南京电子器件研究所基于MOCVD平台,在100 mm SiC半绝缘衬底上,提出恒压式气流吹扫和台阶式流场调控技术分别应用于生长AlN/GaN异质结界面和AlN势垒层,显著改善了AlN/GaN异质结界面不清晰、Al原子表面扩散长度偏低的外延难题,研制出高性...南京电子器件研究所基于MOCVD平台,在100 mm SiC半绝缘衬底上,提出恒压式气流吹扫和台阶式流场调控技术分别应用于生长AlN/GaN异质结界面和AlN势垒层,显著改善了AlN/GaN异质结界面不清晰、Al原子表面扩散长度偏低的外延难题,研制出高性能AlN/GaN HEMT外延材料。图1为AFM 5μm×5μm范围下的表面形貌,势垒层表面平整,原子台阶明显,RMS=0.3 nm,且无明显缺陷。展开更多
南京电子器件研究所基于国产半绝缘SiC衬底研制出了高质量152.4 mm (6英寸)GaN HEMT外延材料。采用高温成核层调制生长技术,有效降低了大尺寸GaN外延材料的位错密度和圆片翘曲度,并利用温流场调控技术,大幅提升了片内均匀性,突破了国产...南京电子器件研究所基于国产半绝缘SiC衬底研制出了高质量152.4 mm (6英寸)GaN HEMT外延材料。采用高温成核层调制生长技术,有效降低了大尺寸GaN外延材料的位错密度和圆片翘曲度,并利用温流场调控技术,大幅提升了片内均匀性,突破了国产半绝缘SiC衬底上高质量152.4 mm (6英寸)GaN HEMT外延材料制备关键技术。展开更多
CaN films with an AlxGa1-xN/AlyGa1-xN superlattice （SL） buffer layer are grown on Si（111） substrates by metal-organic chemical vapor deposition （MOCVD）. The structure and strain properties of the samples are stu...CaN films with an AlxGa1-xN/AlyGa1-xN superlattice （SL） buffer layer are grown on Si（111） substrates by metal-organic chemical vapor deposition （MOCVD）. The structure and strain properties of the samples are studied by optical microscopy, Raman spectroscopy, x-ray diffractometry and atomic force microscopy. The results show that the strain status and crystalline quality of the CaN layers are strongly dependent on the difference of the Al composition between AlxCa1-xN barriers and AlyCa1-yN wells in the SLs. With a large Al composition difference, the CaN film tends to generate cracks on the surface due to the severe relaxation of the SLs. Otherwise, when using a small Al composition difference, the crystalline quality of the CaN layer degrades due to the poor function of the SLs in filtering dislocations. Under an optimized condition that the Al composition difference equals 0.1, the crack-free and compressive strained CaN film with an improved crystalline quality is achieved. Therefore, the AlxGa1-xN/AlyGal-yN SL buffer layer is a promising buffer structure for growing thick CaN films on Si substrates without crack generation.展开更多
文摘南京电子器件研究所基于国产半绝缘SiC衬底研制出了高质量152.4 mm (6英寸)GaN HEMT外延材料。采用高温成核层调制生长技术,有效降低了大尺寸GaN外延材料的位错密度和圆片翘曲度,并利用温流场调控技术,大幅提升了片内均匀性,突破了国产半绝缘SiC衬底上高质量152.4 mm (6英寸)GaN HEMT外延材料制备关键技术。
基金Supported by the National Natural Science Foundation of China under Grant Nos 61076120 and 61106130the Natural Science Foundation and Scientific Support Plan of Jiangsu Province under Grant Nos BK2012516,BK20131072,and BE2012007
文摘CaN films with an AlxGa1-xN/AlyGa1-xN superlattice （SL） buffer layer are grown on Si（111） substrates by metal-organic chemical vapor deposition （MOCVD）. The structure and strain properties of the samples are studied by optical microscopy, Raman spectroscopy, x-ray diffractometry and atomic force microscopy. The results show that the strain status and crystalline quality of the CaN layers are strongly dependent on the difference of the Al composition between AlxCa1-xN barriers and AlyCa1-yN wells in the SLs. With a large Al composition difference, the CaN film tends to generate cracks on the surface due to the severe relaxation of the SLs. Otherwise, when using a small Al composition difference, the crystalline quality of the CaN layer degrades due to the poor function of the SLs in filtering dislocations. Under an optimized condition that the Al composition difference equals 0.1, the crack-free and compressive strained CaN film with an improved crystalline quality is achieved. Therefore, the AlxGa1-xN/AlyGal-yN SL buffer layer is a promising buffer structure for growing thick CaN films on Si substrates without crack generation.
