在高强度X射线辐照下,X射线自由电子激光(X-ray Free-electron Laser,XFEL)装置的光学元件薄膜产生的大量辐照缺陷会导致材料结构损伤,引起宏观性能退化,从而影响其服役寿命,进而影响到XFEL装置的可靠性和稳定性。为了研究材料辐照缺陷...在高强度X射线辐照下,X射线自由电子激光(X-ray Free-electron Laser,XFEL)装置的光学元件薄膜产生的大量辐照缺陷会导致材料结构损伤,引起宏观性能退化,从而影响其服役寿命,进而影响到XFEL装置的可靠性和稳定性。为了研究材料辐照缺陷过程以及方便耐辐照材料的数据积累,提供了一种基于Python语言的自动化辐照模拟程序AISL(Automatic Irradiation Simulation based on LAMMPS),以支持采用分子动力学方法模拟XFEL对材料的辐照损伤进行微观研究。AISL实现了模拟任务的自动化工作流管道,包括高通量计算任务的管理和执行,计算数据的高可靠存储和热力学信息的后处理。基于AISL在XFEL光学元件金属薄膜辐照损伤模拟的应用实例研究,表明了AISL是一种便捷开展高通量自动化的辐照模拟研究的有效方法,能够显著提高基于LAMMPS的材料辐照损伤模拟计算效率。展开更多
Nb can improve the resistance of Ni-based Hastelloy N alloy to Te-induced intergranular embrittlement.First-principles calculations are performed to research this mechanism by simulating the Ni(111) surface and the 5(...Nb can improve the resistance of Ni-based Hastelloy N alloy to Te-induced intergranular embrittlement.First-principles calculations are performed to research this mechanism by simulating the Ni(111) surface and the 5(012) grain boundary. The calculated adsorption energy suggests that Te atoms prefer diffusing along the grain boundary to forming the surface-reaction layer with Nb on surface of the Ni alloy. First-principles tensile tests show that the Nb segregation can enhance the cohesion of grain boundary. The strong Nb-Ni bonding can prevent the Te migration into the inside of the alloy. According to the Rice-Wang model, the strengthening/embrittling energies of Nb and Te are calculated, along with their mechanical and chemical components.The chemical bonds and electronic structures are analyzed to uncover the physical origin of the different effects of Te and Nb. Our work sheds lights on the effect of Nb additive on the Te-induced intergranular embrittlement in Hastelloy N alloy on the atomic and electronic level.展开更多
In this paper,we present a theoretical study on excitonic absorption spectra of one-dimensional semiconductor quantum wires.The carrier-carrier scattering is treated by the second Bom approximation in the Markovian li...In this paper,we present a theoretical study on excitonic absorption spectra of one-dimensional semiconductor quantum wires.The carrier-carrier scattering is treated by the second Bom approximation in the Markovian limit.The absorption spectra of different carrier densities and temperatures are discussed.The excitonic absorption peak position and width show complicated dependence on carrier density and temperature,indicating the importance of carrier-carrier scattering.The behavior can be understood by the cooperative effects of exchange self-energy and Coulomb correlation due to carrier-carrier scattering.展开更多
The interactions of He with dissociated screw dislocations in face-centered-cubic (fcc) Ni are investigated by using molecular dynamics simulations based on an embedded-atom method model. The binding and formation e...The interactions of He with dissociated screw dislocations in face-centered-cubic (fcc) Ni are investigated by using molecular dynamics simulations based on an embedded-atom method model. The binding and formation energies of interstitial He in and near Shockley partial cores are calculated. The results show that interstitial He atoms at tetrahedral sites in the perfect fee lattice and atoms occupying sites one plane above or below one of the two Shockley partial cores exhibit the strongest binding energy. The attractive or repulsive nature of the interaction between interstitial He and the screw dislocation depends on the relative position of He to these strong binding sites. In addition, the effect of He on the dissociation of screw dislocations are investigated. It is found that Fie atoms homogeneously distributed in the glide plane can reduce the stacking fault width.展开更多
The first principles density-functional theoretical calculations of U adatom adsorption and diffusion on a planar graphene and quasi-one-dimensional graphene nanoribbons(GNRs) are performed. An energetic preference ...The first principles density-functional theoretical calculations of U adatom adsorption and diffusion on a planar graphene and quasi-one-dimensional graphene nanoribbons(GNRs) are performed. An energetic preference is found for U adatom diffusing to the hollow sites of both graphene and GNRs surface. A number of U distinctive diffusion paths either perpendicular or parallel to the ribbon growth direction are examined. The edge effects are evidenced by the calculated energy barriers of U adatom diffusion on armchair and zigzag nanoribbons surfaces. The calculation results indicate that the diffusion of U adatom from the inner site toward the edge site is a feasible process, particularly in zigzagGNR. It is viable to control the initial morphology of nuclear carbon material to retard the diffusion and concentration of nuclides.展开更多
