The title complex [Cd2（NO3）2（OCH3）2（TPOM）2]·8H2O （TPOM = tetrakis（4-pyri- dyloxymethylene） methane） has been synthesized and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray...The title complex [Cd2（NO3）2（OCH3）2（TPOM）2]·8H2O （TPOM = tetrakis（4-pyri- dyloxymethylene） methane） has been synthesized and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. It crystallizes in the orthorhombic crystal system Ccca with a = 17.125（2）, b = 40.751（3）, c = 24.938（2）A, β = 90.00°, V= 17403（3）A3 C26H27N5O8Cd, Mr = 649.93, Z= 16, F（000） = 5280, Dc = 0.992 mg/m3,μ（MoKa） = 0.538 mm-1, S = 1.080, the final R = 0.0533 and wR = 0.1449 for 6627 observed reflections （I 〉 2σ（I））. The crystal structure shows that each Cd atom is coordinated to four pyridyl nitrogen atoms from four TPOM ligands and each tetrahedral TPOM ligand links up four Cd atoms into a 2-fold interpenetrating 3D framework. The TG analysis shows that the framework of the title complex is stable up to 300 ℃.展开更多
基金Supported by the National Natural Science Foundation of China (20931004)
文摘The title complex [Cd2（NO3）2（OCH3）2（TPOM）2]·8H2O （TPOM = tetrakis（4-pyri- dyloxymethylene） methane） has been synthesized and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. It crystallizes in the orthorhombic crystal system Ccca with a = 17.125（2）, b = 40.751（3）, c = 24.938（2）A, β = 90.00°, V= 17403（3）A3 C26H27N5O8Cd, Mr = 649.93, Z= 16, F（000） = 5280, Dc = 0.992 mg/m3,μ（MoKa） = 0.538 mm-1, S = 1.080, the final R = 0.0533 and wR = 0.1449 for 6627 observed reflections （I 〉 2σ（I））. The crystal structure shows that each Cd atom is coordinated to four pyridyl nitrogen atoms from four TPOM ligands and each tetrahedral TPOM ligand links up four Cd atoms into a 2-fold interpenetrating 3D framework. The TG analysis shows that the framework of the title complex is stable up to 300 ℃.
