PrCo5 nanoflakes with strong texture and high coercivity of 8.15 kOe were prepared by surfactant-assisted ball milling with heat-treated starting powder. The thickness and length of the as-milled nanoflakes are mainly...PrCo5 nanoflakes with strong texture and high coercivity of 8.15 kOe were prepared by surfactant-assisted ball milling with heat-treated starting powder. The thickness and length of the as-milled nanoflakes are mainly in the ranges of 50–100 nm and 0.5–3 μm, respectively. The x-ray diffraction patterns demonstrate that the heat treatment can increase the single phase and crystallinity of the PrCo5 compound, and combined with the demagnetization curves, indicate that the single phase and crystallinity are important for preparing high-coercivity and strong-textured rare earth permanent magnetic nanoflakes. In addition, the coercivity mechanism of the as-milled PrCo5 nanoflakes is studied by the angle dependence of coercivity for an aligned sample and the field dependence of coercivity, isothermal(IRM) and dc demagnetizing(DCD)remanence curves for an unaligned sample. The results indicate that the coercivity is dominated by co-existing mechanisms of pinning and nucleation. Furthermore, exchange coupling and dipolar coupling also co-exist in the sample.展开更多
A series of CeMn2(Si1-xGex)2(x = 0.2, 0.4, 0.6, 0.8) compounds are prepared by the arc-melting method. All the samples primarily crystallize in the Th Cr2Si2-type structure. The temperature dependences of zero-fie...A series of CeMn2(Si1-xGex)2(x = 0.2, 0.4, 0.6, 0.8) compounds are prepared by the arc-melting method. All the samples primarily crystallize in the Th Cr2Si2-type structure. The temperature dependences of zero-field-cooled(ZFC) and FC magnetization measurements show a transition from antiferromagnetic(AFM) state to ferromagnetic(FM) state at room temperature with the increase of the Ge concentration. For x = 0.4, the sample exhibits two kinds of phase transitions with increasing temperature: from AFM to FM and from FM to paramagnetic(PM) at around TN-197 K and T C-300 K,respectively. The corresponding Arrott curves indicate that the AFM–FM transition is of first-order character and the FM–PM transition is of second-order character. Meanwhile, the coexistence of positive and negative magnetic entropy changes can be observed, which are corresponding to the AFM–FM and FM–PM transitions, respectively.展开更多
To explore the mechanism of carbonyl iron flake composites for microwave complex permeability, this paper investigates the feature of the flakes. The shape anisotropy was certified by the results of the magnetization ...To explore the mechanism of carbonyl iron flake composites for microwave complex permeability, this paper investigates the feature of the flakes. The shape anisotropy was certified by the results of the magnetization hysteresis loops and the Mossbauer spectra. Furthermore, the shape anisotropy was used to explain the origin of composite microwave performance, and the calculated results agree with the experiment. It is believed that the shape anisotropy dominates microwave complex permeability, and the natural resonance plays main role in flake.展开更多
MM14Fe79.9B6.1/Nd13.5Fe80.5B6 magnets were fabricated by dual alloy method(MM, misch metal). Some magnets have two Curie temperatures. Curie temperatures Tc1corresponds to the main phase which contains more La Ce, a...MM14Fe79.9B6.1/Nd13.5Fe80.5B6 magnets were fabricated by dual alloy method(MM, misch metal). Some magnets have two Curie temperatures. Curie temperatures Tc1corresponds to the main phase which contains more La Ce, and Tc1 decreases from 276.5℃ to 256.6℃ with the content of MM increasing from 30.3 at.% to 50.6 at.%. The variation of Br with the increase of MM indicates the existence of inter-grain exchange coupling in the magnets. When MM/R ≤ 30.3 at.%,the magnetic properties can reach the level of the intrinsic coercivity Hcj≥ 7.11 kOe and the maximum energy product(BH)max≥ 41 MGOe. Compared with Nd, La and Ce are easier to diffuse to the grain boundaries in the sintering process,and this will cause the decrease of H(cj) Due to the diffusion between the grains, the atomic ratio of La, Ce, Pr, and Nd in each grain is different and the percentage of Nd in all grains is higher than that in misch metal.展开更多
