This paper adopts a medium pressure mercury lamp as light source and ZnO powder as catalyst to investigate the effect of radioactive wave length, component of phenol ZnO suspension and st...This paper adopts a medium pressure mercury lamp as light source and ZnO powder as catalyst to investigate the effect of radioactive wave length, component of phenol ZnO suspension and stirring method on phenol decomposition rate. The optimized conditions for the phenol decomposition are: (1) Radioactive wave length: 360~420 nm; (2)Phenol concentration in the suspension is less than 200 mg/l; (3)ZnO concentration is 3~8 g/l; (4)pH value is 5~7; (5)Reaction temperature is 25℃~40℃; (6)Agitation at atmosphere. Phenol can decompose in two ways: (1)Reacting with photogenerated cavity; (2)Reacting with ·OH radical.展开更多
文摘This paper adopts a medium pressure mercury lamp as light source and ZnO powder as catalyst to investigate the effect of radioactive wave length, component of phenol ZnO suspension and stirring method on phenol decomposition rate. The optimized conditions for the phenol decomposition are: (1) Radioactive wave length: 360~420 nm; (2)Phenol concentration in the suspension is less than 200 mg/l; (3)ZnO concentration is 3~8 g/l; (4)pH value is 5~7; (5)Reaction temperature is 25℃~40℃; (6)Agitation at atmosphere. Phenol can decompose in two ways: (1)Reacting with photogenerated cavity; (2)Reacting with ·OH radical.