We examine RCoO3 （R=La, Ce, Pr, Nd, Sin, Eu, Gd, and Dy） perovskites prepared with the solid-state reaction method by Raman spectroscopy, and report the Raman active phonons in the RCoO3 perovskites crystallized in ...We examine RCoO3 （R=La, Ce, Pr, Nd, Sin, Eu, Gd, and Dy） perovskites prepared with the solid-state reaction method by Raman spectroscopy, and report the Raman active phonons in the RCoO3 perovskites crystallized in cubic symmetry for RCoO3 （R=La, Ce, Pr and Nd） and orthorhombic symmetry for RCoO3 （R=Sm, Eu, Gd, and Dy）. It is found that the Raman spectra of RCoO3 perovskites are strongly dependent on the ionic radius of the rare earth elements, and the frequency shift of the most intense modes of the orthorhombic samples are correlated with some structural parameters such as Co-O bond distances, ionic radius of the rare earth elements and Jahn-Teller distortion. It is clear that Raman spectroscopy has the advantage of sensitivity to structure distortion and oxygen motion.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 30370406.
文摘We examine RCoO3 （R=La, Ce, Pr, Nd, Sin, Eu, Gd, and Dy） perovskites prepared with the solid-state reaction method by Raman spectroscopy, and report the Raman active phonons in the RCoO3 perovskites crystallized in cubic symmetry for RCoO3 （R=La, Ce, Pr and Nd） and orthorhombic symmetry for RCoO3 （R=Sm, Eu, Gd, and Dy）. It is found that the Raman spectra of RCoO3 perovskites are strongly dependent on the ionic radius of the rare earth elements, and the frequency shift of the most intense modes of the orthorhombic samples are correlated with some structural parameters such as Co-O bond distances, ionic radius of the rare earth elements and Jahn-Teller distortion. It is clear that Raman spectroscopy has the advantage of sensitivity to structure distortion and oxygen motion.
