A Bench top Quadrupole Mass Spectrometer System for Accurate Analysis of Trace Noble Gas was introduced in this paper. The inlet system was a especially designed one. And a capacitance pressure gauge with its linearit...A Bench top Quadrupole Mass Spectrometer System for Accurate Analysis of Trace Noble Gas was introduced in this paper. The inlet system was a especially designed one. And a capacitance pressure gauge with its linearity less than 0.01% was used to measure the fixed volume sample ratio. By using the calibration gas with the uncertainty of which less than 0.1% ,isotope condensed diluent could be quantified online. The procedure is done by alternate online mixture gas measurement of diluent gas, calibration gas to quantify the diluent gas, and diluent gas, sample gas to quantify the sample gas. The precision of six inlet from the same sample is +_0.13%0; The precision of six getting sample from the same source is less than ±0.5%. Self test was done by testing the mixture gas got with weighing method, in which consists Kr and Xe of 30 mg/kg. The system uncertainty tested to be below ±1%.展开更多
A scheme of hemispherical hot cavity solid ion source with electron impact is brought up. Sample evaporation and ionization is accomplished in the quasi-tight hemispherical cavity. The two axial designed holes are use...A scheme of hemispherical hot cavity solid ion source with electron impact is brought up. Sample evaporation and ionization is accomplished in the quasi-tight hemispherical cavity. The two axial designed holes are used to lead electrons into the cavity and to draw ions out of it. The area of two holes takes up only 1/150 of whole cavity's surface area. Sample atoms after evaporation will go through many times of sticking, desorption, release and finally diffuse out of the cavity and be partly ionized. The flying direction of atoms and ions in cavity points to the cavity center. Electrons from ring cathode are focused into the cavity by electrostatic field without magnet. The hemispherical cavity was heated by axis current which forms a centripetal field to drift ions in cavity. In the area close to the cavity center, ions will be drawn out and focused to a point. The atom's ionization efficiency, the ion's extracting performance, the fractionation and chemistry selectivity, and the applicable scope about this ion source are discussed.展开更多
Technique of lutetium isotopic analysis by laser resonance ionization mass spectrometry(LRIMS) was developed in the presence of isobaric interference. In the case of real sample, the elemental selectivity was better t...Technique of lutetium isotopic analysis by laser resonance ionization mass spectrometry(LRIMS) was developed in the presence of isobaric interference. In the case of real sample, the elemental selectivity was better than 8×105, and the detection efficiency was 8.3×10-5. The technique of wavelength scanning method was set up in order that the accurate isotopic ratio could be determined. And the numerical computational method was provided to calculate the correct factor of isotopic ratio. Using this technique, the isotopic ratio measured by LRIMS is in good agreement with standard value measured by TIMS.展开更多
The brief procedure of how to get a gas mixture of low concentration and high accuracy with the double balance weighing method was described. This method requires two balances of both different ranges and high resolut...The brief procedure of how to get a gas mixture of low concentration and high accuracy with the double balance weighing method was described. This method requires two balances of both different ranges and high resolutions, also tow sets of equipment for introducing Ar, Ne, Kr, Xe, and the Nitrogen for balance gas. Two sets of equipment were fulfilled according to the described procedure without any backflow of the component gases. The residual gas in the filling equipment was analyzed to correct the mass of the component gases filled into the mixture gas. By this way, the concentration of Kr and Xe in the preparing mixture gas, is about 0.1%, with the maximum uncertainty of about 0.1%.展开更多
This paper presents The investigation of laser resonance ionization mass spectroscopy of lutetium with our laser ionization mass spectrometry system manufactured by our own. The optimum radius of laser focal spot over...This paper presents The investigation of laser resonance ionization mass spectroscopy of lutetium with our laser ionization mass spectrometry system manufactured by our own. The optimum radius of laser focal spot overlapped with atomic beam is calculated theoretical.Lutetium ionic signal at The rate of 1.8 ×105 s- 1is detected The Sample she of 1 μg lutetium.. With laser resonance ionization and The of atomizer,it is possible that The detection ho reaches 106 atoms. The effect of laser-induce isotopic discrimination on The measurement of isotope ratio is discussed. It is proposed that laser bandwidth and wavelength tuning effects are The main factors of deviation of lutetium isotopic ratios with this broad bandwidth laser.展开更多
文摘A Bench top Quadrupole Mass Spectrometer System for Accurate Analysis of Trace Noble Gas was introduced in this paper. The inlet system was a especially designed one. And a capacitance pressure gauge with its linearity less than 0.01% was used to measure the fixed volume sample ratio. By using the calibration gas with the uncertainty of which less than 0.1% ,isotope condensed diluent could be quantified online. The procedure is done by alternate online mixture gas measurement of diluent gas, calibration gas to quantify the diluent gas, and diluent gas, sample gas to quantify the sample gas. The precision of six inlet from the same sample is +_0.13%0; The precision of six getting sample from the same source is less than ±0.5%. Self test was done by testing the mixture gas got with weighing method, in which consists Kr and Xe of 30 mg/kg. The system uncertainty tested to be below ±1%.
文摘A scheme of hemispherical hot cavity solid ion source with electron impact is brought up. Sample evaporation and ionization is accomplished in the quasi-tight hemispherical cavity. The two axial designed holes are used to lead electrons into the cavity and to draw ions out of it. The area of two holes takes up only 1/150 of whole cavity's surface area. Sample atoms after evaporation will go through many times of sticking, desorption, release and finally diffuse out of the cavity and be partly ionized. The flying direction of atoms and ions in cavity points to the cavity center. Electrons from ring cathode are focused into the cavity by electrostatic field without magnet. The hemispherical cavity was heated by axis current which forms a centripetal field to drift ions in cavity. In the area close to the cavity center, ions will be drawn out and focused to a point. The atom's ionization efficiency, the ion's extracting performance, the fractionation and chemistry selectivity, and the applicable scope about this ion source are discussed.
文摘Technique of lutetium isotopic analysis by laser resonance ionization mass spectrometry(LRIMS) was developed in the presence of isobaric interference. In the case of real sample, the elemental selectivity was better than 8×105, and the detection efficiency was 8.3×10-5. The technique of wavelength scanning method was set up in order that the accurate isotopic ratio could be determined. And the numerical computational method was provided to calculate the correct factor of isotopic ratio. Using this technique, the isotopic ratio measured by LRIMS is in good agreement with standard value measured by TIMS.
文摘The brief procedure of how to get a gas mixture of low concentration and high accuracy with the double balance weighing method was described. This method requires two balances of both different ranges and high resolutions, also tow sets of equipment for introducing Ar, Ne, Kr, Xe, and the Nitrogen for balance gas. Two sets of equipment were fulfilled according to the described procedure without any backflow of the component gases. The residual gas in the filling equipment was analyzed to correct the mass of the component gases filled into the mixture gas. By this way, the concentration of Kr and Xe in the preparing mixture gas, is about 0.1%, with the maximum uncertainty of about 0.1%.
文摘This paper presents The investigation of laser resonance ionization mass spectroscopy of lutetium with our laser ionization mass spectrometry system manufactured by our own. The optimum radius of laser focal spot overlapped with atomic beam is calculated theoretical.Lutetium ionic signal at The rate of 1.8 ×105 s- 1is detected The Sample she of 1 μg lutetium.. With laser resonance ionization and The of atomizer,it is possible that The detection ho reaches 106 atoms. The effect of laser-induce isotopic discrimination on The measurement of isotope ratio is discussed. It is proposed that laser bandwidth and wavelength tuning effects are The main factors of deviation of lutetium isotopic ratios with this broad bandwidth laser.