Based on the first-principles method,we predict two new stable BN allotropes:C12-BN and O16-BN,which belong to cubic and orthorhombic crystal systems,respectively.It is confirmed that both the phases are thermally and...Based on the first-principles method,we predict two new stable BN allotropes:C12-BN and O16-BN,which belong to cubic and orthorhombic crystal systems,respectively.It is confirmed that both the phases are thermally and dynamically stable.The results of molecular dynamics simulations suggest that both the BN phases are highly stable even at high temperatures of 1000 K.In the case of mechanical properties,C12-BN has a bulk modulus of 359 GPa and a hardness of 43.4 GPa,making it a novel superhard material with potential technological and industrial applications.Electronic band calculations reveal that both C12-BN and O16-BN are insulators with direct band gaps of 3.02 e V and 3.54 e V,respectively.The XRD spectra of C12-BN and O16-BN are also simulated to provide more information for possible experimental observation.Our findings enrich the BN allotrope family and are expected to stimulate further experimental interest.展开更多
The stability of coiled carbon nanotubes under C ion irradiation is investigated by molecular dynamics simulations.The defect statistics shows that small curvature coiled carbon nanotubes have better radiation toleran...The stability of coiled carbon nanotubes under C ion irradiation is investigated by molecular dynamics simulations.The defect statistics shows that small curvature coiled carbon nanotubes have better radiation tolerance than normal straight carbon nanotubes.To understand the effect of the curvature on defect production,the threshold displacement energies for the upper and lower walls,as well as those for the side parts,are calculated.The results show that the lower wall has better radiation tolerance than the upper wall.For the upper wall,a small increase in the curvature of nanotube axis gives rise to an increase in the radiation tolerance and then a decrease with the curvature becomes larger.However,for the lower wall,as the curvature of the nanotube axis increases,the radiation tolerance increases as the bonds compressed slightly in our simulation.展开更多
We theoretically study the quantum confinement effects on the self-energies of electrons and holes in quasi-onedimensional semiconductor systems.It is found that the effective Coulomb interactions are enhanced with th...We theoretically study the quantum confinement effects on the self-energies of electrons and holes in quasi-onedimensional semiconductor systems.It is found that the effective Coulomb interactions are enhanced with the increase in lateral confinement and the decrease in confinement size.The single-particle self-energies of electrons and holes are calculated in dynamic plasmon pole approximation within the GW approximation,where G refers to Green’s function and W is the dynamically screened Coulomb interaction.The real and imaginary parts of the self-energies have a strong dependence on the effective Coulomb interactions.展开更多
Channeling phenomena of He,Ne,Ar and Kr ions at energy(200–5000 eV)in single-wall carbon nanotubes(SWCNTs)are investigated by molecular dynamics simulation with analytical potentials.The critical angles for the parti...Channeling phenomena of He,Ne,Ar and Kr ions at energy(200–5000 eV)in single-wall carbon nanotubes(SWCNTs)are investigated by molecular dynamics simulation with analytical potentials.The critical angles for the particles to be channeled in an SWCNT are analyzed.In the incident energy range of 200–5000 eV,it is found that the ion energy dependence of the critical angle obeys an improved Lindhard equation which is closely related to the ratio of nuclear charge number to atomic mass Z/M.The critical angle for different types of ions channeling in SWCNTs is determined by both the atomic nuclear charge and mass.展开更多
