The complex [Cd（bbb）Cl2]·DMF·H2O, where bbb is 2-（2-（1H-benzo[d]imidazol-2-yl）benzyl）-1H-benzo[d]imidazole, was synthesized and characterized by X-ray single-crystal structure analyses. For the complex...The complex [Cd（bbb）Cl2]·DMF·H2O, where bbb is 2-（2-（1H-benzo[d]imidazol-2-yl）benzyl）-1H-benzo[d]imidazole, was synthesized and characterized by X-ray single-crystal structure analyses. For the complex： C24H25Cl2CdN5O2, Mr = 598.77, crystal system, triclinic, space group P1, a = 9.9878（12）, b = 10.0008（12）, c = 13.2217（15） , α = 80.674（2）, β = 72.158（2）, γ = 86.776（2）°, V = 1240.5（3） 3, Z = 2, Dc = 1.598 g/cm3, λ = 0.71073, μ（MoKα） = 1.127 mm–1, F（000） = 600, S = 1.04, R = 0.0905 and wR = 0.3088 for 4805 observed reflections with I 〉 2σ（I）. It is a neutral complex. The distorted tetrahedral geometry of cadmium ion is coordinated by two nitrogen atoms of ligand and two chloride ions. The complex emits blue green luminescence with emission peaks at 480 nm in DMF solution.展开更多
A complex [Cd2（tbb）C14]·4DMF·3H2O, where tbb is 1,2,3,4-tetra（1H-benzo[d]imi- dazol-2-yl）butane, was synthesized and characterized by X-ray single-crystal structure analyses. For this complex： C44H49Cd2...A complex [Cd2（tbb）C14]·4DMF·3H2O, where tbb is 1,2,3,4-tetra（1H-benzo[d]imi- dazol-2-yl）butane, was synthesized and characterized by X-ray single-crystal structure analyses. For this complex： C44H49Cd2C14N12OT, Mr= 1224.55, monoclinie system, space group C2/c, a = 29.563（3）, b = 14.2580（17）, c = 26.355（3） A,β = 97.036（2）°, V = 11025（2） A3, Z = 8, D,.= 1.475 g/cm3, 2 = 0.71073 A, IL（MoKa） = 1.021 mm-1, F（000） = 4936, S = 1.047, R = 0.0680 and wR = 0.1832 for 11812 observed reflections with I 〉 2σ（I）. It is a neutral dinuclear complex. One 1,2,3,4-tetra（1H-benzo[d]imidazol-2-yl）butane coordinates to two cadmium ions. Each cadmium ion is coordinated by two nitrogen atoms of tbb and two chloride ions. The complex emits blue luminescence in DMF solution as well as in solid powder state.展开更多
A dinuclear cadmium complex [Cd2（bpbb）2Cl2（μ-Cl2）], where bpbb is 1,2-bis（1-phenyl-1H-benzo[d]imidazol-2-yl）benzene, was synthesized and characterized by X-ray singlecrystal structure analyses. Crystal data： C...A dinuclear cadmium complex [Cd2（bpbb）2Cl2（μ-Cl2）], where bpbb is 1,2-bis（1-phenyl-1H-benzo[d]imidazol-2-yl）benzene, was synthesized and characterized by X-ray singlecrystal structure analyses. Crystal data： C（64）H（44）Cd2Cl4N8, Mr = 1291.67, triclinic system, space group P1, a = 10.076（3）, b = 12.730（4）, c = 13.176（4） A, α = 99.087（3）, β = 109.859（3）, γ = 112.551（3）°, V = 1384.8（7） A3, Z = 1, Dc = 1.549 g/cm^3, λ = 0.71073 A, μ（Mo Kα） = 1.010 mm^（–1）, F（000） = 648, S = 1.062, R = 0.0425 and wR = 0.1130 for 9688 observed reflections with I 〉 2s（I）. One 1,2-bis（1-phenyl-1H-benzo[d]imidazol-2-yl）benzene coordinates to one cadmium ion. The cadmium is five-coordinated by three chloride ions and two nitrogen atoms from bpbb. Each cadmium ion is bridged by two chloride ions. The decomposition temperature is up to 420 ℃. The complex emits blue luminescence in DMF solution and in solid powder state.展开更多
A novel mononuclear copper（Ⅱ） complex [Cu（bbmc）Cl_2]·DMF,where bbmc is 1,1-bis（1H-benzoimidazol-2-ylmethyl）cyclohexane,was synthesized and characterized by X-ray single-crystal structure analysis.The compl...A novel mononuclear copper（Ⅱ） complex [Cu（bbmc）Cl_2]·DMF,where bbmc is 1,1-bis（1H-benzoimidazol-2-ylmethyl）cyclohexane,was synthesized and characterized by X-ray single-crystal structure analysis.The complex crystallizes in triclinic,space group P1 with a = 9.1088（5）,b = 11.0075（4）,c = 14.2326（6）A,α = 97.188（3）,β = 96.394（4）,γ = 111.430（4）°,V = 1298.73（10） A^3,Z = 2,D_c = 1.409 g/cm^3,μ（Mo Kα） = 1.074 mm^-1,F（000） = 572,S = 1.078,R = 0.0381 and w R = 0.0876 for 5593 observed reflections with I 〉 2σ（I）.The central Cu（Ⅱ） ion adopts a distorted tetrahedral geometry coordinated by two nitrogen atoms of the ligand and two chloride ions.The complex showed its thermal decomposition temperature up to 226 ℃ and exhibited an irreversible one-electron transfer process involving Cu^Ⅱ/Cu^I couple.展开更多
基金financially supported by the Natural Science Foundation of Guangdong Province(No.10152404801000017)Guangdong Province Undergraduate Training Programs for Innovation
文摘The complex [Cd（bbb）Cl2]·DMF·H2O, where bbb is 2-（2-（1H-benzo[d]imidazol-2-yl）benzyl）-1H-benzo[d]imidazole, was synthesized and characterized by X-ray single-crystal structure analyses. For the complex： C24H25Cl2CdN5O2, Mr = 598.77, crystal system, triclinic, space group P1, a = 9.9878（12）, b = 10.0008（12）, c = 13.2217（15） , α = 80.674（2）, β = 72.158（2）, γ = 86.776（2）°, V = 1240.5（3） 3, Z = 2, Dc = 1.598 g/cm3, λ = 0.71073, μ（MoKα） = 1.127 mm–1, F（000） = 600, S = 1.04, R = 0.0905 and wR = 0.3088 for 4805 observed reflections with I 〉 2σ（I）. It is a neutral complex. The distorted tetrahedral geometry of cadmium ion is coordinated by two nitrogen atoms of ligand and two chloride ions. The complex emits blue green luminescence with emission peaks at 480 nm in DMF solution.