The misch-metal (MM) partially substituted Nd-Fe-B sintered magnets were fabricated by the dual alloy method, and the crystal structure, microstructure, and magnetic properties were analyzed comprehensively. X-ray d...The misch-metal (MM) partially substituted Nd-Fe-B sintered magnets were fabricated by the dual alloy method, and the crystal structure, microstructure, and magnetic properties were analyzed comprehensively. X-ray diffraction (XRD) reveals that the increasing content of the MM has an inconsiderable effect on the crystallographic alignment of the magnets. Grains of the two main phases are uniformly distributed, and slightly deteriorate on the grain boundary. Due to the diffusion between the adjacent grains, the MM substituted Nd-Fe-B magnets contain three types of components with different Ce/La concentrations. Moreover, the first-order reversal curve (FORC) diagram is introduced to analyze the magnetization reversal process, coercivity mechanism, and distribution of reversal field in magnetic samples. The analysis indicates that there are two major reversal components, corresponding to the two different main phases. The domain nucleation and growth are determined to be the leading mechanism in controlling the magnetization reversal processes of the magnets sintered by the dual alloy method.展开更多
Microwave magnetic properties are studied for rhombohedral structure Nd2Fe17N3-δ with planar magnetic anisotropy. Its resin composites show the permeability μ'0 = 4.15 at low frequency, the natural resonance freque...Microwave magnetic properties are studied for rhombohedral structure Nd2Fe17N3-δ with planar magnetic anisotropy. Its resin composites show the permeability μ'0 = 4.15 at low frequency, the natural resonance frequency fT = 1.71 GHz and the resonance bandwidth 6.66 GHz. The calculated static permeability of Nd2Fe17N3-δ reaches 133. The microwave magnetic properties are determined by the c-axis anisotropy field, basal plane anisotropy field and high saturation magnetization. Based on microwave measurement and theoretical fitting on complex permeability spectra, Nd2Fe17N3-δ may be a promising microwave absorber with bandwidth wider than traditional hexaferrites materials in GHz ranges.展开更多
基金Project supported by the National Basic Research Program of China(Grant No.2014CB643702)the National Natural Science Foundation of China(Grant No.51401235)Beijing Natural Science Foundation,China(Grant No.2152034)
文摘PrCo5 nanoflakes with strong texture and high coercivity of 8.15 kOe were prepared by surfactant-assisted ball milling with heat-treated starting powder. The thickness and length of the as-milled nanoflakes are mainly in the ranges of 50–100 nm and 0.5–3 μm, respectively. The x-ray diffraction patterns demonstrate that the heat treatment can increase the single phase and crystallinity of the PrCo5 compound, and combined with the demagnetization curves, indicate that the single phase and crystallinity are important for preparing high-coercivity and strong-textured rare earth permanent magnetic nanoflakes. In addition, the coercivity mechanism of the as-milled PrCo5 nanoflakes is studied by the angle dependence of coercivity for an aligned sample and the field dependence of coercivity, isothermal(IRM) and dc demagnetizing(DCD)remanence curves for an unaligned sample. The results indicate that the coercivity is dominated by co-existing mechanisms of pinning and nucleation. Furthermore, exchange coupling and dipolar coupling also co-exist in the sample.
基金Project supported by the Beijing Natural Science Foundation,China(Grant No.2152034)the National Natural Science Foundation of China(Grant Nos.11274357 and 51271196)
文摘A series of CeMn2(Si1-xGex)2(x = 0.2, 0.4, 0.6, 0.8) compounds are prepared by the arc-melting method. All the samples primarily crystallize in the Th Cr2Si2-type structure. The temperature dependences of zero-field-cooled(ZFC) and FC magnetization measurements show a transition from antiferromagnetic(AFM) state to ferromagnetic(FM) state at room temperature with the increase of the Ge concentration. For x = 0.4, the sample exhibits two kinds of phase transitions with increasing temperature: from AFM to FM and from FM to paramagnetic(PM) at around TN-197 K and T C-300 K,respectively. The corresponding Arrott curves indicate that the AFM–FM transition is of first-order character and the FM–PM transition is of second-order character. Meanwhile, the coexistence of positive and negative magnetic entropy changes can be observed, which are corresponding to the AFM–FM and FM–PM transitions, respectively.
