Influences of polymer-based grinding aid(PGA) on the damage process of concrete exposed to sulfate attack under dry-wet cycles were investigated. The mass loss, dynamic modulus of elasticity(Erd), and S and Ca ele...Influences of polymer-based grinding aid(PGA) on the damage process of concrete exposed to sulfate attack under dry-wet cycles were investigated. The mass loss, dynamic modulus of elasticity(Erd), and S and Ca element contents of concrete specimens were measured. Scanning electron microscopy(SEM), mercury intrusion porosimetry(MIP), and X-ray diffractometry(XRD) were used to investigate the changing of microstructure of interior concrete. The results indicated that PGA was capable of reducing the mass loss and improving the sulfate attack resistance of concrete. X-ray fluorescence(XRF) analysis revealed that PGA delayed the transport process of sulfate ions and Ca ions. In addition, MIP analysis disclosed that the micropores of concrete with PGA increased in the fraction of 20-100 nm and decreased in the residues of 200 nm. Compared with the blank sample, concrete with PGA had more slender and well-organized hydration products, and no changes in hydration products ratio or type were observed.展开更多
基金Funded by National Natural Science Foundation of China(No.51578141)National Program on Key Basic Research Project(973 Program)(No.2015CB655102)Ministry of Science and Technology of China(No.2016YFE011820)
文摘Influences of polymer-based grinding aid(PGA) on the damage process of concrete exposed to sulfate attack under dry-wet cycles were investigated. The mass loss, dynamic modulus of elasticity(Erd), and S and Ca element contents of concrete specimens were measured. Scanning electron microscopy(SEM), mercury intrusion porosimetry(MIP), and X-ray diffractometry(XRD) were used to investigate the changing of microstructure of interior concrete. The results indicated that PGA was capable of reducing the mass loss and improving the sulfate attack resistance of concrete. X-ray fluorescence(XRF) analysis revealed that PGA delayed the transport process of sulfate ions and Ca ions. In addition, MIP analysis disclosed that the micropores of concrete with PGA increased in the fraction of 20-100 nm and decreased in the residues of 200 nm. Compared with the blank sample, concrete with PGA had more slender and well-organized hydration products, and no changes in hydration products ratio or type were observed.