shielding performance of FMDE,exhibiting an excellent EMI shielding effectiveness of up to 58 dB in the X band(8.2–12.4 GHz)and stable EMI shielding capability during repeated deformations.This work provides a promising strategy for the design and manufacture of novel flexible EMI shielding materials.展开更多
基金supported by the National Natural Science Foundation of China (51861165203)China Postdoctoral Science Foundation (2019M653398)+1 种基金Sichuan Science and Technology Program (2020YJ0261)Shiyanjia Lab (www.shiyanjia.com) for the support of VSM and XRD test
文摘Electromagnetic interference(EMI)and radiation of electronic devices are ubiquitous,which are potentially hazardous to the normal operation of electronic equipment and human health.MXenes are extremely attractive in the preparation of EMI shielding materials due to their excellent metallic conductivity and tunable surface chemistry.Herein,by virtue of the designed nanostructure and regulation of interface interactions,we fabricated flexible Fe_(3)O_(4)@Ti_(3)C_(2)Tx MXene/3,4-dihydroxyphenylacetic acid(DOPAC)-epoxidized natural rubber(ENR)elastomers(FMDE)with 3D segregated interconnected structures.The elaborately designed metalligand coordination crosslinking between Fe_(3)O_(4)nanoparticles and DOPAC ligand molecules provides strong interfacial interactions,resulting in significantly reinforced mechanical properties.Compared with Ti_(3)C_(2)Tx/ENR elastomers,the maximum tensile strength and toughness of FMDE are elevadted by~306%and 475%,respectively.Moreover,the 3D segregated conductive network constructed by Fe_(3)O_(4)@Ti_(3)C_(2)Tx nanoflakes resulted from volume exclusion effect of ENR latex and the introduction of magnetic Fe_(3)O_(4)nanoparticles with enhanced electromagnetic wave absorption greatly improved the EMI shielding performance of FMDE,exhibiting an excellent EMI shielding effectiveness of up to 58 dB in the X band(8.2–12.4 GHz)and stable EMI shielding capability during repeated deformations.This work provides a promising strategy for the design and manufacture of novel flexible EMI shielding materials.
