A new set of reaction conditions has been established and allowed for the first non-noble Cu(II)-catalyzed asymmetric 1,4-hydrosilylation ofN-aryl β-enamino esters under air to afford a selection ofN-aryl β-amino ...A new set of reaction conditions has been established and allowed for the first non-noble Cu(II)-catalyzed asymmetric 1,4-hydrosilylation ofN-aryl β-enamino esters under air to afford a selection ofN-aryl β-amino acid es- ters of moderate-to-good enantiopurities (ee up to 91%).展开更多
文摘A new set of reaction conditions has been established and allowed for the first non-noble Cu(II)-catalyzed asymmetric 1,4-hydrosilylation ofN-aryl β-enamino esters under air to afford a selection ofN-aryl β-amino acid es- ters of moderate-to-good enantiopurities (ee up to 91%).