The effects of metal core dimension, oxide shell thickness and ellipsoid aspect ratio of Al-Al2O3 core-shell nanoparticles on the near-infrared and visible absorption spectra of nanocomposite Al-Al2O3/nitrocellulose...The effects of metal core dimension, oxide shell thickness and ellipsoid aspect ratio of Al-Al2O3 core-shell nanoparticles on the near-infrared and visible absorption spectra of nanocomposite Al-Al2O3/nitrocellulose（NC） film are investigated by numerical calculations. Both the size-dependent interband transitions and frequency-dependent free electron damping of the nanometallic aluminium are taken into account in the calculations. Oxidation effect of nanoaluminium is also analysed. It is shown that oxidation may enhance but may also reduce the optical absorption, depending on the excited light energy and initial dimension of nanoparticle. Metal core size and excited light energy dominate the absorption characteristic. The absorption ability of ellipsoidal nanoparticles is larger than that of spheroidal nanoparticles and increases by the square index as the aspect ratio increases. These calculations will provide some significant theoretical guidance for the preparation and laser ignition of nanoenergetic materials.展开更多
This paper demonstrates the femtosecond time-resolved coherent anti-Stokes Raman scattering by using folded BOXCARS geometry where an ultrashort broadband coherent white light continuum was used as Stokes pulse, and c...This paper demonstrates the femtosecond time-resolved coherent anti-Stokes Raman scattering by using folded BOXCARS geometry where an ultrashort broadband coherent white light continuum was used as Stokes pulse, and carries out the non-contact detection at long distance, The CARS signal is so easy to be detected that it can be seen even by nude eye. The C-H bonds of chloroform or PMMA were detected and the vibration modes belonging to the side chain and the main chain in PMMA were also compared. Their vibrational characteristics involved decay process and quantum beating were discussed. This modified CARS experimental technique could make up the deficiency of traditional CARS technique.展开更多
Heat current exchanged between a two-level quantum dot(QD) and a phonon reservoir coupled to it is studied within the nonequilibrium Green's function method. We consider that the QD is connected to the left and ri...Heat current exchanged between a two-level quantum dot(QD) and a phonon reservoir coupled to it is studied within the nonequilibrium Green's function method. We consider that the QD is connected to the left and right ferromagnetic leads. It is found that the negative differential of the heat generation(NDHG) phenomenon,i.e.,the intensity of the heat generation decreases with increasing bias voltage,is obviously enhanced as compared to that in single-level QD system. The NDHG can emerge in the absence of the negative differential conductance of the electric current,and occurs in different bias voltage regions when the magnetic moments of the two leads are arranged in parallel or antiparallel configurations. The characteristics of the found phenomena can be understood by examining the change of the electron number on the dot.展开更多
基金supported by the National Natural Science Foundation of China (Grant No 20573028)
文摘The effects of metal core dimension, oxide shell thickness and ellipsoid aspect ratio of Al-Al2O3 core-shell nanoparticles on the near-infrared and visible absorption spectra of nanocomposite Al-Al2O3/nitrocellulose（NC） film are investigated by numerical calculations. Both the size-dependent interband transitions and frequency-dependent free electron damping of the nanometallic aluminium are taken into account in the calculations. Oxidation effect of nanoaluminium is also analysed. It is shown that oxidation may enhance but may also reduce the optical absorption, depending on the excited light energy and initial dimension of nanoparticle. Metal core size and excited light energy dominate the absorption characteristic. The absorption ability of ellipsoidal nanoparticles is larger than that of spheroidal nanoparticles and increases by the square index as the aspect ratio increases. These calculations will provide some significant theoretical guidance for the preparation and laser ignition of nanoenergetic materials.
基金Project supported by the National Natural Science Foundation of China (Grant Nos 60478015 and 20573028)
文摘This paper demonstrates the femtosecond time-resolved coherent anti-Stokes Raman scattering by using folded BOXCARS geometry where an ultrashort broadband coherent white light continuum was used as Stokes pulse, and carries out the non-contact detection at long distance, The CARS signal is so easy to be detected that it can be seen even by nude eye. The C-H bonds of chloroform or PMMA were detected and the vibration modes belonging to the side chain and the main chain in PMMA were also compared. Their vibrational characteristics involved decay process and quantum beating were discussed. This modified CARS experimental technique could make up the deficiency of traditional CARS technique.
基金Supported by the National Natural Science Foundation of China under Grant No.61274101the Liaoning Excellent Talents Programand(LJQ2013118)the Foundation of State Key Laboratory of Explosion Science and Technology of Beijing Institute of Technology(KFJJ14-08M)
文摘Heat current exchanged between a two-level quantum dot(QD) and a phonon reservoir coupled to it is studied within the nonequilibrium Green's function method. We consider that the QD is connected to the left and right ferromagnetic leads. It is found that the negative differential of the heat generation(NDHG) phenomenon,i.e.,the intensity of the heat generation decreases with increasing bias voltage,is obviously enhanced as compared to that in single-level QD system. The NDHG can emerge in the absence of the negative differential conductance of the electric current,and occurs in different bias voltage regions when the magnetic moments of the two leads are arranged in parallel or antiparallel configurations. The characteristics of the found phenomena can be understood by examining the change of the electron number on the dot.