基金supported by the Natural Science Foundation of Guangdong Province(No.1414050000021)the National Natural Science Foundation of China((NO.21403191))the State Undergraduate Training Programs for Innovation
文摘A complex [Cd2（tbb）C14]·4DMF·3H2O, where tbb is 1,2,3,4-tetra（1H-benzo[d]imi- dazol-2-yl）butane, was synthesized and characterized by X-ray single-crystal structure analyses. For this complex： C44H49Cd2C14N12OT, Mr= 1224.55, monoclinie system, space group C2/c, a = 29.563（3）, b = 14.2580（17）, c = 26.355（3） A,β = 97.036（2）°, V = 11025（2） A3, Z = 8, D,.= 1.475 g/cm3, 2 = 0.71073 A, IL（MoKa） = 1.021 mm-1, F（000） = 4936, S = 1.047, R = 0.0680 and wR = 0.1832 for 11812 observed reflections with I 〉 2σ（I）. It is a neutral dinuclear complex. One 1,2,3,4-tetra（1H-benzo[d]imidazol-2-yl）butane coordinates to two cadmium ions. Each cadmium ion is coordinated by two nitrogen atoms of tbb and two chloride ions. The complex emits blue luminescence in DMF solution as well as in solid powder state.
基金financially supported by the Natural Science Foundation of Guangdong Province(No.2014A030307010)Special funds for public welfare research and capacity building of Guangdong Province(Nos.2015A010105031,2016A010103042 and 2015A020211038)+1 种基金the National Spark Program Project(No.2015GA780053 and 2015GA780033)Lingnan Normal University Science Research Foundation(No.LZL1504)
文摘A dinuclear cadmium complex [Cd2（bpbb）2Cl2（μ-Cl2）], where bpbb is 1,2-bis（1-phenyl-1H-benzo[d]imidazol-2-yl）benzene, was synthesized and characterized by X-ray singlecrystal structure analyses. Crystal data： C（64）H（44）Cd2Cl4N8, Mr = 1291.67, triclinic system, space group P1, a = 10.076（3）, b = 12.730（4）, c = 13.176（4） A, α = 99.087（3）, β = 109.859（3）, γ = 112.551（3）°, V = 1384.8（7） A3, Z = 1, Dc = 1.549 g/cm^3, λ = 0.71073 A, μ（Mo Kα） = 1.010 mm^（–1）, F（000） = 648, S = 1.062, R = 0.0425 and wR = 0.1130 for 9688 observed reflections with I 〉 2s（I）. One 1,2-bis（1-phenyl-1H-benzo[d]imidazol-2-yl）benzene coordinates to one cadmium ion. The cadmium is five-coordinated by three chloride ions and two nitrogen atoms from bpbb. Each cadmium ion is bridged by two chloride ions. The decomposition temperature is up to 420 ℃. The complex emits blue luminescence in DMF solution and in solid powder state.
基金Financially supported from National Natural Science Foundation of China(No.21403191)Natural Science Foundation of Guangdong Province(Nos.2014A030307010 and 2015A0303010406)+2 种基金Special funds for public welfare research and capacity building in Guangdong Province(No.2015A010105031)Zhanjiang Science Technology Project(No.2013B01054)Lingnan Normal University Science Research Foundation(Nos.L1301 and LZL1504)
文摘A novel mononuclear copper（Ⅱ） complex [Cu（bbmc）Cl_2]·DMF,where bbmc is 1,1-bis（1H-benzoimidazol-2-ylmethyl）cyclohexane,was synthesized and characterized by X-ray single-crystal structure analysis.The complex crystallizes in triclinic,space group P1 with a = 9.1088（5）,b = 11.0075（4）,c = 14.2326（6）A,α = 97.188（3）,β = 96.394（4）,γ = 111.430（4）°,V = 1298.73（10） A^3,Z = 2,D_c = 1.409 g/cm^3,μ（Mo Kα） = 1.074 mm^-1,F（000） = 572,S = 1.078,R = 0.0381 and w R = 0.0876 for 5593 observed reflections with I 〉 2σ（I）.The central Cu（Ⅱ） ion adopts a distorted tetrahedral geometry coordinated by two nitrogen atoms of the ligand and two chloride ions.The complex showed its thermal decomposition temperature up to 226 ℃ and exhibited an irreversible one-electron transfer process involving Cu^Ⅱ/Cu^I couple.