基金Project supported by the National Natural Science Foundation of China (Grant Nos 90505007 and 10774061)
文摘To explore the mechanism of carbonyl iron flake composites for microwave complex permeability, this paper investigates the feature of the flakes. The shape anisotropy was certified by the results of the magnetization hysteresis loops and the Mossbauer spectra. Furthermore, the shape anisotropy was used to explain the origin of composite microwave performance, and the calculated results agree with the experiment. It is believed that the shape anisotropy dominates microwave complex permeability, and the natural resonance plays main role in flake.
基金Project supported by the National Key Research and Development Program of China(Grant Nos.2014CB643702 and 2016YFB0700903)the National Natural Science Foundation of China(Grant No.51590880)the Knowledge Innovation Project of the Chinese Academy of Sciences(Grant No.KJZD-EW-M05)
文摘MM14Fe79.9B6.1/Nd13.5Fe80.5B6 magnets were fabricated by dual alloy method(MM, misch metal). Some magnets have two Curie temperatures. Curie temperatures Tc1corresponds to the main phase which contains more La Ce, and Tc1 decreases from 276.5℃ to 256.6℃ with the content of MM increasing from 30.3 at.% to 50.6 at.%. The variation of Br with the increase of MM indicates the existence of inter-grain exchange coupling in the magnets. When MM/R ≤ 30.3 at.%,the magnetic properties can reach the level of the intrinsic coercivity Hcj≥ 7.11 kOe and the maximum energy product(BH)max≥ 41 MGOe. Compared with Nd, La and Ce are easier to diffuse to the grain boundaries in the sintering process,and this will cause the decrease of H(cj) Due to the diffusion between the grains, the atomic ratio of La, Ce, Pr, and Nd in each grain is different and the percentage of Nd in all grains is higher than that in misch metal.
基金Project supported by the National Natural Science Foundation of China(Grant No.51590880)the National Key Research and Development Program of China(Grant Nos.2014CB643702 and 2016YFB0700903)+1 种基金Key Research Program of the Chinese Academy of Sciences of Chinathe Inner Mongolia Science and Technology Major Project of China 2016
文摘The misch-metal (MM) partially substituted Nd-Fe-B sintered magnets were fabricated by the dual alloy method, and the crystal structure, microstructure, and magnetic properties were analyzed comprehensively. X-ray diffraction (XRD) reveals that the increasing content of the MM has an inconsiderable effect on the crystallographic alignment of the magnets. Grains of the two main phases are uniformly distributed, and slightly deteriorate on the grain boundary. Due to the diffusion between the adjacent grains, the MM substituted Nd-Fe-B magnets contain three types of components with different Ce/La concentrations. Moreover, the first-order reversal curve (FORC) diagram is introduced to analyze the magnetization reversal process, coercivity mechanism, and distribution of reversal field in magnetic samples. The analysis indicates that there are two major reversal components, corresponding to the two different main phases. The domain nucleation and growth are determined to be the leading mechanism in controlling the magnetization reversal processes of the magnets sintered by the dual alloy method.
基金Supported by the National Natural Science Foundation of China under Grant Nos 90505007 and 10774061.
文摘Microwave magnetic properties are studied for rhombohedral structure Nd2Fe17N3-δ with planar magnetic anisotropy. Its resin composites show the permeability μ'0 = 4.15 at low frequency, the natural resonance frequency fT = 1.71 GHz and the resonance bandwidth 6.66 GHz. The calculated static permeability of Nd2Fe17N3-δ reaches 133. The microwave magnetic properties are determined by the c-axis anisotropy field, basal plane anisotropy field and high saturation magnetization. Based on microwave measurement and theoretical fitting on complex permeability spectra, Nd2Fe17N3-δ may be a promising microwave absorber with bandwidth wider than traditional hexaferrites materials in GHz ranges.