The clustering behavior of helium atoms in thorium dioxide has been investigated by first-principles calculations. The results show that He atoms tend to form a cluster around an octahedral interstitial site(OIS). A...The clustering behavior of helium atoms in thorium dioxide has been investigated by first-principles calculations. The results show that He atoms tend to form a cluster around an octahedral interstitial site(OIS). As the concentration of He atoms in ThO2 increases, the strain induced by the He atoms increases and the octahedral interstitial site is not large enough to accommodate a large cluster, such as a He hexamer. We considered three different Schottky defect(SD) configurations(SD1, SD2, and SD3). When He atoms are located in the SD sites, the strain induced by the He atoms is released and the incorporation and binding energies decrease. The He trimer is the most stable cluster in SD1. Large He clusters, such as a He hexamer, are also stable in the SDs.展开更多
The elastic properties and point defects of thorium monocarbide(ThC) have been studied by means of density functional theory based on the projector-augmented-wave method. The calculated electronic and elastic proper...The elastic properties and point defects of thorium monocarbide(ThC) have been studied by means of density functional theory based on the projector-augmented-wave method. The calculated electronic and elastic properties of ThC are in good agreement with experimental data and previous theoretical results. Five types of point defects have been considered in our study, including the vacancy defect, interstitial defect, antisite defect, schottky defect, and composition-conserving defect. Among these defects, the carbon vacancy defect has the lowest formation energy of 0.29 eV. The second most stable defect(0.49 eV) is one of composition-conserving defects in which one carbon is removed to another carbon site forming a C2 dimer. In addition, we also discuss several kinds of carbon interstitial defects, and predict that the carbon trimer configuration may be a transition state for a carbon dimer diffusion in Th C.展开更多
Propagation of a heat pulse in (10,0) zig-zag carbon nanotubes, modeled by the Brenner-H and Tersoff bondorder potentials, respectively, is investigated using a molecular dynamics simulation. The longitudinal acoust...Propagation of a heat pulse in (10,0) zig-zag carbon nanotubes, modeled by the Brenner-H and Tersoff bondorder potentials, respectively, is investigated using a molecular dynamics simulation. The longitudinal acoustic mode, twisting phonon mode, and second sound waves are observed in the simulation. The time variations of speed and intensity of the above three phonon modes are in good agreement with the previous works based on the Brenner-I potential. Higher speed and weaker peak intensity are observed in the simulation of the Tersoff potential. The inherent over-binding of radicals and the non-local effects in Tersoff's covalent-bonding formula may play an important role in the heat pulse propagating simulation.展开更多
文摘在高强度X射线辐照下,X射线自由电子激光(X-ray Free-electron Laser,XFEL)装置的光学元件薄膜产生的大量辐照缺陷会导致材料结构损伤,引起宏观性能退化,从而影响其服役寿命,进而影响到XFEL装置的可靠性和稳定性。为了研究材料辐照缺陷过程以及方便耐辐照材料的数据积累,提供了一种基于Python语言的自动化辐照模拟程序AISL(Automatic Irradiation Simulation based on LAMMPS),以支持采用分子动力学方法模拟XFEL对材料的辐照损伤进行微观研究。AISL实现了模拟任务的自动化工作流管道,包括高通量计算任务的管理和执行,计算数据的高可靠存储和热力学信息的后处理。基于AISL在XFEL光学元件金属薄膜辐照损伤模拟的应用实例研究,表明了AISL是一种便捷开展高通量自动化的辐照模拟研究的有效方法,能够显著提高基于LAMMPS的材料辐照损伤模拟计算效率。
基金Supported by Science and Technology Commission of Shanghai Municipality(No.11JC1414900)Project supported by the National Basic Research Program of China(No.2010CB934501)+2 种基金Thorium Molten Salts Reactor Fund(No.XDA02000000)the National Natural Science Foundation of China(No.11005148),the National Natural Science Foundation of China(No.51371188)the Special Presidential Foundation of the Chinese Academy of Science,China(No.29)
文摘Nb can improve the resistance of Ni-based Hastelloy N alloy to Te-induced intergranular embrittlement.First-principles calculations are performed to research this mechanism by simulating the Ni(111) surface and the 5(012) grain boundary. The calculated adsorption energy suggests that Te atoms prefer diffusing along the grain boundary to forming the surface-reaction layer with Nb on surface of the Ni alloy. First-principles tensile tests show that the Nb segregation can enhance the cohesion of grain boundary. The strong Nb-Ni bonding can prevent the Te migration into the inside of the alloy. According to the Rice-Wang model, the strengthening/embrittling energies of Nb and Te are calculated, along with their mechanical and chemical components.The chemical bonds and electronic structures are analyzed to uncover the physical origin of the different effects of Te and Nb. Our work sheds lights on the effect of Nb additive on the Te-induced intergranular embrittlement in Hastelloy N alloy on the atomic and electronic level.
