The crystallographic structure and intrinsic magnetic properties have been investigated in the RTiFe_(11) compounds, where Rrepresents Nd, Sin, Gd, Tb, Dy, Ho, Er and Y. The magnetic structure and the exchange interac...The crystallographic structure and intrinsic magnetic properties have been investigated in the RTiFe_(11) compounds, where Rrepresents Nd, Sin, Gd, Tb, Dy, Ho, Er and Y. The magnetic structure and the exchange interaction between various magnetic ions in RT Fe_(11) have been analysed. It is found that the intensity of R-Fe exchange interaction is proportional to((?)—1)~2J(J—1) for the heavy-rare-earth ions. while for the light rare earth, the effect caused by 5d-4f electron exchange interaction varying with rare-earth atoms must be taken into account. In RTiFe_(11) compounds the interatomic distance dependence on the exchange interaction between Fe-Fe atoms has been observed, and the result of enhancing the Curie temperature has been obtained. The Fe atomic magnetic moment in RTiFe_(11) is discussed in terms of the band theory, and the approach has been investigated on enhancement of saturation magnetization by means of substitution of atoms. RTiFe_(11) compoumds reveal a variety of magnetocrystalline anisotropy behaviors. For Fe sublattice the easy magnetization direction and the variation of the anisotropy constants with temperature have been measured with X-ray and magnetic techniques. On the basis of the crystalline field theory, by using a single-ion model, the anisotropy conatants and their temperature dependence of the R ions have been calculated, which helps explain the spin reorientations observed in RTiFe_(11).展开更多
文摘The crystallographic structure and intrinsic magnetic properties have been investigated in the RTiFe_(11) compounds, where Rrepresents Nd, Sin, Gd, Tb, Dy, Ho, Er and Y. The magnetic structure and the exchange interaction between various magnetic ions in RT Fe_(11) have been analysed. It is found that the intensity of R-Fe exchange interaction is proportional to((?)—1)~2J(J—1) for the heavy-rare-earth ions. while for the light rare earth, the effect caused by 5d-4f electron exchange interaction varying with rare-earth atoms must be taken into account. In RTiFe_(11) compounds the interatomic distance dependence on the exchange interaction between Fe-Fe atoms has been observed, and the result of enhancing the Curie temperature has been obtained. The Fe atomic magnetic moment in RTiFe_(11) is discussed in terms of the band theory, and the approach has been investigated on enhancement of saturation magnetization by means of substitution of atoms. RTiFe_(11) compoumds reveal a variety of magnetocrystalline anisotropy behaviors. For Fe sublattice the easy magnetization direction and the variation of the anisotropy constants with temperature have been measured with X-ray and magnetic techniques. On the basis of the crystalline field theory, by using a single-ion model, the anisotropy conatants and their temperature dependence of the R ions have been calculated, which helps explain the spin reorientations observed in RTiFe_(11).
