We have set up the high pressure device used for single crystal X-ray diffraction, determined the X-ray absorption curve of the device on Nicolet four-circle diffractometer, established the data collection programme o...We have set up the high pressure device used for single crystal X-ray diffraction, determined the X-ray absorption curve of the device on Nicolet four-circle diffractometer, established the data collection programme of a fixed φ scheme, and corrected the offsets of the optical centering of the crystal by using a reflection which is measured in eight different orientations. The mixture ratio of methanol: ethanol: water 16: 3: 1 was used as a pressure medium, high pressure calibration was based on the wavelength shift of the R_1 fluorescence line of ruby, and the pressure of 100 kbar was obtained.展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘We have set up the high pressure device used for single crystal X-ray diffraction, determined the X-ray absorption curve of the device on Nicolet four-circle diffractometer, established the data collection programme of a fixed φ scheme, and corrected the offsets of the optical centering of the crystal by using a reflection which is measured in eight different orientations. The mixture ratio of methanol: ethanol: water 16: 3: 1 was used as a pressure medium, high pressure calibration was based on the wavelength shift of the R_1 fluorescence line of ruby, and the pressure of 100 kbar was obtained.