基金Supported by the National Basic Research Program of China(No.2010CB934504)the National Natural Science Foundation of China(No.10874197)
文摘In this paper,we present a theoretical study on excitonic absorption spectra of one-dimensional semiconductor quantum wires.The carrier-carrier scattering is treated by the second Bom approximation in the Markovian limit.The absorption spectra of different carrier densities and temperatures are discussed.The excitonic absorption peak position and width show complicated dependence on carrier density and temperature,indicating the importance of carrier-carrier scattering.The behavior can be understood by the cooperative effects of exchange self-energy and Coulomb correlation due to carrier-carrier scattering.
基金Supported by the Program of International S&T Cooperation under Grant No 2014DFG60230the Strategically Leading Program of the Chinese Academy of Sciences under Grant No XDA02040100+1 种基金the Shanghai Municipal Science and Technology Commission under Grant No 13ZR1448000the National Natural Science Foundation of China under Grant No 11505266
文摘The interactions of He with dissociated screw dislocations in face-centered-cubic (fcc) Ni are investigated by using molecular dynamics simulations based on an embedded-atom method model. The binding and formation energies of interstitial He in and near Shockley partial cores are calculated. The results show that interstitial He atoms at tetrahedral sites in the perfect fee lattice and atoms occupying sites one plane above or below one of the two Shockley partial cores exhibit the strongest binding energy. The attractive or repulsive nature of the interaction between interstitial He and the screw dislocation depends on the relative position of He to these strong binding sites. In addition, the effect of He on the dissociation of screw dislocations are investigated. It is found that Fie atoms homogeneously distributed in the glide plane can reduce the stacking fault width.
基金supported by the International S&T Cooperation Program of China(Grant No.2014DFG60230)the National Natural Science Foundation of China(Grant Nos.91326105,21306220,and 21501189)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA02040104)
文摘The first principles density-functional theoretical calculations of U adatom adsorption and diffusion on a planar graphene and quasi-one-dimensional graphene nanoribbons(GNRs) are performed. An energetic preference is found for U adatom diffusing to the hollow sites of both graphene and GNRs surface. A number of U distinctive diffusion paths either perpendicular or parallel to the ribbon growth direction are examined. The edge effects are evidenced by the calculated energy barriers of U adatom diffusion on armchair and zigzag nanoribbons surfaces. The calculation results indicate that the diffusion of U adatom from the inner site toward the edge site is a feasible process, particularly in zigzagGNR. It is viable to control the initial morphology of nuclear carbon material to retard the diffusion and concentration of nuclides.
基金supported by PhD research startup foundation of Civil Aviation University of China(Grant No.2020KYQD94)。
文摘Based on the first-principles method,we predict two new stable BN allotropes:C12-BN and O16-BN,which belong to cubic and orthorhombic crystal systems,respectively.It is confirmed that both the phases are thermally and dynamically stable.The results of molecular dynamics simulations suggest that both the BN phases are highly stable even at high temperatures of 1000 K.In the case of mechanical properties,C12-BN has a bulk modulus of 359 GPa and a hardness of 43.4 GPa,making it a novel superhard material with potential technological and industrial applications.Electronic band calculations reveal that both C12-BN and O16-BN are insulators with direct band gaps of 3.02 e V and 3.54 e V,respectively.The XRD spectra of C12-BN and O16-BN are also simulated to provide more information for possible experimental observation.Our findings enrich the BN allotrope family and are expected to stimulate further experimental interest.
基金Supported by the National Basic Research Program of China under Grant No 2010CB934504Strategically Leading Program of the Chinese Academy of Sciences under Grant No XDA02040100+2 种基金the National Natural Science Foundation of China(11075196,11005142)the Shanghai Municipal Science and Technology Commission(11ZR1445200)CAS Hundred Talents Program.
文摘The stability of coiled carbon nanotubes under C ion irradiation is investigated by molecular dynamics simulations.The defect statistics shows that small curvature coiled carbon nanotubes have better radiation tolerance than normal straight carbon nanotubes.To understand the effect of the curvature on defect production,the threshold displacement energies for the upper and lower walls,as well as those for the side parts,are calculated.The results show that the lower wall has better radiation tolerance than the upper wall.For the upper wall,a small increase in the curvature of nanotube axis gives rise to an increase in the radiation tolerance and then a decrease with the curvature becomes larger.However,for the lower wall,as the curvature of the nanotube axis increases,the radiation tolerance increases as the bonds compressed slightly in our simulation.
