The title compound [(CH 3CH 2) 4N] 4H 3O{Na[(HMo 2O 5) 3(HPO 4)(H 2PO 4) 3] 2}·(H 2PO 4) 2·10H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X ray analysis. T...The title compound [(CH 3CH 2) 4N] 4H 3O{Na[(HMo 2O 5) 3(HPO 4)(H 2PO 4) 3] 2}·(H 2PO 4) 2·10H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X ray analysis. The cluster anion of the title compound shows a P1 symmetry sandwich structure. The crystal is triclinic, space group P 1 with a =15.151 3(2) nm, b =15.851 7(10) nm, c =23\^025 1(10) nm, α = 89.00(1)° , β =80.09(3)°, γ = 74.30(2)°, V =5.241 90(8) nm 3, Z =2, D c=2.105 g/cm 3, F (000)=3 270, S =1.039, μ =1. 655 mm -1 .展开更多
The by products from the dehydration of exo 2 camphanol in the camphor manufacture by hydration process contains two unknown components: A in 14% and B in 15%. The sample mixture containing 90% A and B with different ...The by products from the dehydration of exo 2 camphanol in the camphor manufacture by hydration process contains two unknown components: A in 14% and B in 15%. The sample mixture containing 90% A and B with different mass ratio(ca. 1∶1, 1∶2 and 1∶4) were collected by further fine fractional distillation with 60 plate number for spectroscopic characterization. The combined spectral results of GC, MS and 13 C NMR of the samples revealed that A is exo 2,2,3 trimethylbicyclo[2,2,1]heptane(exo isocamphane) and B is endo 2,2,3 trimethylbicyclo[2,2,1]heptane(endo isocomphane).展开更多
There exists an optimal range of intensity of a chaotic force in which the behavior of a chaos-driven bistable system with two weak inputs can be consistently mapped to a specific logic output. This phenomenon is call...There exists an optimal range of intensity of a chaotic force in which the behavior of a chaos-driven bistable system with two weak inputs can be consistently mapped to a specific logic output. This phenomenon is called logical chaotic resonance(LCR). However, realization of a reliable exclusive disjunction(XOR) through LCR has not been reported.Here, we explore the possibility of using chaos to enhance the reliability of XOR logic operation in a triple-well potential system via LCR. The success probability P of obtaining XOR logic operation can take the maximum value of 1 in an optimal window of intensity D of a chaotic force. Namely, success probability P displays characteristic bell-shaped behavior by altering the intensity of the chaotic driving force, indicating the occurrence of LCR. Further, the effects of periodic force on LCR have been investigated. For a subthreshold chaotic force, a periodic force with appropriate amplitude and frequency can help enhance the reliability of XOR logic operation. Thus, LCR can be effectively regulated by changing the amplitude and frequency of the periodic force.展开更多
Logical resonance has been demonstrated to be present in the Fitz Hugh-Nagumo(FHN)neuron,namely,the FHN neuron can operate as a reliable logic gate within an optimal parameter window.Here we attempt to extend the resu...Logical resonance has been demonstrated to be present in the Fitz Hugh-Nagumo(FHN)neuron,namely,the FHN neuron can operate as a reliable logic gate within an optimal parameter window.Here we attempt to extend the results to the more biologically realistic Hodgkin-Huxley(HH)model of neurons.In general,biological organisms have an optimal temperature at which the biological functions are most effective.In view of this,we examine if there is an optimal range of temperature where the HH neuron can work like a specific logic gate,and how temperature influences the logical resonance.Here we use the success probability P to measure the reliability of the specific logic gate.For AND logic gate,P increases with temperature T,reaches the maximum in an optimal window of T,and eventually decreases,which indicates the occurrence of the temperature-induced logical resonance phenomenon in the HH neuron.Moreover,single and double logical resonances can be induced by altering the frequency of the modulating periodic signal under the proper temperatures,suggesting the appearance of temperature-controlled transition of logical resonance.These results provide important clues for constructing neuron-based energy-efficient new-fashioned logical devices.展开更多
文摘The title compound [(CH 3CH 2) 4N] 4H 3O{Na[(HMo 2O 5) 3(HPO 4)(H 2PO 4) 3] 2}·(H 2PO 4) 2·10H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X ray analysis. The cluster anion of the title compound shows a P1 symmetry sandwich structure. The crystal is triclinic, space group P 1 with a =15.151 3(2) nm, b =15.851 7(10) nm, c =23\^025 1(10) nm, α = 89.00(1)° , β =80.09(3)°, γ = 74.30(2)°, V =5.241 90(8) nm 3, Z =2, D c=2.105 g/cm 3, F (000)=3 270, S =1.039, μ =1. 655 mm -1 .
文摘The by products from the dehydration of exo 2 camphanol in the camphor manufacture by hydration process contains two unknown components: A in 14% and B in 15%. The sample mixture containing 90% A and B with different mass ratio(ca. 1∶1, 1∶2 and 1∶4) were collected by further fine fractional distillation with 60 plate number for spectroscopic characterization. The combined spectral results of GC, MS and 13 C NMR of the samples revealed that A is exo 2,2,3 trimethylbicyclo[2,2,1]heptane(exo isocamphane) and B is endo 2,2,3 trimethylbicyclo[2,2,1]heptane(endo isocomphane).
基金supported by the Technology Innovation Team Program in Higher Education Institutions in Hubei Province, China (Grant No. T2020039)。
文摘There exists an optimal range of intensity of a chaotic force in which the behavior of a chaos-driven bistable system with two weak inputs can be consistently mapped to a specific logic output. This phenomenon is called logical chaotic resonance(LCR). However, realization of a reliable exclusive disjunction(XOR) through LCR has not been reported.Here, we explore the possibility of using chaos to enhance the reliability of XOR logic operation in a triple-well potential system via LCR. The success probability P of obtaining XOR logic operation can take the maximum value of 1 in an optimal window of intensity D of a chaotic force. Namely, success probability P displays characteristic bell-shaped behavior by altering the intensity of the chaotic driving force, indicating the occurrence of LCR. Further, the effects of periodic force on LCR have been investigated. For a subthreshold chaotic force, a periodic force with appropriate amplitude and frequency can help enhance the reliability of XOR logic operation. Thus, LCR can be effectively regulated by changing the amplitude and frequency of the periodic force.
基金This Project supported by the National Natural Science Foundation of China (Grant No.11804111)。
文摘Logical resonance has been demonstrated to be present in the Fitz Hugh-Nagumo(FHN)neuron,namely,the FHN neuron can operate as a reliable logic gate within an optimal parameter window.Here we attempt to extend the results to the more biologically realistic Hodgkin-Huxley(HH)model of neurons.In general,biological organisms have an optimal temperature at which the biological functions are most effective.In view of this,we examine if there is an optimal range of temperature where the HH neuron can work like a specific logic gate,and how temperature influences the logical resonance.Here we use the success probability P to measure the reliability of the specific logic gate.For AND logic gate,P increases with temperature T,reaches the maximum in an optimal window of T,and eventually decreases,which indicates the occurrence of the temperature-induced logical resonance phenomenon in the HH neuron.Moreover,single and double logical resonances can be induced by altering the frequency of the modulating periodic signal under the proper temperatures,suggesting the appearance of temperature-controlled transition of logical resonance.These results provide important clues for constructing neuron-based energy-efficient new-fashioned logical devices.
