利用建立起来的理论模型,深入研究了联合电解催化交换(Combined Electrolysis and Catalytic Exchange,CECE)工艺中各种因素对氢同位素分离性能的影响。电解池分离因子的提高对浓缩倍数和脱氚率均有显著影响,降低电解池滞留量是提高浓...利用建立起来的理论模型,深入研究了联合电解催化交换(Combined Electrolysis and Catalytic Exchange,CECE)工艺中各种因素对氢同位素分离性能的影响。电解池分离因子的提高对浓缩倍数和脱氚率均有显著影响,降低电解池滞留量是提高浓缩倍数的有效手段。进料位置在1.5m处系统性能好于3m处;催化剂传质系数在3~4mol·m-3·s-1范围内,浓缩倍数和脱氚率基本呈线性增长。各种因素对HD/H2O和HT/H2O两个体系的影响具有相似的规律性,由于热力学因素的差异,相同条件下,HT/H2O体系分离性能好于HD/H2O。展开更多
为研究带侧线反馈的低温精馏氢同位素分离规律性,建立了带侧线反馈的低温精馏氢同位素分离计算方法,并以H2/HD/D2体系进行了计算分析。计算结果表明,侧线反馈对分离性能影响显著,再沸器中以D2为主,氘丰度可达到0.90,而无侧线反馈情况下...为研究带侧线反馈的低温精馏氢同位素分离规律性,建立了带侧线反馈的低温精馏氢同位素分离计算方法,并以H2/HD/D2体系进行了计算分析。计算结果表明,侧线反馈对分离性能影响显著,再沸器中以D2为主,氘丰度可达到0.90,而无侧线反馈情况下,再沸器中以HD为主,氘丰度不超过0.50;有侧线反馈条件下,系统运行约40 h HD向D2的转化达到峰值,而在无侧线情况下,HD浓缩在40 h已达到饱和;当侧线采出比为1时,脱氘率最高。展开更多
A theoretical model was built to study the separation of hydrogen isotopes by the electrolysis-distillation process,and the separation performance of H2/HD/HT was investigated.Enrichment behavior of both electrolysis ...A theoretical model was built to study the separation of hydrogen isotopes by the electrolysis-distillation process,and the separation performance of H2/HD/HT was investigated.Enrichment behavior of both electrolysis and distillation was obtained: HDO and HTO concentration in electrolysis reached 8.35×10-4 and 6.34×10-6 respectively;HD and HT concentration in reboiler finally reached 0.033 and 6.06×10-5 respectively.For the difference of separation factor for H/D and H/T,about 63.4% HTO stay in electrolysis cell which brought a poorer HT enrichment in reboiler compared with that of HD.As enrichment developed,deuterium(tritium) extraction efficiency decreased with time.展开更多
文摘利用建立起来的理论模型,深入研究了联合电解催化交换(Combined Electrolysis and Catalytic Exchange,CECE)工艺中各种因素对氢同位素分离性能的影响。电解池分离因子的提高对浓缩倍数和脱氚率均有显著影响,降低电解池滞留量是提高浓缩倍数的有效手段。进料位置在1.5m处系统性能好于3m处;催化剂传质系数在3~4mol·m-3·s-1范围内,浓缩倍数和脱氚率基本呈线性增长。各种因素对HD/H2O和HT/H2O两个体系的影响具有相似的规律性,由于热力学因素的差异,相同条件下,HT/H2O体系分离性能好于HD/H2O。
文摘为研究带侧线反馈的低温精馏氢同位素分离规律性,建立了带侧线反馈的低温精馏氢同位素分离计算方法,并以H2/HD/D2体系进行了计算分析。计算结果表明,侧线反馈对分离性能影响显著,再沸器中以D2为主,氘丰度可达到0.90,而无侧线反馈情况下,再沸器中以HD为主,氘丰度不超过0.50;有侧线反馈条件下,系统运行约40 h HD向D2的转化达到峰值,而在无侧线情况下,HD浓缩在40 h已达到饱和;当侧线采出比为1时,脱氘率最高。
文摘A theoretical model was built to study the separation of hydrogen isotopes by the electrolysis-distillation process,and the separation performance of H2/HD/HT was investigated.Enrichment behavior of both electrolysis and distillation was obtained: HDO and HTO concentration in electrolysis reached 8.35×10-4 and 6.34×10-6 respectively;HD and HT concentration in reboiler finally reached 0.033 and 6.06×10-5 respectively.For the difference of separation factor for H/D and H/T,about 63.4% HTO stay in electrolysis cell which brought a poorer HT enrichment in reboiler compared with that of HD.As enrichment developed,deuterium(tritium) extraction efficiency decreased with time.