基金Supported by the National Basic Research Program of China under Grant No 2010CB934504the National Natural Science Foundation of China under Grant No 10874197the CAS Hundred Talents Program.
文摘We theoretically study the quantum confinement effects on the self-energies of electrons and holes in quasi-onedimensional semiconductor systems.It is found that the effective Coulomb interactions are enhanced with the increase in lateral confinement and the decrease in confinement size.The single-particle self-energies of electrons and holes are calculated in dynamic plasmon pole approximation within the GW approximation,where G refers to Green’s function and W is the dynamically screened Coulomb interaction.The real and imaginary parts of the self-energies have a strong dependence on the effective Coulomb interactions.
基金by the Key Project of the Knowledge Innovation Program of Chinese Academy of Sciences(KJCX3-SYW-N10)the Hundred Talents Program of Chinese Academy of Sciences,the National Natural Science Foundation of China(10874197)+1 种基金the Scientific Research Starting Foundation of the Ministry of Human Resources and Social Security of China for Returned Overseas Chinese Scholarsthe Shanghai Municipal Science and Technology Commission(09ZR1438300,11ZR1445200).
文摘Channeling phenomena of He,Ne,Ar and Kr ions at energy(200–5000 eV)in single-wall carbon nanotubes(SWCNTs)are investigated by molecular dynamics simulation with analytical potentials.The critical angles for the particles to be channeled in an SWCNT are analyzed.In the incident energy range of 200–5000 eV,it is found that the ion energy dependence of the critical angle obeys an improved Lindhard equation which is closely related to the ratio of nuclear charge number to atomic mass Z/M.The critical angle for different types of ions channeling in SWCNTs is determined by both the atomic nuclear charge and mass.
基金Project supported by the Program of International S&T Cooperation,China(Grant No.2014DFG60230)the National Natural Science Foundation of China(Grant Nos.11605273,21571185,U1404111,11504089,21501189,and 21676291)+1 种基金the Shanghai Municipal Science and Technology Commission,China(Grant No.16ZR1443100)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA02040104)
文摘The clustering behavior of helium atoms in thorium dioxide has been investigated by first-principles calculations. The results show that He atoms tend to form a cluster around an octahedral interstitial site(OIS). As the concentration of He atoms in ThO2 increases, the strain induced by the He atoms increases and the octahedral interstitial site is not large enough to accommodate a large cluster, such as a He hexamer. We considered three different Schottky defect(SD) configurations(SD1, SD2, and SD3). When He atoms are located in the SD sites, the strain induced by the He atoms is released and the incorporation and binding energies decrease. The He trimer is the most stable cluster in SD1. Large He clusters, such as a He hexamer, are also stable in the SDs.
基金Project supported by the International S&T Cooperation Program of China(Grant No.2014DFG60230)the National Natural Science Foundation of China(Grant No.91326105)+1 种基金the National Basic Research Program of China(Grant No.2010CB934504)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA02040104)
文摘The elastic properties and point defects of thorium monocarbide(ThC) have been studied by means of density functional theory based on the projector-augmented-wave method. The calculated electronic and elastic properties of ThC are in good agreement with experimental data and previous theoretical results. Five types of point defects have been considered in our study, including the vacancy defect, interstitial defect, antisite defect, schottky defect, and composition-conserving defect. Among these defects, the carbon vacancy defect has the lowest formation energy of 0.29 eV. The second most stable defect(0.49 eV) is one of composition-conserving defects in which one carbon is removed to another carbon site forming a C2 dimer. In addition, we also discuss several kinds of carbon interstitial defects, and predict that the carbon trimer configuration may be a transition state for a carbon dimer diffusion in Th C.
文摘Propagation of a heat pulse in (10,0) zig-zag carbon nanotubes, modeled by the Brenner-H and Tersoff bondorder potentials, respectively, is investigated using a molecular dynamics simulation. The longitudinal acoustic mode, twisting phonon mode, and second sound waves are observed in the simulation. The time variations of speed and intensity of the above three phonon modes are in good agreement with the previous works based on the Brenner-I potential. Higher speed and weaker peak intensity are observed in the simulation of the Tersoff potential. The inherent over-binding of radicals and the non-local effects in Tersoff's covalent-bonding formula may play an important role in the heat pulse propagating simulation.