研究了酸解法从豆腐柴叶中提取果胶的动力学过程,建立了受溶解果胶分子降解影响的果胶提取动力学模型,并用数学方法确定了最大的得率和最佳的提取时间。模型可应用于描述在实验室条件下,60、70、80和90℃时用盐酸从豆腐柴叶中提取果胶...研究了酸解法从豆腐柴叶中提取果胶的动力学过程,建立了受溶解果胶分子降解影响的果胶提取动力学模型,并用数学方法确定了最大的得率和最佳的提取时间。模型可应用于描述在实验室条件下,60、70、80和90℃时用盐酸从豆腐柴叶中提取果胶的酸提取过程,确立了提取过程的速率常数,从60℃下的3.01×10-4s-1变化到90℃下的8.64×10-4s-1,应用该模型对豆腐柴叶果胶的提取得率进行了理论计算,获得了90℃下最佳提取时间(50.19 m in)时的最大得率(8.007%),模型计算结果与实验数据吻合较好。所提出的理论模型能充分描述在酸性条件下的果胶提取过程和预测果胶的最大得率、果胶降解量和最佳的提取时间。展开更多
A novel carbonyl transposition reaction led by aromatic amines nucleophilic addition to \{2 oxo glycoside\} was discovered. The mechanism of the reaction was provided through tracing the change of 1H NMR of a hemiacet...A novel carbonyl transposition reaction led by aromatic amines nucleophilic addition to \{2 oxo glycoside\} was discovered. The mechanism of the reaction was provided through tracing the change of 1H NMR of a hemiacetal intermediate which was obtained in the reaction of o phenylene diamine with 2 oxo glycoside. Both the intermediate and the product were identified by FTIR, 1H NMR, 13 C NMR, 1H 1H COSY and 1H 13 C COSY spectra. The other aromatic amines reaction with 2 oxo glycoside also proved the mechanism. This reaction provides a new method for preparing 2 deoxy 2 aromatic amino 3 oxo glycosides, which is a new kind of material used in assymetric synthesis.展开更多
文摘研究了酸解法从豆腐柴叶中提取果胶的动力学过程,建立了受溶解果胶分子降解影响的果胶提取动力学模型,并用数学方法确定了最大的得率和最佳的提取时间。模型可应用于描述在实验室条件下,60、70、80和90℃时用盐酸从豆腐柴叶中提取果胶的酸提取过程,确立了提取过程的速率常数,从60℃下的3.01×10-4s-1变化到90℃下的8.64×10-4s-1,应用该模型对豆腐柴叶果胶的提取得率进行了理论计算,获得了90℃下最佳提取时间(50.19 m in)时的最大得率(8.007%),模型计算结果与实验数据吻合较好。所提出的理论模型能充分描述在酸性条件下的果胶提取过程和预测果胶的最大得率、果胶降解量和最佳的提取时间。
文摘A novel carbonyl transposition reaction led by aromatic amines nucleophilic addition to \{2 oxo glycoside\} was discovered. The mechanism of the reaction was provided through tracing the change of 1H NMR of a hemiacetal intermediate which was obtained in the reaction of o phenylene diamine with 2 oxo glycoside. Both the intermediate and the product were identified by FTIR, 1H NMR, 13 C NMR, 1H 1H COSY and 1H 13 C COSY spectra. The other aromatic amines reaction with 2 oxo glycoside also proved the mechanism. This reaction provides a new method for preparing 2 deoxy 2 aromatic amino 3 oxo glycosides, which is a new kind of material used in assymetric synthesis.