Cp_(2)TiCl_(2)-LiAlH_(4)体系的研究——芳香族二元醇、二元酮及其它有机官能团的还原

本文报道了Cp_(2)TjCl_(2)-LiAlH_(4)体系对芳香族二元醇、 二元酮及其它有机官能团的还原作用,发现对于不同的芳香族二元醇、二元酮等,其还原反应产物的组成不同。

Cp_2ZrCl_2-i-BuMgBr试剂体系的研究——烯烃和炔烃的还原二聚反应和二烯烃的环化

二氯二茂锆同异丁基格氏试剂以1:2摩尔比反应,于室温下生成有机锆中间体,后者同烯烃、炔烃或二烯反应,最后生成还原的二聚物或分子内环化产物。

HYDROBORATION OF ALKENES,ALKADIENES AND OXYGEN-CONTAINING UNSATURATED COMPOUNDS WITH SODIUM BOROHY-DRIDES CATALYZED BY ZIRCONIUM COMPLEX

We have previously reported that the Ti complex generated from Cp2TiCl2 and LiBH4 serves as a catalyst for hydroboration of alkenes. Sodium borohydride can also be utilized as a reagent for hydroboration if reaction is carried out in the pre-