A novel Schiff-base compound based on ferrocene C18H17OFeN3 (1) has been synthesized and characterized by X-ray diffraction. The title compound crystallizes in monoclinic, space group P21/c with a = 19.2343(17), b...A novel Schiff-base compound based on ferrocene C18H17OFeN3 (1) has been synthesized and characterized by X-ray diffraction. The title compound crystallizes in monoclinic, space group P21/c with a = 19.2343(17), b = 10.5084(9), c = 7.9373(7) A, β = 97.7740°, Z = 4, V = 1589.6(2) A^3, Dc = 1.451 g/cm^3, μ(MoKα) = 0.956 mm^-1, F(000) = 720, the final R = 0.0343 and wR = 0.0973 for 2759 observed reflections (I 〉 2σ(I)). Electrochemical measurements exhibit that compound 1 undergoes a reversible one-electron redox process.展开更多
基金supported by the Chemistry College of Jilin Normal University
文摘A novel Schiff-base compound based on ferrocene C18H17OFeN3 (1) has been synthesized and characterized by X-ray diffraction. The title compound crystallizes in monoclinic, space group P21/c with a = 19.2343(17), b = 10.5084(9), c = 7.9373(7) A, β = 97.7740°, Z = 4, V = 1589.6(2) A^3, Dc = 1.451 g/cm^3, μ(MoKα) = 0.956 mm^-1, F(000) = 720, the final R = 0.0343 and wR = 0.0973 for 2759 observed reflections (I 〉 2σ(I)). Electrochemical measurements exhibit that compound 1 undergoes a reversible one-electron redox process.